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    • 95. 发明申请
    • Polycarbonate Prepolymer for Solid Phase Polymerization and Process for Producing Polycarbonate
    • 用于固相聚合的聚碳酸酯预聚物和用于生产聚碳酸酯的方法
    • US20080064847A1
    • 2008-03-13
    • US10546527
    • 2004-02-20
    • Mitsunori Ito
    • Mitsunori Ito
    • C08G64/30C08G64/00
    • C08G64/36
    • A polycarbonate prepolymer for solid state polymerization, which is produced by an oxidative carbonylation reaction of an aromatic dihydroxy compound, a monohydric phenol having a boiling point of 330° C. or below, carbon monoxide and oxygen, the polycarbonate prepolymer being characterized by that (a) a ratio of aryl carbonate groups and hydroxyl groups each constituting terminal groups of the prepolymer is from 2:8 to 8:2, and (b) a molecular weight distribution (Mw/Mn) is from 1.1 to 2.1; and a process of producing polycarbonates including a step of solid state-polymerizing the prepolymer so as to increase the molecular weight thereof. According to the present invention, the prepolymer having a controlled molecular weight distribution suitable for solid state polymerization is provided, and a high quality polycarbonate is efficiently produced in environmentally friend manner.
    • 一种用于固态聚合的聚碳酸酯预聚物,其通过芳族二羟基化合物,沸点为330℃以下的一元酚,一氧化碳和氧气的氧化羰基化反应产生,所述聚碳酸酯预聚物的特征在于 a)各自构成预聚物端基的碳酸芳基酯和羟基的比例为2:8〜8:2,(b)分子量分布(Mw / Mn)为1.1〜2.1; 以及制造聚碳酸酯的方法,包括使预聚物固态聚合的步骤,以增加其分子量。 根据本发明,提供了具有适合于固态聚合的受控分子量分布的预聚物,并且以环保的方式有效地制备了高质量的聚碳酸酯。
    • 99. 发明授权
    • Polycarbonate and optical material
    • 聚碳酸酯和光学材料
    • US06462165B1
    • 2002-10-08
    • US09646113
    • 2000-09-26
    • Mitsunori ItoShigeki Kuze
    • Mitsunori ItoShigeki Kuze
    • C08G6400
    • C08G64/30
    • Disclosed are polycarbonates which are obtained by preparing a polycarbonate prepolymer through prepolymerization followed by polymerizing it through solid-phase, swollen solid-phase or thin film melt-phase transesterification, and have a remaining monomer content of smaller than 100 ppm, especially a dihydroxy compound content of smaller than 100 ppm, or have an acetone soluble content of at most 3.5 or at most 3.0% by weight, or have a terminal hydroxyl fraction of smaller than 2 or smaller than 15 mol %; and optical materials and blow molding materials comprising the polycarbonate. The polycarbonates contain a reduced amount of impurities such as remaining monomers, oligomers and others and have improved physical properties including impact strength, and these are useful as optical materials and blow molding materials.
    • 公开了聚碳酸酯,其通过预聚合制备聚碳酸酯预聚物,然后通过固相,溶胀固相或薄膜熔融相酯交换聚合制得聚碳酸酯,并且其剩余单体含量小于100ppm,特别是二羟基化合物 或者丙酮可溶物含量为至多3.5重量%或至多3.0重量%,或具有小于2或小于15摩尔%的末端羟基分数; 以及包含聚碳酸酯的光学材料和吹塑材料。 聚碳酸酯含有减少量的杂质,例如剩余的单体,低聚物等,并具有包括冲击强度在内的改善的物理性能,并且它们可用作光学材料和吹塑材料。