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1. 发明授权

US07329697B2 Elastomeric compositions 失效
标题翻译：弹性组合物
公开(公告)号：US07329697B2
公开(公告)日：2008-02-12
申请号：US10494993
申请日：2002-12-09
申请人： Walter Harvey Waddell , David Yen-Lung Chung
发明人： Walter Harvey Waddell , David Yen-Lung Chung
IPC分类号： C08L3/00
CPC分类号： C08F8/20 , C08L23/22 , C08L53/02 , C08L2205/02 , C08L2312/00 , C08F210/12 , C08L2666/04
摘要： The present invention includes compositions suitable for tire treads or sidewalls and other articles where abrasion resistance and flexibility are desirable. The invention includes a tire tread or sidewall made by combining a filler; a sulfur cure system; optionally at least one secondary rubber; and at least one halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin derived units, and p-alkylstyrene derived units. Examples of suitable fillers include carbon black, silica, and combinations thereof. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer. Examples of suitable initiators include cumyl compounds and or halogenated organic compounds, especially secondary or tertiary halogenated compounds such as, for example, t-butylchloride, 2-acetyl-2-phenylpropane (cumyl acetate), 2-methoxy 2-phenyl propane (cumylmethyl-ether), 1,4-di(2-methoxy-2-propyl)benzene (di(cumylmethyl ether)); the cumyl halides, particularly the chlorides, such as, for example 2-chloro-2-phenylpropane, cumyl chloride (1-chloro-1-methylethyl)benzene), 1,4-di(2-chloro-2-propyl)benzene (di(cumylchloride)), and 1,3,5-tri(2-chloro-2-propyl)benzene (tri(cumylchloride)); the aliphatic halides, particularly the chlorides, such as, for example, 2-chloro-2,4,4-trimethylpentane (TMPCl), and 2-bromo-2,4,4-trimethylpentane (TMPBr).
摘要翻译：本发明包括适用于轮胎胎面或侧壁的组合物以及其中需要耐磨性和柔韧性的其它制品。本发明包括通过组合填料制成的轮胎胎面或侧壁; 硫磺硫化体系; 任选地至少一种次级橡胶; 和至少一种C 4至C 8 O 8异构烯烃衍生单元，C 4至C 14多烯烃的卤化三元共聚物衍生单元和对烷基苯乙烯衍生单元。合适的填料的实例包括炭黑，二氧化硅及其组合。本发明还包括一种制备弹性体三元共聚物组合物的方法，其包括在稀释剂C 4〜C 8 O 8异构烯烃单体，C 4〜 C 14 O 12烯烃单体和对烷基苯乙烯单体在路易斯酸和至少一种引发剂的存在下反应以产生三元共聚物。合适的引发剂的实例包括枯基化合物和/或卤代有机化合物，特别是仲或叔卤代化合物，例如叔丁基氯，2-乙酰基-2-苯基丙烷（乙酸异丙酯），2-甲氧基-2-苯基丙烷 - 醚），1,4-二（2-甲氧基-2-丙基）苯（二（枯基甲基醚））; 枯基卤化物，特别是氯化物，例如2-氯-2-苯基丙烷，枯基氯（1-氯-1-甲基乙基）苯），1,4-二（2-氯-2-丙基）苯（二（氯仿））和1,3,5-三（2-氯-2-丙基）苯（三（氯仿））。脂族卤化物，特别是氯化物，例如2-氯-2,4,4-三甲基戊烷（TMPCl）和2-溴-2,4,4-三甲基戊烷（TMPBr）。

2. 发明授权

US07960454B2 Processing aids for elastomeric compositions 有权
标题翻译：弹性体组合物的加工助剂
公开(公告)号：US07960454B2
公开(公告)日：2011-06-14
申请号：US12093786
申请日：2005-12-16
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey , Dirk Frans Rouckhout
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey , Dirk Frans Rouckhout
IPC分类号： D06M15/11 , E01C7/26 , C08K3/26 , C08K3/34 , C04B28/26 , C04B26/06 , C08J3/22 , C08L37/00 , C08L35/02 , C08L27/00 , C08L27/04
CPC分类号： C08L21/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , B60C5/02 , C08K3/04 , C08K5/01 , C08L15/00 , C08L19/006 , C08L23/26 , C08L23/283 , C08L23/36 , C08L51/06 , C08L2666/06 , C08L2666/08 , C08L2666/24 , C08L2666/02
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包含至少一种具有至少一个酸酐基的官能化聚合物。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

3. 发明授权

US07241831B2 Elastomeric compositions 失效
标题翻译：弹性组合物
公开(公告)号：US07241831B2
公开(公告)日：2007-07-10
申请号：US10494994
申请日：2002-12-09
申请人： Walter Harvey Waddell , David Yen-Lung Chung
发明人： Walter Harvey Waddell , David Yen-Lung Chung
IPC分类号： C08L27/00
CPC分类号： C08F8/20 , C08K3/013 , C08L21/00 , C08L23/22 , C08L23/283 , C08L53/02 , C08L2205/02 , C08L2312/00 , C08F210/12
摘要： The present invention includes compositions suitable for air barriers such as innerliners where adhesion to tire carcass materials (e.g., SBR) and flexibility are desirable, as well as low air permeability. The invention includes a tire innerliner made by combining a filler; a sulfur cure system; optionally at least one secondary rubber; and at least one halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin derived units, and p-alkylstyrene derived units. Examples of suitable fillers include modified carbon black, carbon black, silica, exfoliated clays, and combinations thereof. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer. Examples of suitable initiators include cumyl compounds and or halogenated organic compounds, especially secondary or tertiary halogenated compounds such as, for example, t-butylchloride, 2-acetyl-2-phenylpropane (cumyl acetate), 2-methoxy-2-phenyl propane (cumylmethyl-ether), 1,4-di(2-methoxy-2-propyl)benzene (di(cumylmethyl ether)); the cumyl halides, particularly the chlorides, such as, for example 2-chloro-2-phenylpropane, cumyl chloride (1-chloro-1-methylethyl)benzene), 1,4-di(2-chloro-2-propyl)benzene (di(cumylchloride)), and 1,3,5-tri(2-chloro-2-propyl)benzene (tri(cumylchloride)); the aliphatic halides, particularly the chlorides, such as, for example, 2-chloro-2,4,4-trimethylpentane (TMPCl), and 2-bromo-2,4,4-trimethylpentane (TMPBr).
摘要翻译：本发明包括适用于空气屏障的组合物，例如其中对轮胎胎体材料（例如SBR）的粘合性和柔性是理想的，以及低的透气性的内衬。本发明包括通过组合填料制成的轮胎内衬; 硫磺硫化体系; 任选地至少一种次级橡胶; 和至少一种C 4至C 8 O 8异构烯烃衍生单元，C 4至C 14多烯烃的卤化三元共聚物衍生单元和对烷基苯乙烯衍生单元。合适的填料的实例包括改性炭黑，炭黑，二氧化硅，剥离粘土及其组合。本发明还包括一种制备弹性体三元共聚物组合物的方法，其包括在稀释剂C 4〜C 8 O 8异构烯烃单体，C 4〜 C 14 O 12烯烃单体和对烷基苯乙烯单体在路易斯酸和至少一种引发剂的存在下反应以产生三元共聚物。合适的引发剂的实例包括枯基化合物和/或卤代有机化合物，特别是仲或叔卤代化合物，例如叔丁基氯，2-乙酰基-2-苯基丙烷（乙酸异丙酯），2-甲氧基-2-苯基丙烷枯基甲基醚），1,4-二（2-甲氧基-2-丙基）苯（二（枯基甲基醚））; 枯基卤化物，特别是氯化物，例如2-氯-2-苯基丙烷，枯基氯（1-氯-1-甲基乙基）苯），1,4-二（2-氯-2-丙基）苯（二（氯仿））和1,3,5-三（2-氯-2-丙基）苯（三（氯仿））。脂族卤化物，特别是氯化物，例如2-氯-2,4,4-三甲基戊烷（TMPCl）和2-溴-2,4,4-三甲基戊烷（TMPBr）。

4. 发明授权

US08283407B2 Processing aids for elastomeric compositions 有权
标题翻译：弹性体组合物的加工助剂
公开(公告)号：US08283407B2
公开(公告)日：2012-10-09
申请号：US12093798
申请日：2005-12-16
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
IPC分类号： C08L23/36 , C08L9/00
CPC分类号： C08F255/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , C08F8/32 , C08F255/02 , C08F255/023 , C08F255/04 , C08L15/00 , C08L19/006 , C08L21/00 , C08L23/26 , C08L23/283 , C08L23/36 , C08L51/06 , C08L2312/04 , C08L2666/06 , C08L2666/08 , C08L2666/02 , C08L2666/24
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid includes the reaction product of at least one functionalized polymer having at least one anhydride group contacted with at least one polyamine, wherein the at least one polyamine includes at least one primary amine. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包括至少一种具有至少一个与至少一个多胺接触的酸酐基的官能化聚合物的反应产物，其中所述至少一种多胺包括至少一种伯胺。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

5. 发明授权

US08247496B2 Processing aids for elastomeric compositions 失效
标题翻译：弹性体组合物的加工助剂
公开(公告)号：US08247496B2
公开(公告)日：2012-08-21
申请号：US12092057
申请日：2005-12-05
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
IPC分类号： C08L27/00 , C08L27/04 , C08L27/24 , C08F14/14
CPC分类号： C08L23/22 , C08L23/283 , C08L2205/02 , C08L2666/06
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one halogen group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包含至少一种具有至少一个卤素基的官能化聚合物。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

6. 发明授权

US07659355B2 Elastomeric compositions, air barriers, and processes for the making the same 有权
标题翻译：弹性组合物，空气屏障和制造相同的方法
公开(公告)号：US07659355B2
公开(公告)日：2010-02-09
申请号：US11628591
申请日：2005-06-13
申请人： Walter Harvey Waddell , David Yen-Lung Chung
发明人： Walter Harvey Waddell , David Yen-Lung Chung
IPC分类号： C08F36/00 , C08F136/00 , C08F236/00 , C08F2/00 , C08F4/12 , C08L9/00 , A61K8/81 , C08K3/34 , C08K3/18 , C08K3/22
CPC分类号： C08L23/283 , C08L23/22 , C08L2312/00 , Y10S152/16 , C08L2666/06
摘要： The invention relates to novel air barriers made from elastomeric compositions. In particular, the invention relates to novel air barriers such as innerliners, air sleeves, and innertubes made from novel C4 to C7 isoolefin based polymers with new sequence distributions or that are substantially free of long chain branching.
摘要翻译：本发明涉及由弹性体组合物制成的新型空气屏障。特别地，本发明涉及新颖的空气屏障，例如由具有新的序列分布的新型C4至C7异烯烃基聚合物制成的内衬，空气套管和内管，基本上不含长链支化。

7. 发明申请

US20080319119A1 Processing Aids for Elastomeric Compositions 有权
标题翻译：弹性组合物加工助剂
公开(公告)号：US20080319119A1
公开(公告)日：2008-12-25
申请号：US12093798
申请日：2005-12-16
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
IPC分类号： C08K3/04 , C08L67/00 , C08L9/00 , C08L23/04 , C08L23/10 , C08K3/36
CPC分类号： C08F255/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , C08F8/32 , C08F255/02 , C08F255/023 , C08F255/04 , C08L15/00 , C08L19/006 , C08L21/00 , C08L23/26 , C08L23/283 , C08L23/36 , C08L51/06 , C08L2312/04 , C08L2666/06 , C08L2666/08 , C08L2666/02 , C08L2666/24
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid includes the reaction product of at least one functionalized polymer having at least one anhydride group contacted with at least one polyamine, wherein the at least one polyamine includes at least one primary amine. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包括至少一种具有至少一个与至少一个多胺接触的酸酐基的官能化聚合物的反应产物，其中所述至少一种多胺包括至少一种伯胺。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

8. 发明申请

US20080281021A1 Processing Aids for Elastomeric Compositions 有权
标题翻译：弹性组合物加工助剂
公开(公告)号：US20080281021A1
公开(公告)日：2008-11-13
申请号：US12093786
申请日：2005-12-16
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey , Dirk Frans Rouckhout
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey , Dirk Frans Rouckhout
IPC分类号： C08L35/02 , C08L27/10 , C08L27/04 , C08K3/26 , C08K3/34 , C08K3/22
CPC分类号： C08L21/00 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , B60C5/02 , C08K3/04 , C08K5/01 , C08L15/00 , C08L19/006 , C08L23/26 , C08L23/283 , C08L23/36 , C08L51/06 , C08L2666/06 , C08L2666/08 , C08L2666/24 , C08L2666/02
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包含至少一种具有至少一个酸酐基的官能化聚合物。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

9. 发明申请

US20080262130A1 Processing Aids for Elastomeric Compositions 失效
标题翻译：弹性组合物加工助剂
公开(公告)号：US20080262130A1
公开(公告)日：2008-10-23
申请号：US12092057
申请日：2005-12-05
申请人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
发明人： Walter Harvey Waddell , David Yen-Lung Chung , Robert Christopher Napier , Donald Sheley Tracey
IPC分类号： C08K3/00 , C08F14/16 , C08F14/14 , C08K3/26 , C08K3/34 , C08K5/00
CPC分类号： C08L23/22 , C08L23/283 , C08L2205/02 , C08L2666/06
摘要： The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one halogen group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
摘要翻译：本发明提供了生产弹性体组合物的方法，该方法包括使至少一种弹性体与加工助剂接触，其中加工助剂包含至少一种具有至少一个卤素基的官能化聚合物。本发明还提供了用于由上述弹性体组合物制造的用于轮胎的内衬的制品。

10. 发明授权

US08354473B2 Halogenation processes 有权
标题翻译：卤化过程
公开(公告)号：US08354473B2
公开(公告)日：2013-01-15
申请号：US13025888
申请日：2011-02-11
申请人： David Yen-Lung Chung , Michael Francis McDonald , Robert Norman Webb , Richard Dwight Hembree
发明人： David Yen-Lung Chung , Michael Francis McDonald , Robert Norman Webb , Richard Dwight Hembree
IPC分类号： C08F8/22 , C08C19/14
CPC分类号： C08F8/22 , C08F210/12
摘要： The invention discloses improved processes to halogenate polymers. In particular, the invention discloses to improved processes to halogenate polymers made from C4-1012 isoolefins.
摘要翻译：本发明公开了卤化聚合物的改进方法。特别地，本发明公开了改进由C4-1012异烯烃制成的聚合物卤化的方法。

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