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1. 发明授权

US5342895A Block copolymer and method of producing the same 失效
标题翻译：嵌段共聚物及其制造方法
公开(公告)号：US5342895A
公开(公告)日：1994-08-30
申请号：US11845
申请日：1993-01-28
申请人： Toshio Tagami , Yoshio Imai , Masaaki Kakimoto , Osamu Kiyohara , Hitoshi Narushima
发明人： Toshio Tagami , Yoshio Imai , Masaaki Kakimoto , Osamu Kiyohara , Hitoshi Narushima
IPC分类号： C08G81/02 , C08L77/00
CPC分类号： C08G81/028
摘要： Disclosed is a polyamide/polybutadiene/acrylonitrile block copolymer useful in a wide variety of applications, such as an adhesive film, which comprises a polycondensate comprising a polybutadiene/acrylonitrile copolymer having a carboxyl group at each terminal thereof and a polyamide having an aminoaryl group at each terminal, and which is represented by general formula (I) ##STR1## wherein R is a divalent organic group, Ar is a divalent aromatic group, x, y, z, m and n each: represent mean degree of polymerization and are integers in the ranges of x=3 to 7, y=1 to 4, z=5 to 15, n=1 to 30, and nm=2 to 20, respectively. Also, disclosed is a method of producing the polyamide/polybutadiene based block copolymer by polycondensing an aromatic diamine with an aromatic dicarboxylic acid to form a polyamide having an aminoaryl group at each terminal thereof, and then polycondensing it with a poiybutadiene/acrylonitrile copolymer having a carboxyl group at each terminal thereof, preferably in the presence of an aromatic phosphite and a pyridine derivative.
摘要翻译：公开了可用于各种应用的聚酰胺/聚丁二烯/丙烯腈嵌段共聚物，例如粘合剂膜，其包含包含其末端具有羧基的聚丁二烯/丙烯腈共聚物和在其末端具有氨基芳基的聚酰胺的缩聚物其中R为二价有机基团，Ar为二价芳族基团，x，y，z，m和n各自表示平均值，表示通式（I）聚合度为x = 3〜7，y = 1〜4，z = 5〜15，n = 1〜30，nm = 2〜20的整数。此外，还公开了通过使芳族二胺与芳族二羧酸缩聚以在其每个末端形成具有氨基芳基的聚酰胺，然后与聚丁二烯/丙烯腈共聚物进行缩聚来制造聚酰胺/聚丁二烯系嵌段共聚物的方法，所述聚丁二烯/ 羧基，优选在芳香族亚磷酸酯和吡啶衍生物的存在下进行。

2. 发明授权

US4806618A Aromatic polyethers having biphenylfluorene group 失效
标题翻译：具有联苯芴基团的芳香族聚醚
公开(公告)号：US4806618A
公开(公告)日：1989-02-21
申请号：US115914
申请日：1987-11-02
申请人： Yoshio Imai , Masaaki Kakimoto , Yutaka Maruyama , Toshio Koishi
发明人： Yoshio Imai , Masaaki Kakimoto , Yutaka Maruyama , Toshio Koishi
IPC分类号： C08G65/40 , C08G75/23 , C08G63/18
CPC分类号： C08G75/23 , C08G65/4012
摘要： Novel aromatic polyethers excellent in heat resistance and soluble in various organic solvents are obtained by introducing 9,9-biphenylfluorene group, optionally together with another divalent aromatic group, into the structural units of a polyether derived from either diphenyl ketone or diphenyl sulfone.
摘要翻译：通过将9,9-联苯芴基任选地与另外的二价芳族基团一起引入到由二苯基酮或二苯基砜衍生的聚醚的结构单元中，得到耐热性优异且可溶于各种有机溶剂的新型芳香族聚醚。

3. 发明授权

US4921728A Process of making a liquid crystal element 失效
标题翻译：制造液晶元件的工艺
公开(公告)号：US4921728A
公开(公告)日：1990-05-01
申请号：US399335
申请日：1989-08-28
申请人： Yasuyuki Takiguchi , Akihiko Kanemoto , Kiyohiro Uehara , Yoshio Imai , Taro Hino , Mitsumasa Iwamoto , Masaaki Kakimoto , Masaaki Suzuki
发明人： Yasuyuki Takiguchi , Akihiko Kanemoto , Kiyohiro Uehara , Yoshio Imai , Taro Hino , Mitsumasa Iwamoto , Masaaki Kakimoto , Masaaki Suzuki
IPC分类号： C07C69/773 , G02F1/1337
CPC分类号： G02F1/133711
摘要： A liquid crystal element comprising opposed substrates, a liquid crystal nipped between said opposed substrates, and an aligning film formed on the surface of at least one of said substrates to effect substantially horizontal alignment of the liquid crystal molecules relative to said surface, which liquid crystal element is characterized by the fact that the molecules forming said aligning film are substantially aligned in themselves.
摘要翻译：一种液晶元件，包括相对的基板，夹在所述相对基板之间的液晶和形成在所述基板中的至少一个基板的表面上的取向膜，以使液晶分子相对于所述表面实质上水平对准，该液晶元素的特征在于，形成所述取向膜的分子本身基本上对准。

4. 发明授权

US5451339A Liquid crystal monomeric compound and liquid crystal polymer compound modified therewith 失效
标题翻译：液晶单体化合物和用其改性的液晶聚合物化合物
公开(公告)号：US5451339A
公开(公告)日：1995-09-19
申请号：US63562
申请日：1993-05-19
申请人： Yoshiichi Suzuki , Yoshio Imai , Masaaki Kakimoto
发明人： Yoshiichi Suzuki , Yoshio Imai , Masaaki Kakimoto
IPC分类号： C07C69/94 , C08G77/38 , C09K19/20 , C09K19/32 , C09K19/40 , C09K19/52 , C07F7/04 , C09K19/12
CPC分类号： C09K19/322 , C07C69/94 , C08G77/38 , C09K19/2021 , C09K19/408
摘要： The present invention is to provide a liquid crystal monomeric compound where a liquid crystal phase readily appears, which is excellent in alignment control, film-formability, durability, heat-stability and compatibility, and is able to be applied to electro-optical liquid crystal elements and recording elements; and a side-chain liquid crystal polymer compound modified with such a monomeric compound.The liquid crystal monomeric compound is represented by the following formula:CH.sub.2 .dbd.CH--(CH.sub.2).sub.m --R [1]wherein m is an integer of 2 to 20 and R is a group selected from the group consisting of ##STR1## wherein p is 1 or 2, Rf is CF.sub.3 or CF.sub.2 F.sub.5, R.sup.1 is an alkyl group having 3-18 carbon atoms, * means an optically active carbon atom, (A) and (B) each is a group independently selected from the group consisting of ##STR2## which may be substituted with one or more halogen atoms, and X is --O--, --COO--or a direct linkage, and ##STR3## wherein p, Rf, R.sup.1, (A), (B), X and * have the same meanings as above.
摘要翻译：本发明提供一种容易出现液晶相的液晶单体化合物，其取向控制，成膜性，耐久性，热稳定性和相容性优异，能够应用于电光液晶元素和记录元素; 和用这种单体化合物改性的侧链液晶高分子化合物。液晶单体化合物由下式表示：CH 2 = CH-（CH 2）m R [1]其中m为2至20的整数，R为选自下组的基团：其中p 是1或2，Rf是CF 3或CF 2 F 5，R 1是具有3-18个碳原子的烷基，*表示光学活性碳原子，（A）和（B）各自独立地选自其中p，R f，R 1，（A），（B），X和*具有相同的基团，X是-O-，-COO-或直链，意义如上。

5. 发明授权

US5218081A Method of producing aromatic polythiazole 失效
标题翻译：制备芳族聚噻唑的方法
公开(公告)号：US5218081A
公开(公告)日：1993-06-08
申请号：US657993
申请日：1991-02-20
申请人： Tatsuya Hattori , Hiroshi Akita , Yoshio Imai , Masaaki Kakimoto
发明人： Tatsuya Hattori , Hiroshi Akita , Yoshio Imai , Masaaki Kakimoto
IPC分类号： C08G73/06 , C08G75/32
CPC分类号： C08G75/32 , C08G73/06
摘要： An aromatic polythiazole is produced from a salt of an aromatic diaminodithiol compound and a dicarboxylic acid derivative, by a method comprising the steps of: (a) reacting the aromatic diaminodithiol compound salt with an alkyl halide having a substituted or unsubstituted alkyl group in an alkaline aqueous solvent, so that hydrogen atoms in thiol groups of the aromatic diaminodithiol compound are substituted with the alkyl groups; (b) polymerizing the resulting alkyl group-substituted aromatic diaminodithiol compound with the dicarboxylic acid derivative to form an aromatic polythiazole prepolymer; and (c) heating the aromatic polythiazole prepolymer to cause a thiazole ring closure reaction, thereby producing the aromatic polythiazole. By this method, the amino groups of the aromatic diaminodithiol compound salt are selectively reacted with the dicarboxylic acid derivative.

6. 发明授权

US4820793A Method of preparing aromatic polyamides and polybenzoxazoles 失效
标题翻译：制备芳香族聚酰胺和聚苯并恶唑的方法
公开(公告)号：US4820793A
公开(公告)日：1989-04-11
申请号：US54965
申请日：1987-05-28
申请人： Yoshio Imai , Masaaki Kakimoto , Yoshiyuki Oishi , Yutaka Maruyama
发明人： Yoshio Imai , Masaaki Kakimoto , Yoshiyuki Oishi , Yutaka Maruyama
IPC分类号： C08G69/32 , C08G73/22 , C08G73/06
CPC分类号： C08G69/32 , C08G73/22
摘要： An aromatic polyamide of sufficiently high molecular weight is prepared by reacting a diphenyldiamino compound having a hydroxyl or siloxyl group in each phenyl group and a Si-containing substituent in each amino group, e.g. 2,2-bis(3-trimethylsilylamino-4-trimethylsiloxyphenyl) propane, with an aromatic dicarboxylic acid dihalide in an organic solvent. The polyamide can be converted into a polybenzoxazole by a dehydrating and cyclizing reaction at 100.degree.-500.degree. C.
摘要翻译：通过使每个苯基中具有羟基或甲硅烷氧基的二苯基二氨基化合物和每个氨基中的含Si取代基，例如， 2,2-双（3-三甲基甲硅烷基氨基-4-三甲基甲硅烷氧基苯基）丙烷与芳族二羧酸二卤化物在有机溶剂中反应。聚酰胺可以通过脱水和环化反应在100-500℃下转化成聚苯并恶唑。

7. 发明授权

US4939214A Film comprised of at least one monomolecular layer and process for its preparation using a higher alkyl amine 失效
标题翻译：由至少一个单分子层构成的膜及其使用高级烷基胺制备的方法
公开(公告)号：US4939214A
公开(公告)日：1990-07-03
申请号：US930910
申请日：1986-11-17
申请人： Yoshio Imai , Taro Hino , Mitsumasa Iwamoto , Masa-aki Kakimoto , Masa-aki Suzuki , Toru Konishi
发明人： Yoshio Imai , Taro Hino , Mitsumasa Iwamoto , Masa-aki Kakimoto , Masa-aki Suzuki , Toru Konishi
IPC分类号： B01D69/12 , B01D71/64 , B05D1/20 , C01B3/50 , C08G73/10 , C08G73/14 , C08G73/16 , C08J5/18 , H01B3/30 , H01L21/312
CPC分类号： B82Y30/00 , B01D69/122 , B01D71/64 , B05D1/202 , B82Y40/00 , C01B3/503 , C08G73/1039 , C08G73/1046 , C08G73/1064 , C08G73/1067 , C08G73/1071 , C08G73/1075 , C08G73/14 , C08G73/16 , C08J5/18 , H01B3/306 , H01L21/3128 , B05D2505/50 , C08J2379/08
摘要： A film comprised of at least one monomolecular layer composed essentially of a polyimide having repeating units of the formula: ##STR1## wherein R.sup.1 is a tetravalent organic group and R.sup.2 is a bivalent organic group.
摘要翻译：一种由至少一个单分子层组成的膜，其基本上由具有下式重复单元的聚酰亚胺组成：其中R1是四价有机基团，R2是二价有机基团。

8. 发明授权

US4946989A Optically active compound 失效
标题翻译：光学活性化合物
公开(公告)号：US4946989A
公开(公告)日：1990-08-07
申请号：US223641
申请日：1988-07-25
申请人： Ichiro Kawamura , Yoshio Imai
发明人： Ichiro Kawamura , Yoshio Imai
IPC分类号： C07C69/76 , C07C69/773 , C09K19/20
CPC分类号： C09K19/2021
摘要： A compound of ##STR1## (wherein n is an integer from 2 to 15; R' is ##STR2## m is total number of carbon atoms in R' and is an integer from 5 to 12, and * mark shows asymmetric carbon atom) which is useful for an electric indicative element of liquid crystal is provided.

9. 发明授权

US4632767A Antistatic agents for synthetic fibers 失效
标题翻译：合成纤维抗静电剂
公开(公告)号：US4632767A
公开(公告)日：1986-12-30
申请号：US801941
申请日：1985-11-26
申请人： Masatsugu Saiki , Yoshio Imai , Makoto Takagi
发明人： Masatsugu Saiki , Yoshio Imai , Makoto Takagi
IPC分类号： D06M13/44 , D06M13/02 , D06M13/244 , D06M13/282 , D06M13/292 , D06M13/322 , D06M13/463 , D06M101/00 , D06M101/16 , D06M11/00
CPC分类号： D06M13/292 , Y10S57/901
摘要： Antistatic agents for synthetic fibers comprising 5-50 weight percent of a specific type of quaternary ammonium alkyl phosphate containing 1 weight percent or less of by-product alkali metal halides and 50-95 weight percent of alkali metal salt of saturated alkyl phosphate have improved antistatic characteristics both in high and low humidity conditions, reduce the amount of deposits that fall off, yellowing by a heat treatment and generation of rust, and allow good coiling forms to be obtained.
摘要翻译：包含5-50重量％特定类型的含1重量％或更少的副产物碱金属卤化物的季铵烷基磷酸酯和50-95重量％的饱和烷基磷酸碱金属盐的合成纤维的抗静电剂具有改善的抗静电性在高，低湿度条件下的特性，减少掉落的沉积物的量，通过热处理变黄，产生锈蚀，并且可以获得良好的卷取形式。

10. 发明授权

US4727177A Quaternary ammonium alkyl phosphates and method for producing same 失效
标题翻译：烷基磷酸铵季铵盐及其制备方法
公开(公告)号：US4727177A
公开(公告)日：1988-02-23
申请号：US836691
申请日：1986-03-06
申请人： Masatsugu Saiki , Yoshio Imai , Makoto Takagi
发明人： Masatsugu Saiki , Yoshio Imai , Makoto Takagi
IPC分类号： D06M13/44 , C07C67/00 , C07C213/00 , C07F9/09 , C07F9/11 , C09K3/16 , D06M13/02 , D06M13/244 , D06M13/292 , D06M13/322 , D06M13/46 , D06M13/463 , D06M13/467 , D06M101/00 , D06M101/16
CPC分类号： D06M13/292 , C07F9/091 , C07F9/11
摘要： Antistatic agents for synthetic fibers comprising a specific type of quaternary ammonium alkyl phosphate as principal constituent and 1 weight percent or less of by-product alkali metal halides have improved antistatic characteristics both in high and low humidity conditions and reduce the amount of deposits that fall off, yellowing by a heat treatment and generation of rust. Methods of producing such antistatic agents are also disclosed.

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