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1. 发明授权

US4195136A Impact-resistant styrene resin composition 失效
标题翻译：耐冲击苯乙烯树脂组合物
公开(公告)号：US4195136A
公开(公告)日：1980-03-25
申请号：US945320
申请日：1978-09-25
申请人： Yasushi Sato , Toshio Ibaragi , Masanobu Ishihara , Makoto Honda
发明人： Yasushi Sato , Toshio Ibaragi , Masanobu Ishihara , Makoto Honda
IPC分类号： C08L53/02 , C08L51/04
CPC分类号： C08L53/02
摘要： The disclosure relates to a resin composition comprising (A) 75-98 parts by weight of a block copolymer mixture of vinyl aromatic hydrocarbon and conjugated diolefin and (B) 25-2 parts by weight of an impact-resistant styrene resin, characterized in that said copolymer mixture (A) is a mixture of a copolymer (1) and a copolymer (2) (the weight ratio of the copolymer (1) to the copolymer (2) is 1.5 or more), the copolymer (1) being a copolymer which contains 55-85% by weight of vinyl aromatic hydrocarbon, consists of at least one vinyl aromatic hydrocarbon polymer block and at least one conjugated diene polymer block, and has a number average molecular weight of about 10,000 to about 500,000 and the copolymer (2) being a homopolymer of vinyl aromatic hydrocarbon or a copolymer which consists of at least one vinyl aromatic hydrocarbon polymer block and at least one conjugated diene polymer block, the vinyl aromatic hydrocarbon content of said copolymer being 75% by weight or more and at least 5% by weight higher than that of the copolymer (1), said homopolymer or copolymer having a number average molecular weight of about 500 to about 130,000, both of said copolymer (1) and said copolymer (2) being obtained by polymerization in an inert organic solvent with an organolithium compound as a catalyst; and that said impact-resistant styrene resin (B) is a polymer obtained by graft-polymerizing 3-12% by weight of a rubbery conjugated diene polymer and 97-88% by weight of a vinyl aromatic hydrocarbon. The said resin composition is far superior to conventional resin compositions of similar type in balance between impact resistance and transparency.
摘要翻译：本公开涉及一种树脂组合物，其包含（A）75-98重量份的乙烯基芳族烃和共轭二烯烃的嵌段共聚物混合物和（B）25-2重量份的耐冲击苯乙烯树脂，其特征在于所述共聚物混合物（A）是共聚物（1）和共聚物（2）的混合物（共聚物（1）与共聚物（2）的重量比为1.5以上），共聚物（1）为共聚物，其含有55-85重量％的乙烯基芳烃，由至少一个乙烯基芳族烃聚合物嵌段和至少一个共轭二烯聚合物嵌段组成，数均分子量为约10,000至约500,000，共聚物（ 2）作为乙烯基芳族烃的均聚物或由至少一种乙烯基芳族烃聚合物嵌段和至少一种共轭二烯聚合物嵌段组成的共聚物，所述共聚物的乙烯基芳烃含量为75重量％以上，所述共聚物（1）和所述共聚物（2）的所述均聚物或共聚物的数均分子量为约500至约130,000，所述共聚物（1）和所述共聚物（2）的至少5重量％通过聚合惰性有机溶剂，有机锂化合物作为催化剂; 并且所述耐冲击苯乙烯树脂（B）是通过将3-12重量％的橡胶状共轭二烯聚合物和97-88重量％的乙烯基芳族烃接枝聚合而获得的聚合物。所述树脂组合物远优于在耐冲击性和透明度之间平衡的类似类型的常规树脂组合物。

2. 发明授权

US4413098A Isoprene-butadiene copolymer rubber having improved processing properties 失效
标题翻译：异戊二烯 - 丁二烯共聚物橡胶具有改进的加工性能
公开(公告)号：US4413098A
公开(公告)日：1983-11-01
申请号：US302787
申请日：1981-09-16
申请人： Yasuo Hattori , Takeshi Ikematu , Toshio Ibaragi , Makoto Honda
发明人： Yasuo Hattori , Takeshi Ikematu , Toshio Ibaragi , Makoto Honda
IPC分类号： C08F4/00 , C08F4/42 , C08F4/48 , C08F4/54 , C08F36/00 , C08F36/04 , C08F236/00 , C08F236/04 , C08F236/06 , C08F297/00 , C08F297/02 , C08F297/04 , C08F236/08 , C08F236/10
CPC分类号： C08F236/06
摘要： An isoprene-butadiene copolymer rubber having improved processing properties which comprises a microstructure of the butadiene portion having from 70% to 90% of trans-1,4 linkage and from 2% to 8% of vinyl linkage, an isoprene content of from 3 to 25 wt %, and a styrene content of from 0 to 30 wt %, said copolymer rubber having a Mooney Viscosity of from 30 to 150, and a molecular weight distribution, Mw/Mn of from 1.2 to 3.5, said rubber, in the unelongated state, not showing a melting point measured by the differential calorimeter analysis method. The copolymer rubber of the present invention can be used for tires, for example, a tread and a carcass or for other rubber uses.
摘要翻译：具有改进加工性能的异戊二烯 - 丁二烯共聚物橡胶，其包含丁二烯部分的显微组织，其具有70％至90％的反式-1,4键和2％至8％的乙烯基键，异戊二烯含量为3至 25重量％，苯乙烯含量为0〜30重量％，所述共聚物橡胶的门尼粘度为30〜150，分子量分布Mw / Mn为1.2〜3.5，所述橡胶在未连续状态，不显示通过差示热量计分析方法测量的熔点。本发明的共聚物橡胶可用于轮胎，例如胎面和胎体，或用于其它橡胶用途。

3. 发明授权

US4424322A Process for producing polymers or copolymers of conjugated dienes 失效
标题翻译：制备共轭二烯的聚合物或共聚物的方法
公开(公告)号：US4424322A
公开(公告)日：1984-01-03
申请号：US305685
申请日：1981-09-25
申请人： Yasuo Hattori , Takeshi Ikematu , Toshio Ibaragi , Makoto Honda
发明人： Yasuo Hattori , Takeshi Ikematu , Toshio Ibaragi , Makoto Honda
IPC分类号： C08F4/00 , C08F4/42 , C08F4/44 , C08F36/00 , C08F36/04 , C08F236/00 , C08F236/04 , C08F236/10 , C08F4/10
CPC分类号： C08F36/04
摘要： A process for producing polymers of a conjugated diene, copolymers of a conjugated diene and another conjugated diene, or copolymers of conjugated diene and a vinyl aromatic hydrocarbon, which comprises polymerizing the corresponding monomers in the presence of a complex initiator consisting of components (a) and (b) described below, or (a) and (b) together with one or more components selected from components (c) and (d); (a) An organic compound of barium, strontium or calcium; (b) An organolithium-beryllium compound or an organolithiummagnesium compound; (c) An organolithium compound, an organoberyllium compound or an organomagnesium compound; and (d) An organoaluminum compound or an organozinc compound. The polymers of a conjugated diene containing relatively high trans-1,4 linkage, or the copolymers of a conjugated diene and a vinyl aromatic compound highly randomized and having high bound styrene and high trans-1,4 linkage can be produced at good yields.
摘要翻译：共轭二烯的共聚物，共轭二烯与共轭二烯的共聚物或共轭二烯与乙烯基芳香烃的共聚物的制造方法，其包括在由组分（a）组成的复合引发剂存在下聚合相应的单体，和（b），或（a）和（b）以及选自组分（c）和（d）的一种或多种组分; （a）钡，锶或钙的有机化合物; （b）有机锂 - 铍化合物或有机锂镁化合物; （c）有机锂化合物，有机溴化合物或有机镁化合物; 和（d）有机铝化合物或有机锌化合物。含有相对高的反式-1,4键的共轭二烯的聚合物，或共轭二烯和高度随机化并具有高结合苯乙烯和高反式-1,4-键的乙烯基芳族化合物的共聚物可以以良好的产率制备。

4. 发明授权

US4332858A Multi-layer laminate comprising a modified styrene-butadiene block copolymer 失效
标题翻译：包含改性苯乙烯 - 丁二烯嵌段共聚物的多层层压体
公开(公告)号：US4332858A
公开(公告)日：1982-06-01
申请号：US106943
申请日：1979-12-26
申请人： Akira Saitoh , Akio Yamori , Toshio Ibaragi
发明人： Akira Saitoh , Akio Yamori , Toshio Ibaragi
IPC分类号： B32B27/00 , B32B27/08 , B32B27/30 , C08F8/46 , B32B9/04 , B32B27/10
CPC分类号： B32B27/08 , Y10T428/31507 , Y10T428/31645 , Y10T428/3175 , Y10T428/31837 , Y10T428/31917 , Y10T428/31924
摘要： A multi-layer laminate comprising at least one A-B double layer structure, characterized in that said layer A is a layer comprising at least one material selected from the group consisting of olefin polymers, polyamide polymers, acrylate polymers, polyether polymers, polycarbonate polymers, polyurethane polymers, vinylidene chloride polymers, thermosetting resins, vulcanized rubbers, glass and papers and said layer B is a layer comprising mainly a modified block copolymer in which an unsaturated carboxylic acid or its derivative is grafted on a styrene-butadiene block copolymer. Said laminate is excellent in interlaminar adhesion, i.e. peeling strength.
摘要翻译：一种包含至少一个AB双层结构的多层层压体，其特征在于，所述层A是包含至少一种选自烯烃聚合物，聚酰胺聚合物，丙烯酸酯聚合物，聚醚聚合物，聚碳酸酯聚合物，聚氨酯聚合物，偏二氯乙烯聚合物，热固性树脂，硫化橡胶，玻璃和纸，并且所述层B是主要包含不饱和羧酸或其衍生物接枝在苯乙烯 - 丁二烯嵌段共聚物上的改性嵌段共聚物的层。所述层压材料具有优异的层间粘合性，即剥离强度。

5. 发明授权

US4183877A High-impact polystyrene composition and production thereof 失效
标题翻译：高抗冲聚苯乙烯组合物及其制备
公开(公告)号：US4183877A
公开(公告)日：1980-01-15
申请号：US892848
申请日：1978-04-03
申请人： Toshio Ibaragi , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa
发明人： Toshio Ibaragi , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa
IPC分类号： C08F12/08 , C08F279/02
CPC分类号： C08F12/08 , C08F279/02
摘要： High-impact polystyrene composition is produced by radical polymerization, e.g. bulk or bulk-suspension polymerization, of styrene having dissolved therein 2 to 20% by weight of one or more polybutadienes prepared by solution polymerization using an organic lithium compound as catalyst, said polybutadienes having (1) 1,2-vinyl content of more than 15 to 35% and cis-1,4 content of 20 to 85%, and (2) Mooney viscosity of 25 to 85, 5% styrene solution viscosity at 25.degree. C. being 50 to 200 cps and between 1.5 and 3.0 of the Mooney viscosity.
摘要翻译：高抗冲聚苯乙烯组合物通过自由基聚合制备，例如其中溶解有苯乙烯的2〜20重量％的一种或多种通过使用有机锂化合物作为催化剂的溶液聚合制备的聚丁二烯的所述聚丁二烯具有（1）1,2-乙烯基含量大于 15〜35％，顺式-1,4-含量为20〜85％，（2）门尼粘度为25〜85,55℃时苯乙烯溶液粘度为5〜200cps，1.5〜3.0 门尼粘度。

6. 发明授权

US4304881A Alkenyl aromatic resin composition having an excellent impact strength 失效
标题翻译：具有优异冲击强度的烯基芳族树脂组合物
公开(公告)号：US4304881A
公开(公告)日：1981-12-08
申请号：US98555
申请日：1979-11-29
申请人： Akira Aoki , Toshinori Shiraki , Toshio Ibaragi
发明人： Akira Aoki , Toshinori Shiraki , Toshio Ibaragi
IPC分类号： C08L51/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/10 , C08L51/02 , C08L51/04 , C08L53/02 , C08L77/00 , C08L101/00
CPC分类号： C08L25/10 , C08L51/04
摘要： An alkenyl aromatic resin composition having an excellent impact strength, which comprises (I) 100 parts by weight of a rubber-modified alkenyl aromatic resin containing from 2 to 35 wt. % of conjugated diolefin components, or a resinous mixture containing at least a component of the resin thereof; and (II) 1 to 50 parts by weight of a random segment copolymer containing at least a Segment A which is a random copolymer of a conjugated diolefin and a vinyl-substituted aromatic compound with a weight ratio being ranging from 30:70 to 5:95 and at least a Segment B, which is a conjugated diolefin polymer or a random copolymer of a conjugated diolefin and a vinyl-substituted aromatic compound with a weight ratio being ranging from 100:0 to 75:25, the random segment copolymer being characterized by containing;(a) at least 10 wt. % of Segment A based on the total random segment copolymer,(b) at least 20 wt. % of Segment B based on the total random segment copolymer, and(c) at least 60 wt. % of a sum of Segment A and Segment B based on the total random segment copolymer.The resin composition of the present invention can be used to make a variety of useful products, such as film, foam, injection moldings and compression moldings.
摘要翻译：具有优异的冲击强度的烯基芳族树脂组合物，其包含（I）100重量份含有2-35重量％的橡胶改性的链烯基芳族树脂。％的共轭二烯烃组分，或至少含有其树脂组分的树脂混合物; 和（II）1至50重量份的至少含有共轭二烯烃和乙烯基取代的芳族化合物的无规共聚物的段A的重量比为30:70至5:1的无规链段共聚物。 95和至少一个段B，其是共轭二烯烃聚合物或共轭二烯烃和乙烯基取代的芳族化合物的无规共聚物，其重量比范围为100:0至75:25，所述无规链段共聚物的特征在于通过包含; （a）至少10wt。基于总随机链段共聚物的段A的％，（b）至少20wt。基于总随机链段共聚物的段B的％，和（c）至少60wt。基于总随机段共聚物的段A和段B的总和的百分比。本发明的树脂组合物可用于制造各种有用的产品，例如薄膜，泡沫，注塑和压缩模制品。

7. 发明授权

US4292414A Process for the preparation of modified block copolymers 失效
标题翻译：改性嵌段共聚物的制备方法
公开(公告)号：US4292414A
公开(公告)日：1981-09-29
申请号：US89237
申请日：1979-10-29
申请人： Akira Saito , Akio Yamori , Toshio Ibaragi
发明人： Akira Saito , Akio Yamori , Toshio Ibaragi
IPC分类号： C08F8/46 , C08L53/02
CPC分类号： C08F8/46
摘要： A process for preparing a modified block copolymer by graft-reacting at least one maleic acid compound with an aromatic vinyl compound/conjugated diene compound block copolymer containing at least one polymer block mainly composed of a conjugated diene compound and at least one polymer block mainly composed of an aromatic vinyl compound, the aromatic vinyl compound/conjugated diene compound weight ratio being within the range of 5/95 to 97/3, characterized in that said graft-reaction is carried out under conditions wherein the generation of radicals can be substantially inhibited. According to this process, it is possible to prevent gelation of the product in the graft-reaction, and the modified block copolymer obtained has excellent appearance characteristics, mechanical properties, and transparency.
摘要翻译：通过将至少一种马来酸化合物与含有至少一个主要由共轭二烯化合物组成的聚合物嵌段的芳族乙烯基化合物/共轭二烯化合物嵌段共聚物接枝反应制备改性嵌段共聚物的方法和至少一个主要由的芳香族乙烯基化合物，芳香族乙烯基化合物/共轭二烯化合物的重量比在5/95〜97/3的范围内，其特征在于，所述接枝反应在基本上被抑制的条件下进行。根据该方法，可以防止接枝反应中的产物凝胶化，得到的改性嵌段共聚物具有优异的外观特性，机械性能，透明性。

8. 发明授权

US3980625A Method for producing novel rubbery polymers from diene monomers 失效
标题翻译：从二烯单体生产新型橡胶聚合物的方法
公开(公告)号：US3980625A
公开(公告)日：1976-09-14
申请号：US433605
申请日：1974-01-15
申请人： Kuniaki Sakamoto , Toshio Ibaragi , Osamu Suzuki
发明人： Kuniaki Sakamoto , Toshio Ibaragi , Osamu Suzuki
IPC分类号： C08F36/04 , C08D1/20 , C08D3/08
CPC分类号： C08F36/04
摘要： Novel rubbery polymer having a uniform and broad molecular weight distribution, a ratio of weight average molecular weight to number average molecular weight of 3 or more, a content of monovinyl aromatic compound of 0 to 30% by weight, a bonding manner of conjugated diolefin of 60% or more of 1,4-linkage and improved processability and physical properties can be obtained by circulating living polymer in the polymerization or copolymerization of conjugated diolefins or copolymerization of conjugated diolefin and monovinyl aromatic hydrocarbon carried out with a lithium-based catalyst.
摘要翻译：具有均匀且宽分子量分布的新型橡胶状聚合物，重均分子量与数均分子量的比例为3以上，单乙烯基芳香族化合物的含量为0〜30重量％，共轭二烯的结合方式通过在共轭二烯烃的聚合或共聚中循环活性聚合物或用锂基催化剂进行共轭二烯烃和单乙烯基芳族烃的共聚，可以获得60重量％以上的1,4-键和改善的加工性能和物理性能。

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