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    • 1. 发明授权
    • Branched, substantially unsaturated fatty alcohol sulfates
    • 分支的,基本不饱和的脂肪醇硫酸盐
    • US06723867B1
    • 2004-04-20
    • US10049960
    • 2002-06-19
    • Norbert HuebnerHans-Christian RathsAlfred Westfechtel
    • Norbert HuebnerHans-Christian RathsAlfred Westfechtel
    • C07C30514
    • C11D1/146A61K8/463A61K47/20A61Q5/02A61Q19/00A61Q19/10C07C305/14
    • Branched, substantially unsaturated fatty alcohol sulfates are produced by a process which comprises the steps of: (a) dimerizing unsaturated C16-22 fatty acid to form a dimer fraction and a monomer fraction comprised of branched, substantially unsaturated fatty acids and straight chain saturated fatty acids, (b) removing the monomer fraction from the dimerization step, (c) converting the branched, substantially unsaturated fatty acids from step (b) into the corresponding fatty acid methyl esters, (d) hydrogenating the branched, substantially unsaturated fatty acid methyl esters with the double bonds intact to form the corresponding branched, substantially unsaturated fatty alcohols and (e) sulfating and neutralizing the branched, substantially unsaturated fatty alcohols. The fatty alcohol sulfates thus produced exhibit improved performance properties and greater oxidative stability than standard unsaturated fatty alcohol sulfates.
    • 分支的,基本上不饱和的脂肪醇硫酸盐通过包括以下步骤的方法制备:(a)使不饱和C16-22脂肪酸二聚以形成二聚体部分和由支链,基本上不饱和的脂肪酸和直链饱和脂肪 酸,(b)从二聚步骤中除去单体部分,(c)将来自步骤(b)的支化基本上不饱和的脂肪酸转化成相应的脂肪酸甲酯,(d)氢化支链的,基本上不饱和的脂肪酸甲基 具有双键的酯完整以形成相应的支链,基本上不饱和的脂肪醇,和(e)硫酸化和中和支化的,基本不饱和的脂肪醇。 如此生产的脂肪醇硫酸盐比标准不饱和脂肪醇硫酸盐显示出改进的性能特性和更大的氧化稳定性。