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91. 发明授权

US5387720A Process for the production of acrolein 失效
标题翻译：丙烯醛生产工艺
公开(公告)号：US5387720A
公开(公告)日：1995-02-07
申请号：US151390
申请日：1993-11-12
申请人： Armin Neher , Thomas Haas , Dietrich Arntz , Herbert Klenk , Walter Girke
发明人： Armin Neher , Thomas Haas , Dietrich Arntz , Herbert Klenk , Walter Girke
IPC分类号： C07B61/00 , C07C45/52 , C07C47/22
CPC分类号： C07C45/52
摘要： A process for the production of acrolein by dehydration of glycerol in the liquid phase or in the gaseous phase, in each case on acidic solid catalysts, is described. Compared with previously known processes, the space-time yield and catalyst service life may be surprisingly increased with higher selectivity by treating a glycerol-water mixture with a glycerol content of 10 to 40 wt. % at 180.degree. to 340.degree. C. (liquid phase) or at 250.degree. to 340.degree. C. (gaseous phase) on a solid catalyst with an H.sub.o value (Hammett acidity function) of less than +2, preferably less than -3.
摘要翻译：描述了通过在液相或气相中，在各种情况下在酸性固体催化剂上脱水甘油来生产丙烯醛的方法。与先前已知的方法相比，通过用甘油含量为10-40重量％的甘油 - 水混合物处理，通过更高的选择性可以惊人地增加时空产率和催化剂使用寿命。在180℃至340℃（液相）下或在250℃至340℃（气相）下，在Ho值（哈米特酸度函数）小于+2，优选小于-3的固体催化剂上。

92. 发明授权

US5334778A Process for the production of 1,3-propanediol 失效
标题翻译： 1,3-丙二醇生产工艺
公开(公告)号：US5334778A
公开(公告)日：1994-08-02
申请号：US63317
申请日：1993-05-19
申请人： Thomas Haas , Norbert Wiegand , Dietrich Arntz
发明人： Thomas Haas , Norbert Wiegand , Dietrich Arntz
IPC分类号： B01J23/42 , B01J23/46 , B01J23/755 , B01J25/02 , C07B61/00 , C07C29/14 , C07C29/141 , C07C31/20
CPC分类号： C07C29/141
摘要： 1,3-Propanediol produced in a known manner by catalytic hydrogenation of 3-hydroxypropionaldehyde (HPA) obtainable from acrolein has a high residual carbonyl content and leads to problems in the production of poly(1,3-propylene glycol terephthalate). Disclosed is a process for producing 1,3-propanediol having a residual carbonyl content, expressed as propionaldehyde, below 500 ppm and generally below 100 ppm produced in the presence of a fixed-bed or suspension hydrogenation catalyst under an H.sub.2 pressure of 5 to 300 bar providing the hydrogenation is carried out at 30.degree. to 80.degree. C. to an HPA conversion of 50 to 95% and is then continued at 100.degree. to 180.degree. C. to an HPA conversion of substantially 100%.
摘要翻译：通过丙烯醛获得的3-羟基丙醛（HPA）的催化氢化以已知方式制备的1,3-丙二醇具有高的残留羰基含量，并且导致聚（1,3-丙二醇对苯二甲酸酯）的生产中存在问题。公开了一种在固定床或悬浮氢化催化剂的存在下，在氢气压力为5至300℃下生产的具有残留羰基含量（表示为丙醛）低于500ppm且通常低于100ppm的1,3-丙二醇的方法提供氢化的条杆在30℃至80℃下进行至50至95％的HPA转化率，然后在100至180℃持续至基本上100％的HPA转化率。

93. 发明授权

US09012227B2 ω-Aminocarboxylic acids, ω-aminocarboxylic acid esters, or recombinant cells which produce lactams thereof 有权
标题翻译： ω-氨基羧酸，ω-氨基羧酸酯或产生其内酰胺的重组细胞
公开(公告)号：US09012227B2
公开(公告)日：2015-04-21
申请号：US12742318
申请日：2008-12-12
申请人： Andreas Karau , Volker Sieber , Thomas Haas , Harald Haeger , Katrin Grammann , Bruno Buehler , Lars Blank , Andreas Schmid , Guido Jach , Bernd Lalla , Andreas Mueller , Katrin Schullehner , Peter Welters , Thorsten Eggert , Andrea Weckbecker
发明人： Andreas Karau , Volker Sieber , Thomas Haas , Harald Haeger , Katrin Grammann , Bruno Buehler , Lars Blank , Andreas Schmid , Guido Jach , Bernd Lalla , Andreas Mueller , Katrin Schullehner , Peter Welters , Thorsten Eggert , Andrea Weckbecker
IPC分类号： C12N15/74 , C12N15/00 , C12N15/52 , C08G69/08 , C08G69/14 , C12P13/00
CPC分类号： C12N15/52 , C08G69/08 , C08G69/14 , C12P13/005
摘要： The present invention relates to a cell, which has been genetically modified relative to its wild type, so that in comparison with its wild type it is able to produce more ω-aminocarboxylic acids, more ω-aminocarboxylic acid esters or more lactams derived from ω-aminocarboxylic acids, starting from carboxylic acids or carboxylic acid esters. Furthermore, the present invention relates to a method for the production of a genetically modified cell, the cells obtainable by this method, a method for the production of ω-aminocarboxylic acids, of ω-aminocarboxylic acid esters or of lactams derived from ω-aminocarboxylic acids, the ω-aminocarboxylic acids, ω-aminocarboxylic acid esters or lactams derived from ω-aminocarboxylic acids obtainable by this method, a method for the production of polyamides based on ω-aminocarboxylic acids or based on lactams and the polyamides obtainable by this method.
摘要翻译：本发明涉及一种相对于其野生型经遗传修饰的细胞，因此与野生型相比，能够产生更多的ω-氨基羧酸，更多的ω-氨基羧酸酯或更多来源于ω的内酰胺氨基羧酸，起始于羧酸或羧酸酯。此外，本发明涉及生产转基因细胞的方法，可通过该方法获得的细胞，ω-氨基羧酸酯或ω-氨基羧酸衍生的内酰胺的生产ω-氨基羧酸的方法酸，ω-氨基羧酸，ω-氨基羧酸酯或衍生自可通过该方法得到的ω-氨基羧酸的内酰胺，制备基于ω-氨基羧酸或基于内酰胺的聚酰胺的方法和可通过该方法获得的聚酰胺。

94. 发明授权

US08255114B2 Method and measuring system for determining a wheel load 有权
标题翻译：用于确定车轮负载的方法和测量系统
公开(公告)号：US08255114B2
公开(公告)日：2012-08-28
申请号：US12555427
申请日：2009-09-08
申请人： Alexander Fink , Thomas Haas , Gregor Kuchler
发明人： Alexander Fink , Thomas Haas , Gregor Kuchler
IPC分类号： G01L5/00 , G01M17/02
CPC分类号： G01M17/007 , G01G19/086 , G01G23/3728 , G01G23/3742
摘要： A method and a measuring system determine a wheel load. These involve measuring a deformation of a tire and using a set of equations and equation parameters to calculate from the deformation the wheel load acting on the tire. In addition, a wheel load or a variable dependent on the load, which is used to calculate the wheel load, is received from an external system. Finally, the two wheel loads determined in different ways are compared, and the equations and/or equation parameters are adapted on the basis of the comparison.
摘要翻译：方法和测量系统确定车轮负载。这些涉及测量轮胎的变形，并使用一组方程式和方程式参数来计算从作用在轮胎上的车轮载荷的变形。此外，从外部系统接收用于计算车轮负载的车轮负载或取决于负载的变量。最后，比较以不同方式确定的两轮负载，并根据比较对方程和/或方程参数进行调整。

95. 发明申请

US20100249903A1 STENT 有权
公开(公告)号：US20100249903A1
公开(公告)日：2010-09-30
申请号：US12514177
申请日：2007-11-09
申请人： Thilo Wack , Thomas Haas
发明人： Thilo Wack , Thomas Haas
IPC分类号： A61F2/82
CPC分类号： A61F2/86 , A61F2/89 , A61F2/915 , A61F2002/91541 , A61F2002/91558 , A61F2230/0054 , A61F2230/0069 , A61F2240/001 , A61F2240/002 , A61F2250/0036 , A61F2250/0039 , B23K26/38 , B23K26/402 , B23K2103/42
摘要： A radially expansible annular stent is disclosed. The stent comprises a plurality of stenting turns around a lumen centred on a longitudinal axis. Adjacent turns of the stent are joined by connector struts. The stent annulus has a wall thickness related to the material from which it is formed. The radial thickness of the connector struts is smaller than that of the stent annulus. A method of making such a stent is also disclosed. The method includes cutting the connector struts from a tubular workpiece with a laser beam. The laser beam is aimed so as to be offset from a longitudinal axis of the workpiece to provide the reduced radial thickness of the connector struts.
摘要翻译：公开了径向可膨胀的环形支架。支架包括以纵向轴线为中心的腔的多个支架绕组。支架的相邻匝连接有连接器支柱。支架环具有与其形成的材料相关的壁厚度。连接器支柱的径向厚度小于支架环的径向厚度。还公开了制造这种支架的方法。该方法包括用激光束从管状工件切割连接器支柱。激光束的目的是偏离工件的纵向轴线，以提供连接器支柱的减小的径向厚度。

96. 发明授权

US07722847B2 Aqueous hydrogen peroxide solutions and method of making same 有权
标题翻译：过氧化氢水溶液及其制备方法
公开(公告)号：US07722847B2
公开(公告)日：2010-05-25
申请号：US10669978
申请日：2003-09-24
申请人： Thomas Haas , Claudia Brasse , Guido Stochniol , Jürgen Glenneberg , Wolfgang Wöll
发明人： Thomas Haas , Claudia Brasse , Guido Stochniol , Jürgen Glenneberg , Wolfgang Wöll
IPC分类号： C01B15/023 , C01B15/037
CPC分类号： C01B15/013 , C01B15/023 , C07D301/12
摘要： An aqueous hydrogen peroxide solution containing i) less than 50 wppm alkali metals, alkaline earth metals or combinations thereof in total, irrespective whether the alkali or alkaline earth metals are present in cationic or complex form; ii) less than 50 wppm of amines having a pkB of less than 4.5 or the corresponding protonated compounds in total; and iii) at least 100 wppm anions or compounds that can dissociate to form anions in total, where the wppm are based on the weight of hydrogen peroxide and the concentration of hydrogen peroxide is more than 50% by weight based on the total weight of the hydrogen peroxide solution. A process for preparation of said hydrogen peroxide solution and the use of said solution in a process for epoxidation of olefins is also disclosed.
摘要翻译：含有i）含有i）总计少于50wppm的碱金属，碱土金属或其组合的过氧化氢水溶液，不论碱金属或碱土金属是以阳离子或复合形式存在; ii）小于50wppm的pkB小于4.5的胺或相应的质子化合物总计; 和iii）至少100wppm的阴离子或化合物，其可以离解以形成阴离子，其中wppm基于过氧化氢的重量，并且过氧化氢的浓度基于总重量的50重量％过氧化氢溶液。还公开了制备所述过氧化氢溶液的方法和在烯烃环氧化方法中使用所述溶液。

97. 发明授权

US07507862B2 Process for hydrogenating an aromatic amine in the presence of a supported ruthenium catalyst 有权
标题翻译：在负载的钌催化剂存在下氢化芳族胺的方法
公开(公告)号：US07507862B2
公开(公告)日：2009-03-24
申请号：US11284932
申请日：2005-11-23
申请人： Guido Stochniol , Bernd Jaeger , Thomas Haas , Norbert Finke , Werner Burkhardt , Juergen Grunert
发明人： Guido Stochniol , Bernd Jaeger , Thomas Haas , Norbert Finke , Werner Burkhardt , Juergen Grunert
IPC分类号： C07C209/00
CPC分类号： C07C209/72 , B01J23/462 , B01J35/10 , B01J35/108 , C07C2601/14 , C07C211/36
摘要： The invention relates to a process for hydrogenating an aromatic amine that has at least one amino group bound to an aromatic nucleus with hydrogen in the presence of a supported catalyst that contains at least ruthenium as active metal. The catalyst support has a BET surface area in the range from greater than 30 m2/g to less than 70 m2/g and more than 50% of the pore volume of the catalyst support is formed by macropores having a pore diameter of greater than 50 nm and less than 50% are mesopores having a pore diameter of 2 to 50 nm.
摘要翻译：本发明涉及一种在至少含有钌作为活性金属的载体催化剂存在下氢化芳族胺的方法，所述芳族胺具有至少一个与芳族核结合的氨基。催化剂载体的BET表面积在大于30m 2 / g至小于70m 2 / g的范围内，并且催化剂载体的孔体积的大于50％由孔径大于50的大孔形成 nm且小于50％是孔径为2〜50nm的中孔。

98. 发明授权

US07400231B2 Sensor device, method and device for monitoring a sensor device, and system having a sensor device 有权
标题翻译：用于监测传感器装置的传感器装置，方法和装置以及具有传感器装置的系统
公开(公告)号：US07400231B2
公开(公告)日：2008-07-15
申请号：US11197281
申请日：2005-08-04
申请人： Thomas Haas
发明人： Thomas Haas
IPC分类号： B60R25/10
CPC分类号： B60C23/0408 , G01D5/485 , G01P3/22
摘要： A sensor device is disposed in a wheel. It contains an acceleration sensor, the measurement signal of which is representative of the acceleration of the sensor device. Detachment of the sensor device from its mounting position is detected according to the measurement signal of the acceleration sensor. The sensor device can also contain a position sensor, the measurement signal of which is representative of a relative position of the sensor device based on its mounting position. The sensor device can also contain a deformation measuring element disposed in such a way that a measurement signal of the deformation measuring element exhibits a characteristic oscillation if the sensor device has become detached from its mounting position.
摘要翻译：传感器装置设置在车轮中。它包含加速度传感器，其测量信号代表传感器装置的加速度。根据加速度传感器的测量信号检测传感器装置与其安装位置的分离。传感器装置还可以包含位置传感器，其测量信号代表传感器装置基于其安装位置的相对位置。传感器装置还可以包含变形测量元件，该变形测量元件以如下方式设置：如果传感器装置已经从其安装位置脱离，则变形测量元件的测量信号表现出特征振动。

99. 发明授权

US07241908B2 Process for the direct synthesis of hydrogen peroxide 有权
标题翻译：直接合成过氧化氢的方法
公开(公告)号：US07241908B2
公开(公告)日：2007-07-10
申请号：US11124059
申请日：2005-05-09
申请人： Thomas Haas , Guido Stochniol , Robert Jahn
发明人： Thomas Haas , Guido Stochniol , Robert Jahn
IPC分类号： C01B15/029 , C07D301/12
CPC分类号： C01B15/029
摘要： The invention is directed to the preparation of organic or aqueous-organic hydrogen peroxide solutions by direct synthesis from a non-explosive gaseous mixture containing hydrogen and oxygen. The process is carried out in the presence of a noble metal catalyst, using a reaction medium containing a halide and a strong acid. It can be performed in a stainless steel reactor without corrosion occurring to the reactor material if, during the reaction, the surface of the stainless steel is, at no place, in permanent contact with the gaseous mixture passing through the reactor.
摘要翻译：本发明涉及通过从含有氢和氧的非爆炸性气体混合物直接合成来制备有机或含水 - 有机过氧化氢溶液。该方法在贵金属催化剂的存在下，使用含有卤化物和强酸的反应介质进行。如果在反应过程中，不锈钢的表面在任何地方与通过反应器的气态混合物永久接触，可以在不锈钢反应器中进行，不会对反应器材料产生腐蚀。

100. 发明申请

US20060252947A1 Process for the production of hydrogen peroxide 有权
标题翻译：过氧化氢生产工艺
公开(公告)号：US20060252947A1
公开(公告)日：2006-11-09
申请号：US11401352
申请日：2006-04-11
申请人： Thomas Haas , Robert Jahn
发明人： Thomas Haas , Robert Jahn
IPC分类号： C01B15/01 , C07D301/12
CPC分类号： C01B15/029 , C07D301/12
摘要： Hydrogen peroxide is produced by reacting hydrogen and oxygen in the presence of a noble metal catalyst in a liquid reaction medium, the reaction being performed in the presence of a sulfuric acid alkyl ester. In the presence of sulfuric acid alkyl esters the noble metal catalyst exhibits a high and lasting activity for the formation of hydrogen peroxide with an elevated selectivity of hydrogen peroxide formation relative to the hydrogen used. Solutions of hydrogen peroxide in methanol obtainable by the process are suitable for use for the epoxidation of olefins.
摘要翻译：过氧化氢是通过氢和氧在贵金属催化剂存在下在液体反应介质中反应生成的，反应在硫酸烷基酯的存在下进行。在存在硫酸烷基酯的情况下，贵金属催化剂表现出用于形成过氧化氢的高且持久的活性，相对于所使用的氢，过氧化氢形成的选择性提高。通过该方法获得的过氧化氢在甲醇中的溶液适用于烯烃的环氧化。

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