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    • 91. 发明授权
    • Infrared absorbing indene-bridged-polymethine dyes for dye-donor element
used in laser-induced thermal dye transfer
    • 用于激光诱导热染料转移的染料供体元件的红外吸收茚 - 桥联聚甲炔染料
    • US5019480A
    • 1991-05-28
    • US367064
    • 1989-06-16
    • Charles D. DeBoerSteven Evans
    • Charles D. DeBoerSteven Evans
    • B41M5/382B41M5/385B41M5/388B41M5/39B41M5/392B41M5/42B41M5/46D06P5/00
    • B41M5/465B41M5/392Y10S430/145Y10S430/146
    • A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is an indene-bridged-polymethine dye. In a preferred embodiment, the indene-bridged-polymethine dye has the following formula: ##STR1## wherein: R represents a substituted or unsubstituted alkyl or cycloalkyl group having from 1 to about 6 carbon atoms or an aryl or hetaryl group having from about 5 to about 10 atoms; R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryly group; or any two of said R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;A represents --COR, --CO.sub.2 R, --CONHR, --CONR.sub.2, --SO.sub.2 R, --SO.sub.2 NHR, --SO.sub.2 NR.sub.2 or --CN;B represents A or hydrogen, --R, --SR, --OR or --NR; or A or B may be joined together to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y represents a dialkyl-substituted carbon atom, a vinylene group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, NR, or a direct bond to the carbon at the R.sup.2 position;Z represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; andn is 0 to 3.
    • 93. 发明授权
    • Infrared absorbing bis(chalcogenopyrylo)polymethine dyes for dye-donor
element used in laser-induced thermal dye transfer
    • 用于激光诱导热染料转移的染料供体元件的红外吸收双(硫属元素复合)聚甲炔染料
    • US4948777A
    • 1990-08-14
    • US366970
    • 1989-06-16
    • Steven EvansCharles D. DeBoer
    • Steven EvansCharles D. DeBoer
    • B41M5/392B41M5/385B41M5/388B41M5/39B41M5/46
    • B41M5/465B41M5/392Y10S428/913Y10S428/914Y10S430/146Y10T428/31786
    • A dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in the dye layer, and wherein the infrared-absorbing material is a bis(chalcogenopyrylo)polymethine dye. In a preferred embodiment, the bis(chalcogenopyrylo)polymethine dye has the following formula: ##STR1## wherein: R.sup.1, R.sup.2 and R.sup.3 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R.sup.1, R.sup.2 and R.sup.3 groups may be joined together to form a 5- to 7-membered substituted or unsubstituted carboxyclic or heterocyclic ring; or R.sup.1 may be joined to Z.sup.1 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; or R.sup.3 may be joined to Z.sup.2 to form a fused 5- or 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring;Y.sup.1 and Y.sup.2 each independently represents sulfur, oxygen, tellurium, or selenium, with the methine chain being joined ortho or para to each of Y.sup.1 and Y.sup.2 ;Z.sup.1 and Z.sup.2 each independently represents hydrogen; a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms; a substituted or unsubstituted aryl or hetaryl group having from about 5 to about 10 atoms; or the atoms necessary to complete a 5- to 7-membered carbocyclic or heterocyclic ring;each m independently is 1 to 4;n is 1 to 3; andX is a monovalent anion.
    • 96. 发明授权
    • Nondiffusible yellow metallized azo dye-releasing compounds
    • 不溶性黄色金属化偶氮染料释放化合物
    • US4481141A
    • 1984-11-06
    • US484806
    • 1983-04-14
    • Steven Evans
    • Steven Evans
    • C09B45/00G03C7/305G03C8/10C09B45/10C09B45/12C09B45/20C09B45/22
    • C09B45/00G03C7/30547G03C8/10
    • Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) Z represents alkyl, substituted alkyl, aryl or substituted aryl;(c) R represents CN or J-L;(d) J represents a bivalent ##STR2## (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring;(f) Z.sup.1 represents the same groups as Z;(g) each CAR independently represents a ballasted carrier moiety capable of releasing the diffusible yellow dye moiety or precursor thereof as a function of development of a silver halide emulsion layer under alkaline conditions;(h) each n is 0 or 1, with the proviso that at least one n is 1;(i) Lig is a monoanionic tridentate ligand; and(j) Me is a polyvalent, hexacoordinate metal ion.
    • 描述了摄影元件,扩散转移组合物,配位络合物和方法,其使用具有可释放的黄色染料部分或其前体的新型不扩散化合物,具有下式的化合物:其中:(a)X表示完成所需的原子 5-或6-元芳族杂环稠合环; (b)Z表示烷基,取代的烷基,芳基或取代的芳基; (c)R表示CN或J-L; (d)J表示二价的(e)L表示烷基,取代的烷基,芳基,取代的芳基,或可以与Z一起以完成含羰基的5-或6-元杂环或碳环; (f)Z1表示与Z相同的基团; (g)每个CAR独立地代表能够在碱性条件下释放可扩散的黄色染料部分或其前体作为卤化银乳剂层的功能的压载载体部分; (h)每个n为0或1,条件是至少一个n为1; (i)Lig是单阴离子三齿配体; 和(j)Me是多价六价金属离子。
    • 97. 发明授权
    • Photographic products and processes employing novel nondiffusible
magenta dye-releasing compounds and precursors thereof
    • 使用新型不扩散品红色染料释放化合物及其前体的摄影产品和方法
    • US4420550A
    • 1983-12-13
    • US458499
    • 1983-01-17
    • Steven EvansJames K. Elwood
    • Steven EvansJames K. Elwood
    • C09B27/00G03C8/10G03C5/54G03C1/10G03C1/40G03C7/00
    • C09B27/00G03C8/10
    • Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible magenta dye moiety comprising a 4-(2-heterocyclylazo)phenol having a heterocyclic ring fused thereto, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring;(b) Y represents the atoms necessary to complete a 5- or 6-membered heterocyclic fused ring;(c) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(d) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.
    • 描述了摄影元件,扩散转移组合物,配位络合物和方法,其使用能够释放至少一个包含稠合有杂环的4-(2-杂环基偶氮)苯酚的可扩散品红色染料部分的新型不扩散化合物,所述化合物具有 式:其中:(a)X表示完成5-或6-元杂环所必需的原子; (b)Y表示完成5-或6-元杂环稠环所必需的原子; (c)CAR表示在碱性条件下能够释放可扩散品红染料部分作为卤化银乳剂层的功能的压载载体部分; (d)R表示羟基,其盐或其可水解的前体,或通过其上的氧原子与染料部分连接的CAR; 和(e)n为0,1或2,条件是当n为0时,R为通过其上的氧原子与染料部分连接的CAR。
    • 98. 发明授权
    • Surface modification of carbon black
    • 炭黑表面改性
    • US09068093B2
    • 2015-06-30
    • US13534293
    • 2012-06-27
    • Steven EvansEllen J. Pyszczek
    • Steven EvansEllen J. Pyszczek
    • C09D11/02C09C1/44C09D11/324
    • C09D11/324
    • A process for modifying the surface of a carbon black by contacting said carbon black with a conjugated diimine compound. The conjugated diimine compound may comprise various substituents to provide the carbon black with desired corresponding properties, such as groups to impart increased hydrophilicity and self-dispersibility to the carbon black. Other embodiments relate to novel carbon black products, which may be prepared according to a process of the invention. The carbon black products may be used in the same applications as conventional carbon blacks. Such uses include, but are not limited to, plastic compositions, aqueous inks, aqueous coatings, rubber compositions, paper compositions, and textile compositions. In a specific embodiment, the resulting surface modified carbon black is employed as a pigment in an aqueous inkjet ink composition.
    • 通过使所述炭黑与共轭二亚胺化合物接触来改性炭黑表面的方法。 共轭二亚胺化合物可以包括各种取代基,以使炭黑具有所需的相应性能,例如赋予炭黑增加的亲水性和自分散性的基团。 其它实施方案涉及新的炭黑产品,其可以根据本发明的方法制备。 炭黑产品可以用于与常规炭黑相同的应用中。 这些用途包括但不限于塑料组合物,水性油墨,水性涂料,橡胶组合物,纸组合物和纺织组合物。 在具体实施方案中,在水性喷墨油墨组合物中使用得到的表面改性炭黑作为颜料。