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    • 93. 发明授权
    • Process for producing photoconductive member from gaseous silicon
compounds
    • 从气态硅化合物制备光导体的方法
    • US4468443A
    • 1984-08-28
    • US354898
    • 1982-03-04
    • Isamu ShimizuKyosuke OgawaEiichi InoueJunichiro Kanbe
    • Isamu ShimizuKyosuke OgawaEiichi InoueJunichiro Kanbe
    • C23C16/30G03G5/082H01L31/0392H01L31/20
    • C23C16/30G03G5/08278H01L31/03921H01L31/202Y02E10/50Y02P70/521
    • A process for producing a photoconductive member, which comprises forming a photoconductive layer on a substrate for formation of a photoconductive layer by introducing starting substances for formation of a photoconductive layer under gaseous state into a deposition chamber maintained under a desired reduced pressure and exciting discharging under the gas atmosphere of said starting substances is characterized in that said starting substances are constituted of at least one substance selected from the first group consisting of substances(O) containing oxygen atoms as constituent atom, substances(N) containing nitrogen atoms as constituent atom and substances(C) containing carbon atoms as constituent atom, and at least two compounds selected from the second group consisting of the compounds of the formula:Si.sub.n H.sub.2n+2 (A)wherein n is a positive integer and the compounds of the formula:Si.sub.m H.sub.l X.sub.k (B)wherein m and k are positive integers, l is 0 or a positive integer, l+k=2m+2, and X represents a halogen atom, n and m being called "order number" hereinafter, and said at least two compounds selected from the second group consisting of the compounds represented by the formulas (A) and (B) to be introduced into said deposition chamber being controlled in amounts such that the proportion of the total of high order compounds is at least 1 vol. % based on the total of the minimum order compounds, the minimum order compound being one whose order number is the minimum among order numbers of said at least two compounds, the high order compound being one whose order number is higher than the order number of the minimum order compound.
    • 一种感光体的制造方法,其特征在于,在用于形成光电导层的基板上形成光电导层,通过将在气态下形成光电导层的起始物质引入到保持在期望的减压下的沉积室中,并且激发放电 所述起始物质的气体气氛的特征在于,所述起始物质由选自由含有氧原子作为构成原子的物质(O),含有氮原子作为构成原子的物质(N))构成的第一组中的至少一种物质和 含有碳原子作为构成原子的物质(C)和至少两种选自下列化合物的化合物:下式化合物SinH2n + 2(A)其中n为正整数,式为SimHlXk( B)其中m和k是正整数,l是0或正整数,l + k = 2m + 2,X表示 卤素原子,n和m在下文中称为“次数”,并且所述至少两种选自由待引入所述沉积室的由式(A)和(B)表示的化合物组成的第二组中的化合物是 控制量使得高级化合物的总量的比例至少为1体积%。 基于最小订单化合物的总量的%,最小订单化合物是其序列号是所述至少两种化合物的订单号中最小值的化合物,高级化合物是其订货号高于 最小订单复合。
    • 95. 发明授权
    • Photoconductive member having barrier and depletion layers
    • 具有阻挡层和耗尽层的感光体
    • US4359514A
    • 1982-11-16
    • US240836
    • 1981-03-05
    • Isamu ShimizuShigeru ShiraiEiichi Inoue
    • Isamu ShimizuShigeru ShiraiEiichi Inoue
    • G03G5/08C23C16/24G03G5/082H01L31/0248H01L31/09H01L31/20G03G5/14
    • H01L31/095C23C16/24G03G5/08235H01L31/202Y02E10/50Y02P70/521
    • A photoconductive member which is stable in its electrical and optical characteristics, not influenced by circumstances for its use, and possesses extremely high sensitivity to light, remarkably high anti-photo-fatigue property, and deterioration-resistant against repeated use, the photoconductive member comprising a substrate; a photoconductive layer; a barrier layer between the substrate and the photoconductive layer, and having a function of substantially inhibiting injection of carriers from the substrate side to the photoconductive layer; and a depletion layer region formed in the interfacial region of the photoconductive layer and the barrier layer, wherein the photoconductive layer and the barrier layer are made of an amorphous material with silicon as a matrix and hydrogen as a constituent atom, a part of the barrier layer is present between the depletion layer region and the substrate in such a thickness that, in order to inhibit injection of the carriers having the same polarity as that of minority carriers in the barrier layer from the substrate side to the photoconductive layer, probability of the carrier reaching the depletion layer region from the substrate side may be substantially neglected, and the photocarriers in the photoconductive layer having the same polarity as that of majority carriers in the barrier layer, among the photo-carriers to be generated in the photoconductive layer by irradiation of electromagnetic waves, are caused to move in the direction of the barrier layer.
    • 一种光电特性稳定的感光体,不受其使用环境的影响,具有非常高的光敏感性,抗光疲劳性,耐反复使用性,耐光老化性能优异, 底物; 光电导层; 基板和光电导层之间的阻挡层,并且具有基本上禁止载流子从基板侧向光电导层注入的功能; 以及形成在光导电层和阻挡层的界面区域中的耗尽层区域,其中光电导层和阻挡层由具有硅作为基体的无定形材料和氢作为构成原子制成,所述势垒的一部分 在耗尽层区域和衬底之间存在这样的厚度,即为了抑制从衬底侧向光电导层将阻挡层中的少数载流子具有相同极性的载流子注入到光电导层, 可以基本上忽略从衬底侧到达耗尽层区域的载流子,并且通过照射在光电导层中产生的光载流子中的光电导层中的光载流子具有与阻挡层中的多数载流子相同极性的光载流子 使电磁波沿阻挡层的方向移动。