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    • 92. 发明授权
    • Pesticidally active phosphoric (phosphonic) acid ester amides
    • 杀虫活性磷酸(膦酸)酸酯酰胺
    • US4386082A
    • 1983-05-31
    • US352687
    • 1982-02-26
    • Dieter ArltBernhard HomeyerIngeborg HammannVolker Paul
    • Dieter ArltBernhard HomeyerIngeborg HammannVolker Paul
    • A01N57/26A01N57/28A01N57/30C07F9/24C07F9/44
    • C07F9/4488A01N57/28A01N57/30C07F9/2483
    • The invention relates to new phosphoric (phosphonic) acid ester amides of the general formula ##STR1## wherein R.sup.1 represents a hydrogen atom or an optionally substituted alkyl radical,R.sup.2 represents an optionally substituted alkyl or optionally substituted alkoxy radical,R.sup.3 represents an optionally substituted alkyl or optionally substituted aryl radical andHal represents a halogen atom,which are obtained by the reaction of phosphoric (phosphonic) acid ester amides of the general formula ##STR2## wherein R.sup.1, R.sup.2 and Hal have the meaning given above, with sulphenyl chlorides of the general formulaClSR.sup.3 (III)wherein R.sup.3 has the meaning given above, in the presence of an acid acceptor and, if appropriate, in the presence of a solvent, and which can be used for combating pests (such as insects, acaricids and nematodes) or for combating microbes (especially fungi).
    • 本发明涉及通式为(I)的新的磷酸(膦酸)酯酰胺,其中R 1表示氢原子或任选取代的烷基,R 2表示任选取代的烷基或任选取代的烷氧基,R 3表示 任选取代的烷基或任选取代的芳基,Hal表示卤素原子,其通过使通式(II)的磷酸(膦酸)酯酯酰胺(其中R1,R2和Hal具有上述含义) ,其中R3具有上述含义的通式为ClSR 3(III)的磺酰氯,在酸受体存在下,如果合适的话,在溶剂存在下,可用于防治害虫(如 昆虫,螨类和线虫)或用于对抗微生物(特别是真菌)。
    • 96. 发明授权
    • Combating pests with N-phosphonylcarbonyl-carbamates
    • 防治害虫与N-膦酰基羰基 - 氨基甲酸酯
    • US4357329A
    • 1982-11-02
    • US276406
    • 1981-06-22
    • Gerhard HeywangEngelbert KuhleIngeborg HammannBernhard Homeyer
    • Gerhard HeywangEngelbert KuhleIngeborg HammannBernhard Homeyer
    • A01N57/18C07F9/38C07F9/40C07F9/6518C07F9/655A01N57/24A01N57/22
    • A01N57/18C07F9/4065C07F9/65181
    • N-Phosphonylcarbonyl-N-methylcarbamic acid esters of the formula ##STR1## in which R.sup.1 and R.sup.2 can be identical or different and each represents alkyl, alkenyl or alkynyl, it being possible for any of these radicals to be substituted by halogen, andR.sup.3 represents alkyl, phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl, it being possible for any of these radicals to carry one or more substituents selected from alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylthio, alkenylthio, alkynylthio, dialkylamino, halogenoalkyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl and dioxolanyl, orR.sup.3 represents a radical of the formula ##STR2## in which R.sup.4 and R.sup.5 can be identical or different and each represents alkyl, alkoxy, alkylthio, alkylthioalkyk, cyano, alkoxycarbonyl, dialkylcarbamoyl, dialkoxyphosphoryl or triazolyl, orR.sup.4 and R.sup.5, together with the C atom to which they are bonded, form a dithiolane, dithiane, oxythiolane or oxathiane ring which is optionally substituted by methyl or phenyl,which are pesticidally active.
    • 其中R 1和R 2可以相同或不同并且各自代表烷基,烯基或炔基,这些基团中的任何一个可以被卤素取代的N-膦酰基羰基-N-甲基氨基甲酸酯, 代表烷基,苯基,萘基,苯并二恶烷基,二氢苯并呋喃基或茚满基,这些基团中的任何一个可以携带一个或多个选自烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷硫基,烯硫基,炔硫基,二烷基氨基,卤代烷基 ,卤素,硝基,氰基,环烷基,甲脒基,二烷基和二氧戊环基,或R 3表示下式的基团,其中R 4和R 5可以相同或不同,并且各自表示烷基,烷氧基,烷硫基,烷硫基烷基,氰基, ,二烷基氨基甲酰基,二烷氧基磷酰基或三唑基,或者R4和R5与它们所键合的C原子一起形成二硫杂环戊烷,二噻烷,氧硫杂环丁烷或氧硫杂环, 由甲基或苯基取代,它们具有杀虫活性。