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    • 5. 发明授权
    • Block copolymer and method of producing the same
    • 嵌段共聚物及其制造方法
    • US5342895A
    • 1994-08-30
    • US11845
    • 1993-01-28
    • Toshio TagamiYoshio ImaiMasaaki KakimotoOsamu KiyoharaHitoshi Narushima
    • Toshio TagamiYoshio ImaiMasaaki KakimotoOsamu KiyoharaHitoshi Narushima
    • C08G81/02C08L77/00
    • C08G81/028
    • Disclosed is a polyamide/polybutadiene/acrylonitrile block copolymer useful in a wide variety of applications, such as an adhesive film, which comprises a polycondensate comprising a polybutadiene/acrylonitrile copolymer having a carboxyl group at each terminal thereof and a polyamide having an aminoaryl group at each terminal, and which is represented by general formula (I) ##STR1## wherein R is a divalent organic group, Ar is a divalent aromatic group, x, y, z, m and n each: represent mean degree of polymerization and are integers in the ranges of x=3 to 7, y=1 to 4, z=5 to 15, n=1 to 30, and nm=2 to 20, respectively. Also, disclosed is a method of producing the polyamide/polybutadiene based block copolymer by polycondensing an aromatic diamine with an aromatic dicarboxylic acid to form a polyamide having an aminoaryl group at each terminal thereof, and then polycondensing it with a poiybutadiene/acrylonitrile copolymer having a carboxyl group at each terminal thereof, preferably in the presence of an aromatic phosphite and a pyridine derivative.
    • 公开了可用于各种应用的聚酰胺/聚丁二烯/丙烯腈嵌段共聚物,例如粘合剂膜,其包含包含其末端具有羧基的聚丁二烯/丙烯腈共聚物和在其末端具有氨基芳基的聚酰胺的缩聚物 其中R为二价有机基团,Ar为二价芳族基团,x,y,z,m和n各自表示平均值,表示通式(I) 聚合度为x = 3〜7,y = 1〜4,z = 5〜15,n = 1〜30,nm = 2〜20的整数。 此外,还公开了通过使芳族二胺与芳族二羧酸缩聚以在其每个末端形成具有氨基芳基的聚酰胺,然后与聚丁二烯/丙烯腈共聚物进行缩聚来制造聚酰胺/聚丁二烯系嵌段共聚物的方法,所述聚丁二烯/ 羧基,优选在芳香族亚磷酸酯和吡啶衍生物的存在下进行。