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    • 93. 发明授权
    • Semiconductor device and manufacturing method thereof
    • 半导体装置及其制造方法
    • US07291911B2
    • 2007-11-06
    • US11047576
    • 2005-02-02
    • Tatsuya Usami
    • Tatsuya Usami
    • H01L23/48
    • H01L21/0337H01L21/3185H01L21/76898H01L23/147H01L23/49827H01L2224/05573H01L2224/16H01L2924/00014H01L2924/13091H01L2924/00H01L2224/05599
    • When forming a silicon nitride film to protect and insulate a surface on which a silicon substrate has been ground or polishing, by use of a mixed gas containing SiH4, N2, and NH3 as a reaction gas, a film is formed by a single-frequency parallel-plate plasma CVD method. Thereby, even when the film forming temperature is made not more than an allowable temperature limit of an adhesive to adhere a support (for example, approximately 100° C. or less, which is an allowable temperature limit when the adhesive is an ultraviolet curing resin), a high-quality film without exfoliation in a CMP step of the following step and with less leakage can be formed. This high-quality film is, if being prescribed by a refractive index, a film whose refractive index with respect to a wavelength of 633 nm is approximately 1.8 through 1.9.
    • 当形成氮化硅膜以保护和绝缘其上已经研磨或抛光硅衬底的表面时,通过使用含有SiH 4 N 2 N 2的混合气体, 和NH 3作为反应气体,通过单频平行板等离子体CVD法形成膜。 因此,即使当成膜温度不大于粘合剂的粘合剂的允许温度极限时(例如约100℃或更低,这是当粘合剂是紫外线固化树脂时的允许温度极限) ),可以形成在后续步骤的CMP步骤中没有剥离并且具有较少泄漏的高质量膜。 如果由折射率规定,则该高品质膜的折射率相对于633nm的折射率为1.8〜1.9左右。
    • 96. 发明授权
    • Semiconductor device and method of manufacturing the same
    • 半导体装置及其制造方法
    • US07217654B2
    • 2007-05-15
    • US10969429
    • 2004-10-21
    • Seiji NagaharaKazutoshi ShibaNobuaki HamanakaTatsuya UsamiTakashi Yokoyama
    • Seiji NagaharaKazutoshi ShibaNobuaki HamanakaTatsuya UsamiTakashi Yokoyama
    • H01L21/4763
    • H01L21/02063H01L21/31116H01L21/31138H01L21/76807H01L21/76808H01L21/76811H01L21/76825H01L21/76828H01L21/76831
    • A method of manufacturing a semiconductor device having a damascene structure contains a process of forming a first interlayer insulating film (6) and a second interlayer insulating film (4) formed of a low dielectric-constant film on a substrate, forming via holes (9) by using a first resist pattern (1a) formed on the second interlayer insulating film, conducting an organic peeling treatment using organic peeling liquid containing amine components and then forming a second resist pattern (1b) on the second interlayer insulating film. After the wet treatment, before a second antireflection coating (2b) is coated so as to be located below the second resist pattern is coated, at least one of an annealing treatment, a plasma treatment, a UV treatment and an organic solvent treatment is carried out to remove amine components which inhibit the catalysis reaction of acid occurring in the resist at the light exposure, thereby preventing degradation of the resolution of the second resist pattern (1b).
    • 一种制造具有镶嵌结构的半导体器件的方法包括在衬底上形成第一层间绝缘膜(6)和由低介电常数膜形成的第二层间绝缘膜(4)的工艺,形成通孔(9 )通过使用形成在第二层间绝缘膜上的第一抗蚀剂图案(1a),使用含有胺成分的有机剥离液进行有机剥离处理,然后在第二层间绝缘膜上形成第二抗蚀剂图案(1b)。 在湿处理之后,涂覆第二抗反射涂层(2b)以便位于第二抗蚀图案下方的涂层,退火处理,等离子体处理,UV处理和有机溶剂处理中的至少一个是 进行以除去抑制在曝光时在抗蚀剂中发生的酸的催化反应的胺成分,从而防止第二抗蚀剂图案(1b)的分辨率的劣化。