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91. 发明授权

US07109221B2 Fungicidal mixtures based on amide compounds and morpholine or piperidine derivatives 有权
标题翻译：基于酰胺化合物和吗啉或哌啶衍生物的杀真菌混合物
公开(公告)号：US07109221B2
公开(公告)日：2006-09-19
申请号：US10183618
申请日：2002-06-28
申请人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N43/40 , A01N47/12
CPC分类号： A01N43/40 , A01N47/34 , A01N47/12 , A01N43/76 , A01N43/08 , A01N37/46 , A01N37/38 , A01N37/36 , A01N2300/00
摘要： Fungicidal mixtures comprise as active components a) an amide compound of the formula I A-CO—NR1R2I in which A, R1 and R2 are as defined in the description, and b) dimethomorph or flumetover, and/or c) a valinamide of the formula III in which R13 is C3–C4-alkyl and R14 is naphthyl or phenyl, where the phenyl radical is substituted in the 4-position by a halogen atom, a C1–C4-alkyl or C1–C4-alkoxy group, and/or d) benalaxyl, ofurace, metalaxyl, furalaxyl or oxydixyl, and/or e) 1-(2-cyano-2-methoxyiminoacetyl)-3-ethylurea in a synergistically effective amount.
摘要翻译：杀真菌混合物包含作为活性组分的a）式I的酰胺化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> A-CO-NR 1 其中A，R 1和R 2各自独立地表示：其中A，R 1，R 2， 2）如说明书中所定义，和b）烯酰吗啉或flumetover，和/或c）式III的缬氨酰胺，其中R 13是C 3

92. 发明授权

US06777411B1 Fungicide mixtures based on pyride amides and morpholine derivatives or piperidine derivatives 失效
标题翻译：基于吡啶酰胺和吗啉衍生物或哌啶衍生物的杀菌剂混合物
公开(公告)号：US06777411B1
公开(公告)日：2004-08-17
申请号：US09581906
申请日：2000-06-19
申请人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A61K31535
CPC分类号： A01N43/40 , A01N43/84 , A01N2300/00
摘要： Fungicidal mixtures comprising as active components a) an amide compound of the formula I A—CO—NR1R2 I in which A is an aryl group or an aromatic or non-aromatic, 5- or 6-membered heterocycle which has from 1 to 3 hetero atoms selected from O, N and S; where the aryl group or the heterocycle may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, halogen, CHF2, CF3, alkoxy, haloalkoxy, alkylthio, alkylsulfynyl and alkylsulfonyl; R1 is a hydrogen atom; R2 is a phenyl or cycloalkyl group which may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cyclo-alkenyloxy, phenyl and halogen, where the aliphatic and cycloaliphatic radicals may be partially or fully halogenated and/or the cycloaliphatic radicals may be substituted by from 1 to 3 alkyl groups and where the phenyl group may have from 1 to 5 halogen atoms and/or from 1 to 3 substituents which are selected, independently of one another, from alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and haloalkylthio, and where the amidic phenyl group may or may not be condensed with a saturated 5-membered ring which may or may not be substituted by one or more alkyl groups and/or may have a hetero atom selected from O and S, and b) a morpholine or piperidine derivative II selected from the group of the compounds IIa, IIb, IIc, IId [sic] and IIe [sic] in a synergistically effective amount.
摘要翻译：包含作为活性组分的杀真菌混合物a）式Iin的酰胺化合物，其中A是具有1至3个选自O，N和S的杂原子的芳基或芳族或非芳族的5或6元杂环; 其中芳基或杂环可以具有或不具有1,2或3个彼此独立地选自烷基，卤素，CHF 2，CF 3，烷氧基，卤代烷氧基，烷硫基，烷基亚硫炔基和烷基磺酰基的取代基; R 1， R 2是苯基或环烷基，其可以具有或不具有1,2或3个彼此独立地选自烷基，烯基，炔基，烷氧基，链烯氧基，炔氧基，环烷基的取代基，环烯基，环烷基氧基，环烯基氧基，苯基和卤素，其中脂族和脂环族基团可以被部分或完全卤化和/或脂环族基团可以被1至3个烷基取代，并且其中苯基可以具有1 至5个卤素原子和/ o 1至3个取代基，其彼此独立地选自烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基和卤代烷硫基，并且其中酰胺苯基可以或可以不与饱和五元环缩合，可以不被一个或多个烷基取代和/或可以具有选自O和S的杂原子，以及b）选自化合物IIa，IIb，IIc，IId和[II]的吗啉或哌啶衍生物II和 IIe [sic]具有协同有效的量。

93. 发明授权

US06489360B2 Fungicidal mixtures 有权
标题翻译：杀菌混合物
公开(公告)号：US06489360B2
公开(公告)日：2002-12-03
申请号：US10035050
申请日：2002-01-03
申请人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
发明人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
IPC分类号： A01N3712
CPC分类号： A01N37/50 , A01N47/24 , A01N37/06 , A01N2300/00
摘要： A fungicidal mixture comprises a1) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c and/or a2) a carbamate of the formula Id where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or one of its salts or adducts, and b) a dinitrophenol derivative of the formula II.a or II.b where n is 0, 1 or 2 in a synergistically effective amount.
摘要翻译：杀真菌混合物包含a）式Ia，Ib或Ic的苯基苄基醚衍生物和/或a2）式Id的氨基甲酸酯，其中X是CH或N，n是0,1或2，R是卤素，C 1 -C 4 - 烷基或C 1 -C 4 - 卤代烷基，如果n是2，则基团R可以不同，或者其盐或加合物之一，和b）式II.a或II.b的二硝基酚衍生物，其中n是 0,1或2，协同有效量。

94. 发明授权

US06436979B1 Fungicidal mixtures 有权
标题翻译：杀菌混合物
公开(公告)号：US06436979B1
公开(公告)日：2002-08-20
申请号：US09674542
申请日：2000-11-02
申请人： Klaus Schelberger , Maria Scherer , Reinhold Saur , Karl Eicken , Hubert Sauter , Eberhard Ammermann , Thomas Grote , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Reinhold Saur , Karl Eicken , Hubert Sauter , Eberhard Ammermann , Thomas Grote , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N4380
CPC分类号： A01N47/12 , A01N47/24 , A01N37/50 , A01N2300/00
摘要： A fungicidal mixture, comprising at least one compound selected from a) [sic] carbamates of the formula I, in which T is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, where the radicals R may be different if n is 2, a2) the oxime ether carboxylate of the formula II or a3) the oxime ether carboxamide of the formula III, and b) a compound of the formula IV where the substituents R1 to R3 have the following meaning: R1 is C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkyl-C3-C7-cycloalkyl, where these radicals may carry substituents selected from halogen, cyano and Cl-C4-alkoxy, R2 is C1-C4-alkyl or C1-C4-haloalkyl, R3 is hydrogen, halogen, Cl-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, N—C1-C4-alkylamino, Cl-C4-haloalkyl or C1-C4-haloalkoxy, Y is O, S, CHR4 or NR5, where R4 and R5 may each have the meanings mentioned for R2, n is 0, 1, 2 or 3, in a synergistically effective amount, and methods for controlling harmful fungi using these mixtures are described.
摘要翻译：一种杀真菌混合物，其包含至少一种选自以下的化合物：其中T为CH或N，n为0,1或2，R为卤素，C 1 -C 4烷基或C 1 -C 4的式I的（S） - 卤代烷基，其中如果n是2，基团R可以不同，a2）式II的肟醚羧酸酯ora3）式III的肟醚甲酰胺，和b）式IV化合物，其中取代基R 1至R 3 具有以下含义：R 1是C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基，C 1 -C 4烷基-C 3 -C 7 - 环烷基，其中这些基团可以带有选自卤素，氰基和Cl C 1-4 - 烷氧基，R 2是C 1 -C 4烷基或C 1 -C 4卤代烷基，R 3是氢，卤素，C 1 -C 4烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，N-C 1 -C 4烷基氨基，C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基，Y是O，S，CHR 4或NR 5，其中R 4和R 5可以各自具有R2，n为0,1,2或3所述的含义，描述了使用这些混合物来控制有害真菌的量和方法。

95. 发明授权

US06423733B1 Fungicidal mixtures 有权
标题翻译：杀菌混合物
公开(公告)号：US06423733B1
公开(公告)日：2002-07-23
申请号：US09871734
申请日：2001-06-04
申请人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
发明人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
IPC分类号： A01N4364
CPC分类号： A01N37/50 , A01N47/24 , A01N37/34 , A01N37/20 , A01N2300/00
摘要： A fungicidal mixture comprises a) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, and/or a carbamate of the formula Id where X is CH or N, n is 0, 1 or 2 and R is halogen, Cl-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, and b) a N-acetonylbenzamide of the formula II where: R1 and R3 independently of one another are each halogen or C1-C4-alkyl; R2 is cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy; R4 is hydrogen or C1-C4-alkyl; R5 is C2-C4-alkyl; R6 is thiocyano, isothiocyano or halogen, or a salt or adduct thereof, in a synergistically effective amount.
摘要翻译：杀真菌混合物包括：a）式Ia，Ib或Ic的苯基苄基醚衍生物和/或式Id的氨基甲酸酯，其中X是CH或N，n是0,1或2，R是卤素，C 1 -C 4 - 烷基或C 1 -C 4卤代烷基，如果n为2，则基团R可以不同，或其盐或其加合物，以及b）式II的N-丙酰基苯甲酰胺，其中：R 1和R 3彼此独立地为每个卤素或C 1 -C 4 - 烷基; R 2是氰基，C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基或C 1 -C 4 - 烷氧基; R 4是氢或C 1 -C 4烷基; -C 1-4 - 烷基; R 6是硫氰基，异硫氰基或卤素，或其盐或加合物，具有协同有效量。

96. 发明授权

US06410572B1 Fungicidal mixtures based on amide compounds and tetrachloroisophthalonitrile 有权
标题翻译：基于酰胺化合物和四氯间苯二腈的杀真菌混合物
公开(公告)号：US06410572B1
公开(公告)日：2002-06-25
申请号：US09581795
申请日：2000-06-19
申请人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N4340
CPC分类号： A01N43/40 , A01N37/34 , A01N2300/00
摘要： Fungicidal mixtures comprise as active components a) an amide compound of the formula I A—CO—NR1R2 in which A is an aryl group or an aromatic or non-aromatic, 5- or 6-membered heterocycle which has from 1 to 3 hetero atoms which are selected from O, N and S; where the aryl group or the heterocycle may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, halogen, CHF2, CF3, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl and alkylsulfonyl; R1 is a hydrogen atom; R2 is a phenyl or cycloalkyl group which may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cycloalkenyloxy, phenyl and halogen, where the aliphatic and cycloaliphatic radicals may be partially or fully halogenated and/or the cycloaliphatic radicals may be substituted by from 1 to 3 alkyl groups and where the phenyl group may have from 1 to 5 halogen atoms and/or from 1 to 3 substituents which are selected, independently of one another, from alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and haloalkylthio, and where the amidic phenyl group may or may not be condensed with a saturated 5-membered ring which may or may not be substituted by one or more alkyl groups and/or may have a hetero atom selected from O and S, and b) tetrachloroisophthalonitrile II in a synergistically effective amount.
摘要翻译：杀真菌混合物包含作为活性成分的a）式I的酰胺化合物，其中A是具有1至3个选自O，N的杂原子的芳基或芳族或非芳族的5或6元杂环其中芳基或杂环可以具有或不具有1,2或3个彼此独立地选自烷基，卤素，CHF 2，CF 3，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基和烷基磺酰基的取代基; R 1 R 2是苯基或环烷基，其可以具有或不具有1,2或3个彼此独立地选自烷基，烯基，炔基，烷氧基，烯氧基，炔氧基，环烷基，环烯基，环烷基氧基，环烯基氧基，苯基和卤素，其中脂族和脂环族基团可以部分或完全卤化，和/或脂环族基团可以被1至3个烷基取代，并且其中苯基可以具有1至5个卤素原子a nd /或1至3个选自烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基和卤代烷硫基的取代基，其中酰胺苯基可以或不可以与饱和五元环缩合可以或可以不被一个或多个烷基取代和/或可以具有选自O和S的杂原子，以及b）四氯间苯二腈II的协同有效量。

97. 发明授权

US06372748B1 Fungicide mixtures based on pyridine amides and fenarimol 失效
标题翻译：基于吡啶酰胺和芬那七醇的杀菌剂混合物
公开(公告)号：US06372748B1
公开(公告)日：2002-04-16
申请号：US09581426
申请日：2000-06-13
申请人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Karl Eicken , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N4354
CPC分类号： A01N43/40 , A01N43/54 , A01N2300/00
摘要： Fungicidal mixtures comprise as active components a) an amide compound of the formula I A—CO—NR1R2 I in which A is an aryl group or an aromatic or non-aromatic, 5- or 6-membered heterocycle which has from 1 to 3 hetero atoms selected from O, N and S; where the aryl group or the heterocycle may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, halogen, CHF2, CF3, alkoxy, haloalkoxy, alkylthio, alkylsulfynyl and alkylsulfonyl; R1 is a hydrogen atom; R2 is a phenyl or cycloalkyl group which may or may not have 1, 2 or 3 substituents which are selected, independently of one another, from alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cycloalkenyloxy, phenyl and halogen, where the aliphatic and cycloaliphatic radicals may be partially or fully halogenated and/or the cycloaliphatic radicals may be substituted by from 1 to 3 alkyl groups and where the phenyl group may have from 1 to 5 halogen atoms and/or from 1 to 3 substituents which are selected, independently of one another, from alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio and haloalkylthio, and where the amidic phenyl group may or may not be condensed with a saturated 5-membered ring which may or may not be substituted by one or more alkyl groups and/or may have a hetero atom selected from O and S, and b) (±)-(2-chlorophenyl)(4-chlorophenyl)(pyrimidin-5-yl)-methanol in a synergistically effective amount.
摘要翻译：杀真菌混合物包含作为活性成分的a）式I的酰胺化合物，其中A是具有1至3个选自O，N和S的杂原子的芳基或芳族或非芳族的5或6元杂环其中芳基或杂环可以具有或不具有1,2或3个彼此独立地选自烷基，卤素，CHF 2，CF 3，烷氧基，卤代烷氧基，烷硫基，烷基亚硫炔基和烷基磺酰基的取代基; R 1是氢原子; R2是苯基或环烷基，其可以具有或不具有1,2或3个彼此独立地选自烷基，烯基，炔基，烷氧基，烯氧基，炔氧基，环烷基，环烯基，环烷氧基，环烯基氧基，苯基和卤素，其中脂族和脂环族基团可以部分或完全卤化，和/或脂环族基团可以被1至3个烷基取代，并且其中苯基可以具有1至5个卤素原子和/或从 1至3个选自烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基和卤代烷硫基的取代基，其中酰胺基苯基可以或不可以与饱和的5元环稠合，其可以或不可以被一个或多个烷基取代和/或可以具有选自O和S的杂原子，和b）（±） - （2-氯苯基）（4-氯苯基）（嘧啶-5-基） - 甲醇的协同效应量。

98. 发明授权

US06365613B1 Fungicidal mixtures 有权
标题翻译：杀菌混合物
公开(公告)号：US06365613B1
公开(公告)日：2002-04-02
申请号：US09423973
申请日：1999-11-17
申请人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N4364
CPC分类号： A01N37/50 , A01N47/24 , A01N47/38 , A01N47/34 , A01N47/18 , A01N43/78 , A01N43/52 , A01N2300/00
摘要： A fungicidal mixture comprises a.1)a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, or a.2) a carbamate of the formula I.d, where X is CH and N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl and C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, and b) a fungicidally active compound from the class of the benzimidazoles or benzimidazole-releasing precursors (II), in a synergistically effective amount.
摘要翻译：杀真菌混合物包含a.1）式Ia，Ib或Ic的苯基苄基醚衍生物，或.2）式Id的氨基甲酸酯，其中X是CH且N，n是0,1或2，R是卤素，C 1 -C 4 - 烷基和C 1 -C 4卤代烷基，如果n为2，基团R可以不同，或其盐或其加合物，和b）来自苯并咪唑或苯并咪唑类的杀真菌活性化合物，释放前体（II），协同有效量。

99. 发明授权

US06316452B1 Fungicidal mixture 有权
标题翻译：杀菌剂混合物
公开(公告)号：US06316452B1
公开(公告)日：2001-11-13
申请号：US09423962
申请日：1999-11-17
申请人： Klaus Schelberger , Dietrich Mappes , Gerd Stammler , Hubert Sauter , Erich Birner , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
发明人： Klaus Schelberger , Dietrich Mappes , Gerd Stammler , Hubert Sauter , Erich Birner , Manfred Hampel , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann
IPC分类号： A01N4354
CPC分类号： A01N37/50 , A01N2300/00
摘要： A fungicidal mixture comprises a) a phenyl benzyl ether derivative of the formula I [sic] and b) (±)-(2-chlorophenyl)(4-chlorophenyl)(pyrimidin-5-yl)methanol in a synergistically effective amount.
摘要翻译：杀真菌混合物包含a）具有协同有效量的式I [sic]和b）（±） - （2-氯苯基）（4-氯苯基）（嘧啶-5-基）甲醇的苯基苄基醚衍生物

100. 发明授权

US06291497B1 Fungicidal mixtures 有权
标题翻译：杀菌混合物
公开(公告)号：US06291497B1
公开(公告)日：2001-09-18
申请号：US09423859
申请日：1999-11-17
申请人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
发明人： Klaus Schelberger , Maria Scherer , Hubert Sauter , Bernd Müller , Erich Birner , Joachim Leyendecker , Eberhard Ammermann , Gisela Lorenz , Siegfried Strathmann , Reinhold Saur
IPC分类号： A01N4364
CPC分类号： A01N37/50 , A01N47/24 , A01N37/34 , A01N37/20 , A01N2300/00
摘要： A fungicidal mixture comprises a) a phenyl benzyl ether derivative of the formula I.a, I.b or I.c, and/or a carbamate of the formula Id where X is CH or N, n is 0, 1 or 2 and R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, it being possible for the radicals R to be different if n is 2, or a salt or adduct thereof, and (b) a N-acetonylbenzamide of the formula II where: R1 and R3 independently of one another are each halogen or C1-C4-alkyl; R2 is cyano, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl or C1-C4-alkoxy; R4 is hydrogen or C1-C4-alkyl; R5 is C2-C4-alkyl; R6 is thiocyano, isothiocyano or halogen, or a salt or adduct thereof, in a synergistically effective amount.
摘要翻译：杀真菌混合物包括：a）式Ia，Ib或Ic的苯基苄基醚衍生物和/或式Id的氨基甲酸酯，其中X是CH或N，n是0,1或2，R是卤素，C 1 -C 4 - 烷基或C 1 -C 4 - 卤代烷基，如果n是2，基团R可以不同，或其盐或其加合物，和（b）式II的N-丙酮基苯甲酰胺，其中：R 1和R 3独立地为另一个为卤素或C 1 -C 4 - 烷基; R 2为氰基，C 1 -C 4 - 烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基或C 1 -C 4 - 烷氧基; R 4为氢或C 1 -C 4 - 是C 2 -C 4 - 烷基; R 6是硫氰基，异硫氰基或卤素，或其盐或加合物，具有协同有效量。

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