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1. 发明授权

US10450390B2 Metallocene compound, metallocene-supported catalyst, and method of preparing polyolefin using the same 有权
公开(公告)号：US10450390B2
公开(公告)日：2019-10-22
申请号：US15507968
申请日：2015-12-15
申请人： LG CHEM, LTD.
发明人： Sung Min Lee , Bog Ki Hong , Kyung Jin Cho , Se Young Kim , Chang Woan Han , Ki Soo Lee , Eun Kyoung Song
IPC分类号： C08F4/00 , C08F4/6592 , C08F4/652 , C08F10/00 , C07C13/465 , C07D221/18 , C08F12/00
摘要： Provided are a novel metallocene compound, a metallocene-supported catalyst, and a method of preparing a polyolefin using the same. The metallocene-supported catalyst according to the present disclosure exhibits a high polymerization activity even when the metallocene compound is supported on a support, thereby showing an excellent activity and preparing a polyolefin having a high molecular weight.

2. 发明授权

US08865849B2 Polyethylene and process for production thereof 有权
标题翻译：聚乙烯及其生产方法
公开(公告)号：US08865849B2
公开(公告)日：2014-10-21
申请号：US13856729
申请日：2013-04-04
申请人： ExxonMobil Chemical Patents Inc.
发明人： Donna J. Crowther , David M. Fiscus
IPC分类号： C08F4/652 , C08F4/642 , C08F4/6592 , C08F210/16 , B32B27/32 , C08F297/08 , C08F210/14 , C08F299/00 , C08F4/52 , C08F4/659
CPC分类号： C08F210/14 , B32B27/32 , C08F4/52 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F297/08 , C08F299/00 , Y10S526/943 , Y10T428/1345 , Y10T428/31938 , C08F2/34 , C08F4/6428 , C08F2500/03 , C08F2500/08 , C08F2500/20 , C08F2500/21
摘要： This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
摘要翻译：本发明涉及一种聚合烯烃的方法，其中在用作活化剂之前，将甲基铝氧烷溶液中的三甲基铝的量调节至1至25mol％，其中通过溶液的1 H NMR确定摩尔％的三甲基铝在与任何支持组合之前。本发明还涉及一种聚合烯烃的方法，其中存在于甲基铝氧烷溶液中的未知物质的量在使用前调节为0.10至0.65个整合单元作为活化剂，其中未知物质的量由在与任何载体组合之前进行的溶液的1 H NMR光谱。优选地，甲基铝氧烷溶液存在于还包含茂金属过渡金属化合物的催化剂体系中。

3. 发明授权

US06930069B2 Polymerization catalyst for olefins and process for polymerization of olefins 有权
标题翻译：烯烃聚合催化剂和烯烃聚合方法
公开(公告)号：US06930069B2
公开(公告)日：2005-08-16
申请号：US10471236
申请日：2002-11-12
申请人： Kunihiko Tashino , Maki Sato
发明人： Kunihiko Tashino , Maki Sato
IPC分类号： C08F4/652 , C08F4/654 , C08F4/658 , C08F10/00 , C08F110/06 , B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6465 , C08F2500/12 , C08F2500/04
摘要： Olefin polymers with a broad molecular weight distribution can be obtained while maintaining the high stereoregularity of the polymers by polymerizing olefins using a catalyst comprising (A) a solid catalyst component prepared by contacting (a) a dialkoxymagnesium, (b) a tetravalent titanium halide compound, and (c) an electron donor compound one another, (B) an organoaluminum compound of the formula R1pAlQ3-p, and (C) an aminosilane compound of the formula R2R3Si(OR4)2.
摘要翻译：可以通过使用包含（A）通过使（a）二烷氧基镁，（b）四价卤化钛化合物（a）和（b））接触而制备的固体催化剂组分的催化剂，通过使烯烃聚合来保持聚合物的高立构规整性，同时保持聚合物的高立构规整性，和（c）彼此的电子给体化合物，（B）式R 1的有机铝化合物，其中R 1，R 3，R 3，和（C）式R 2的三氨基硅烷化合物Si（OR 4）2 N 2。

4. 发明授权

US06858558B2 Olefin polymerization catalyst component and catalyst system and polymerization process using such a catalyst system 失效
标题翻译：烯烃聚合催化剂组分和催化剂体系以及使用这种催化剂体系的聚合方法
公开(公告)号：US06858558B2
公开(公告)日：2005-02-22
申请号：US10469832
申请日：2002-03-05
申请人： Winfried Peter Kretschmer
发明人： Winfried Peter Kretschmer
IPC分类号： C08F10/00 , B01J31/00 , C08F4/44 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/652 , C08F4/6592
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F210/16 , C08F2420/04 , Y10S526/943 , C08F4/6592 , C08F210/14 , C08F2500/03
摘要： The invention relates to a catalyst component and a catalyst system for the preparation of high molecular weight ethylene or alpha-olefin homopolymers, ethylene-alpha-olefin copolymers, terpolymers or tetrapolymers, in a polymerization process, which is expediently effected in solution, at elevated temperature, preferably at least 80 DEG C. The catalyst system comprises a group 4-6 metal, preferably group 4 metal, a cyclic ligand (such as a cyclopentadienyl-type ligand), which forms a delocalized pi-bond with the metal M, a monohapto bonded 1,3-diaza-2-imino heterocyclic ligand (such as an iminoimidazolidine-type ligand) and anionic ligands and a catalyst activator coupound.
摘要翻译：本发明涉及在聚合过程中用于制备高分子量乙烯或α-烯烃均聚物，乙烯-α-烯烃共聚物，三元共聚物或四元共聚物的催化剂组分和催化剂体系，其在溶液中有利地在升高的温度，优选至少80℃。催化剂体系包括4-6族金属，优选4族金属，与金属M形成离域π键的环状配体（例如环戊二烯基型配体）单偶键连接的1,3-二氮杂-2-亚氨基杂环配体（如亚氨基咪唑烷型配体）和阴离子配体和催化剂活化剂。

5. 发明授权

US5288824A Preparation of homo- and copolymers of propene by means of a Ziegler-Natta catalyst system 失效
标题翻译：通过齐格勒 - 纳塔催化剂体系制备丙烯的均聚物和共聚物
公开(公告)号：US5288824A
公开(公告)日：1994-02-22
申请号：US934848
申请日：1992-08-25
申请人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
发明人： Juergen Kerth , Rainer Hemmerich , Peter Koelle , Patrik Mueller
IPC分类号： C08F4/658 , C08F4/02 , C08F4/60 , C08F4/647 , C08F4/652 , C08F10/00 , C08F10/06 , C08F4/64
CPC分类号： C08F10/06
摘要： Polymers of propene are prepared using a Ziegler-Natta catalyst system comprising (1) titanium component which is based on a finely divided, shape-imparting silica gel and contains titan- ium, magnesium, chlorine and a benzenecarboxylic acid derivative, (2) an aluminum component and (3) a silane component. The process employs a titanium component (1) which is obtained by a method in which (1.1) first (I) a carrier is prepared from (Ia) a silica gel which has a relatively high moisture content, (Ib) an organomagnesium compound and (Ic) a gaseous chlorinating agent in a manner such that (1.1.1) first (Ia) is reacted with (Ib), (1.1.2) then (Ic) is passed into the mixture obtained from (1.1.1), (1.2) then a solid-phase intermediate is prepared from (I), (II) an alkanol, (III) titanium tetrachloride and (IV) a phthalic acid derivative in a manner such that (1.2.1) first (I) is reacted with (II), (1.2.2) then (III) is introduced into the mixture resulting from (1.2.1), with the proviso that (IV) is also introduced in (1.2.1) or (1.2.2), (1.3) then the solid-phase intermediate resulting from (1.2) is extracted with titanium tetrachloride or with a titanium tetrachloride/-hydrocarbon mixture and (1.4) finally the solid-phase product resulting from (1.3) is washed with a liquid hydrocarbon.
摘要翻译：使用齐格勒 - 纳塔催化剂体系制备丙烯聚合物，该催化剂体系包括（1）基于精细分散的形状赋予硅胶并含有钛，镁，氯和苯甲酸衍生物的钛组分，（2）铝成分和（3）硅烷成分。该方法采用通过以下方法得到的钛组分（1）：其中（1.1）第一（I）载体由（Ia）由具有相对高的水分含量的硅胶制备，（Ib）有机镁化合物和（Ic）气态氯化剂，使得（1.1.1）第一（Ia）与（Ib），（1.1.2）反应，然后（Ic）进入从（1.1.1）获得的混合物中，（1.2），然后以（I），（II）烷醇，（III）四氯化钛和（IV）邻苯二甲酸衍生物的方式制备固相中间体，使得（1.2.1）第一（I）为与（II）反应，（1.2.2）然后将（III）引入由（1.2.1）得到的混合物中，条件是（IV）也引入（1.2.1）或（1.2.2），（1.3），然后用四氯化钛或四氯化钛/ - 烃混合物萃取由（1.2）得到的固相中间体，（1.4）最后将由（1.3）得到的固相产物用液体烃。

6. 发明授权

US4826794A Catalyst system for (co)polymerization of ethylene in solution 失效
标题翻译：溶液中乙烯（共）聚合的催化剂体系
公开(公告)号：US4826794A
公开(公告)日：1989-05-02
申请号：US154370
申请日：1988-02-10
申请人： Luc M. C. Coosemans , Frans J. P. G. van den Bosch
发明人： Luc M. C. Coosemans , Frans J. P. G. van den Bosch
IPC分类号： B01J31/14 , B01J37/04 , C08F4/60 , C08F4/62 , C08F4/64 , C08F4/646 , C08F4/652 , C08F4/659 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02
摘要： Catalyst system, suitable for the (co)polymerization of ethylene and optionally minor amounts of 1-alkenes and/or dienes at such temperatures that the copolymer formed goes into solution, to be prepared by combining at least two components A and B, which components comprise:A. one or more magnesium compounds, one or more aluminium compounds, one or more transition metal compounds and optionally one or more halogen compounds, in such amounts that the atomic ratio of halogen to magnesium is at least 2, the atomic ratio of aluminium to transition metal is at least 3, the atomic ratio of aluminium to magnesium is at least 1, and the atomic ratio of magnesium to transition metal is at least 0.5,B. one or more organoaluminium compounds of the general formula R.sub.m.sup.1 Al X.sup.1.sub.3-m, where the symbols R.sup.1 are equal or different and represent a hydrocarbon residue with 1-20 carbon atoms and the symbols X.sup.1 are equal or different and represent a hydrogen atom, a group of the general formula --NR.sup.2.sub.2 (where R.sup.2 is a hydrocarbon residue with 1-10 carbon atoms), a group of the general formula --OR.sup.3 (where R.sup.3 is a hydrocarbon residue with 1-20 carbon atoms or a group of the general formula --Si(R.sup.4).sub.3, where the symbols R.sup.4 are equal or different and represent a hydrogen atom and/or a hydrocarbon residue with 1-20 carbon atoms), and 0

7. 发明授权

US4332697A Process for the preparation of catalyst component for the polymerization of .alpha.-olefins 失效
标题翻译：制备用于α-烯烃聚合的催化剂组分的方法
公开(公告)号：US4332697A
公开(公告)日：1982-06-01
申请号：US216766
申请日：1980-12-15
申请人： Kouhei Kimura , Hiroyasu Ohba , Atsushi Murai
发明人： Kouhei Kimura , Hiroyasu Ohba , Atsushi Murai
IPC分类号： C08F4/02 , C08F4/46 , C08F4/50 , C08F4/64 , C08F4/652 , C08F10/00
CPC分类号： C08F4/022 , C08F10/00
摘要： Disclosed is a process for the preparation of the former catalyst component of a catalyst for the polymerization of .alpha.-olefins composed of a titanium-based catalyst component and an organo aluminium compound. According to the above process, a magnesium halide is copulverized with aluminium isopropoxide to form a first copulverization product, to which an electron donor compound is added for copulverization to form a second copulverization product, and the second copulverization product is brought into contact with a titanium halide followed by washing with an inert organic solvent.In the polymerization of .alpha.-olefins by use of the former catalyst component as above, both polymerization activity per unit weight of the catalyst component and yield of stereoregular polymers are remarkably increased.
摘要翻译：公开了一种制备用于聚合由钛基催化剂组分和有机铝化合物组成的α-烯烃的催化剂的前催化剂组分的方法。根据上述方法，将卤化镁与异丙醇铝共烧以形成第一共混物，向其中加入电子给体化合物以共混以形成第二共沉积产物，并将第二共沉积产物与钛卤化物，然后用惰性有机溶剂洗涤。在通过使用如上所述的前述催化剂组分的α-烯烃的聚合中，催化剂组分的每单位重量的聚合活性和立体规则聚合物的产率都显着增加。

8. 发明授权

US4037041A Process for the polymerization of alpha-olefins, catalyst employed in such a process and method for the preparation thereof 失效
标题翻译： α-烯烃聚合方法，用于该方法的催化剂及其制备方法
公开(公告)号：US4037041A
公开(公告)日：1977-07-19
申请号：US562800
申请日：1975-03-27
申请人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
发明人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
IPC分类号： C08F4/00 , C08F4/02 , C08F4/20 , C08F4/26 , C08F4/60 , C08F4/64 , C08F4/652 , C08F110/00 , C08F110/02 , C08F10/02
CPC分类号： C08F110/00
摘要： Ethylene is polymerized through the use of an improved catalyst system consisting of a carrier such as neodymium oxide having a high superficial area, an aluminum compound such as triisobutylaluminum and the combination product of titanium trichloride and an isostructural chloride of another transition metal prepared by impregnating the carrier with a solution of a carbonyl derivative of the other transition metal, refluxing the impregnated carrier with titanium tetrachloride until that carbonyl derivative is converted to the chloride of the other transition metal, and then removing the excess of titanium tetrachloride.
摘要翻译：乙烯通过使用由载体如高表面积的氧化钕，三异丁基铝等铝化合物和三氯化钛的组合产物和另一种过渡金属的结构氯化物组成的改进的催化剂体系进行聚合，所述过渡金属通过浸渍载体与其他过渡金属的羰基衍生物的溶液，使浸渍的载体与四氯化钛回流，直到羰基衍生物转化为其它过渡金属的氯化物，然后除去过量的四氯化钛。

9. 发明授权

US07897706B2 Polymerization process using a supported, treated catalyst system 有权
标题翻译：使用负载型处理催化剂体系的聚合方法
公开(公告)号：US07897706B2
公开(公告)日：2011-03-01
申请号：US12215645
申请日：2008-06-27
申请人： Sun-Chueh Kao
发明人： Sun-Chueh Kao
IPC分类号： C08F4/44 , C08F4/613 , C08F4/652 , C08F4/6592
CPC分类号： B01J31/1805 , B01J31/0214 , B01J31/128 , B01J31/143 , B01J31/1616 , B01J31/2295 , B01J31/38 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F110/02 , Y02P20/588 , C08F4/65904 , C08F2500/04
摘要： The present invention relates to a supported, treated catalyst system and its use in a process for polymerizing olefin(s). More particularly, it provides a supported, treated catalyst system produced by a process comprising the steps of: (a) forming a supported bimetallic catalyst system comprising a first catalyst component and a metallocene catalyst compound; and (b) contacting the supported bimetallic catalyst system of (a) with at least one methylalumoxane-activatable compound.
摘要翻译：本发明涉及负载型处理的催化剂体系及其在烯烃聚合方法中的应用。更具体地，它提供了一种通过包括以下步骤的方法制备的负载型处理的催化剂体系：（a）形成包含第一催化剂组分和茂金属催化剂化合物的负载双金属催化剂体系; 和（b）使负载的（a）双金属催化剂体系与至少一种甲基铝可激活化合物接触。

10. 发明申请

US20050054799A1 Bimodal polyolefin production process and films therefrom 审中-公开
公开(公告)号：US20050054799A1
公开(公告)日：2005-03-10
申请号：US10945502
申请日：2004-09-20
申请人： Chi-I Kuo , Laughlin McCullough , Pradeep Shirodkar , Fred Ehrman , Porter Shannon , Robert Santana , Steven Ackerman , Daniel O'Neil
发明人： Chi-I Kuo , Laughlin McCullough , Pradeep Shirodkar , Fred Ehrman , Porter Shannon , Robert Santana , Steven Ackerman , Daniel O'Neil
IPC分类号： C08J5/18 , C08F2/34 , C08F4/02 , C08F4/44 , C08F4/60 , C08F4/642 , C08F4/646 , C08F4/652 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , C08F4/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , Y10S526/943 , C08F4/65904 , C08F2/34 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/18 , C08F2500/26
摘要： A process of producing a bimodal polyolefin composition is described, which includes in one embodiment contacting monomers with a supported bimetallic catalyst composition for a time sufficient to form a bimodal polyolefin composition that includes a high molecular weight polyolefin component and a low molecular weight polyolefin component; wherein the supported bimetallic catalyst includes a first catalyst component that is preferably non-metallocene, and a second catalyst component that includes a metallocene catalyst compound having at least one fluoride or fluorine containing leaving group, wherein the bimetallic catalyst is supported by an enhanced silica, dehydrated at a temperature of 800° C. or more in one embodiment.

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