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    • 6. 发明申请
    • MAGNETICALLY INSENSITIVE, HIGHLY HARD AND CONSTANT-MODULUS ALLOY, AND ITS PRODUCTION METHOD, AS WELL AS HAIR SPRING, MECHANICAL DRIVING APPARATUS AND WATCH AND CLOCK
    • 磁性敏感,高硬度和恒定的模量合金及其生产方法,如毛发弹簧,机械驱动装置和手表和时钟
    • US20110286312A1
    • 2011-11-24
    • US13125831
    • 2009-11-16
    • Yuetsu MurakamiKoichiro JujoOsamu TakahashiJun TsuneyoshiRyo SugawaraTakeshi Takano
    • Yuetsu MurakamiKoichiro JujoOsamu TakahashiJun TsuneyoshiRyo SugawaraTakeshi Takano
    • G04B17/06C22F1/16C22C30/00
    • C22C38/52C21D6/004C21D6/007C21D8/0236C21D8/0242C21D8/0273C21D8/06C21D8/12C21D9/0075C21D9/02C22C19/07C22C30/00C22C38/02C22C38/04C22C38/06C22C38/44C22F1/00C22F1/10G04B17/066G04B43/007
    • [Task] A constant-modulus alloy, which has a low saturation magnetic flux density to provide weakly magnetic properties, a high Young's modulus, a low temperature coefficient of Young's modulus, and high hardness, is provided. A hairspring, a mechanical driving apparatus and a watch and clock, in which the alloy is used, are provided.[Means for Solution]The alloy consists essentially of, by atomic weight ratio, 20 to 40% Co and 7 to 22% Ni, with the total of Co and Ni being 42.0 to 49.5%, 5 to 13% Cr and 1 to 6% Mo, with the total of Cr and Mo being 13.5 to 16.0%, and with the balance being essentially Fe (with the proviso that Fe is present in an amount of 37% or more) and inevitable impurities. The alloy is heated to a temperature of 1100 degrees C. or higher and lower than the melting point, followed by cooling. The alloy is subsequently subjected to repeated wiredrawing and intermediate annealing at 800 to 950 degrees C., thereby forming a wire at a working ratio of 90% or more. The resultant wire has a fiber structure having a fiber axis. The wire is subsequently cold rolled at a rolling reduction of 20% or more, thereby obtaining a sheet, followed by heating the sheet at a temperature of 580 to 700 degrees C. The obtained magnetically insensitive, highly hard, constant modulus alloy has a {110} texture. 2500 to 3500 G of saturation flux density, (−5˜+5)×10−5 degrees C−1 of temperature coefficient of Young's modulus as measured at 0 to 40 degrees C., and 350 to 550 of Vickers hardness
    • [任务]提供一种具有低饱和磁通密度以提供弱磁性能,高杨氏模量,低温系数杨氏模量和高硬度的恒模量合金。 提供了使用合金的游丝,机械驱动装置和钟表。 [解决方案]合金基本上由原子量比为20〜40%的Co和7〜22%的Ni,Co和Ni的合计为42.0〜49.5%,Cr为5〜13%,1〜6 %Mo,Cr和Mo的总量为13.5〜16.0%,余量基本上为Fe(条件是Fe的含量为37%以上)和不可避免的杂质。 将合金加热至1100℃以上且低于熔点,然后冷却。 随后在800-950℃下对该合金进行重复拉丝和中间退火,从而以90%以上的加工率形成线。 所得到的线具有具有<111>纤维轴的纤维结构。 然后将线材以20%以上的压下率进行冷轧,得到片材,然后在580〜700℃的温度下加热片材。得到的磁性不敏感,高硬度,恒定模量的合金具有{ 110} <111>纹理。 在0至40摄氏度测量的2500至3500G的饱和磁通密度,(-5〜+ 5)×10-5摄氏度的杨氏模量的温度系数,以及维氏硬度的350至550