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    • 2. 发明授权
    • Solid oxide fuel cell
    • 固体氧化物燃料电池
    • US08492041B2
    • 2013-07-23
    • US13262174
    • 2010-03-31
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/04H01M8/12
    • H01M8/04753H01M8/04559H01M8/04589H01M8/04619H01M8/0494H01M2008/1293
    • Provides a solid oxide fuel cell with which product life can be extended while a practical output power is maintained. The present invention is a solid oxide fuel cell, having a fuel cell module (2), a fuel supply device (38), an oxidant gas supply device (45), and a controller (110) for controlling the fuel supply amount; whereby the controller is furnished with a degradation determining circuit (110a) for determining degradation in a fuel cell module, and with a fuel correction circuit (110b) for correcting operating conditions based on a degradation determination; the fuel correction circuit can execute an increasing correction mode for increasing the fuel supply amount supplied to the fuel cell module so that rated output power is maintained, or can execute a decreasing correction mode for reducing rated output voltage so that the fuel supply amount is reduced; there is also a mode selection device (110c) for selecting correction modes.
    • 提供固体氧化物燃料电池,可延长产品寿命,同时保持实际的输出功率。 本发明是一种固体氧化物燃料电池,具有燃料电池模块(2),燃料供给装置(38),氧化剂气体供给装置(45)和用于控制燃料供给量的控制器(110) 由此控制器配备有用于确定燃料电池模块的劣化的劣化确定电路(110a),以及用于基于劣化确定校正操作条件的燃料校正电路(110b); 燃料校正电路可以执行用于增加提供给燃料电池模块的燃料供给量以增加额定输出功率的增加校正模式,或者可以执行减小额定输出电压的减小校正模式,使得燃料供给量减少 ; 还存在用于选择校正模式的模式选择装置(110c)。
    • 4. 发明授权
    • Solid oxide fuel cell
    • 固体氧化物燃料电池
    • US08859156B2
    • 2014-10-14
    • US13262135
    • 2010-03-31
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/04H01M8/12
    • H01M8/04619H01M8/04701H01M8/04753H01M2008/1293Y02E60/50Y02E60/525
    • To provide a solid oxide fuel cell capable of extending the time period over which a minimum rated output power can be maintained while restraining the advance of fuel cell module degradation.The present invention is a solid oxide fuel cell (1), having a fuel cell module (2), a fuel supply device (38), an oxidant gas supply device (45), and a controller (110); wherein the controller is furnished with a degradation determining circuit for determining degradation (110a) and a fuel correction circuit for correcting operating condition (110b); in which the fuel correction circuit executes a correction to reduce rated output power so that the fuel supply amount is reduced when a determination is made that the fuel cell module has degraded, and when degradation of the fuel cell module advances and predetermined correction switching condition is satisfied, the fuel correction circuit corrects the fuel supply amount supplied to the fuel cell module so as to maintain the reduced rated output power.
    • 提供一种固体氧化物燃料电池,其能够延长能够保持最小额定输出功率的时间段,同时抑制燃料电池模块劣化的进行。 本发明是一种具有燃料电池模块(2),燃料供应装置(38),氧化剂气体供应装置(45)和控制器(110)的固体氧化物燃料电池(1) 其中所述控制器配备有用于确定劣化的劣化确定电路(110a)和用于校正操作条件(110b)的燃料校正电路; 其中燃料校正电路执行校正以降低额定输出功率,使得当确定燃料电池模块已经劣化时,并且当燃料电池模块的劣化前进并且预定的校正切换条件为 燃料校正电路校正供给燃料电池模块的燃料供给量,以保持额定输出功率的降低。
    • 6. 发明授权
    • Solid oxide fuel cell device
    • 固体氧化物燃料电池装置
    • US08497044B2
    • 2013-07-30
    • US12788923
    • 2010-05-27
    • Katsuhisa TsuchiyaToshiharu OtsukaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • Katsuhisa TsuchiyaToshiharu OtsukaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/04H01M8/06
    • H01M8/0612H01M8/0271H01M8/04223H01M8/04225H01M8/04753H01M8/2428H01M8/243H01M8/2484H01M2008/1293
    • To provide a solid oxide fuel cell device capable of stably increasing the temperature of a fuel cell units and smoothly starting electrical generation. The present invention is a solid oxide fuel cell device (1), having a fuel cell module (2); a reformer (20); a fuel supply means (38); a reforming oxidant gas supply means (44); a water supply means (28); a generating oxidant gas supply means (45); and a control section (110) for causing reforming reactions to occur in the reformer at the temperature at which electricity can be generated, prior to the start of electrical generation, in the sequence: POX, in which only the partial oxidation reaction occurs, ATR, in which the partial oxidation reaction and the steam reforming reactions occur, and SR, in which only steam reforming reaction occurs; whereby the control section controls the fuel supply means so that the rate of change in the fuel supply flow rate versus time at the time of transition from the ATR to the SR is the smallest of the rates of change when the fuel supply flow rate is changed at the temperature at which electricity can be generated.
    • 提供能够稳定地提高燃料电池单元的温度并平稳地开始发电的固体氧化物型燃料电池装置。 本发明是一种具有燃料电池模块(2)的固体氧化物燃料电池装置(1)。 改革者(20); 燃料供给装置(38); 重整氧化剂气体供给装置(44); 供水装置(28); 产生氧化剂气体供给装置(45); 以及控制部(110),其在仅在发生部分氧化反应的POX(其中仅发生部分氧化反应)的情况下,在发电开始之前,在重整器中发生重整反应的重整反应 ,其中发生部分氧化反应和蒸汽重整反应,以及仅发生蒸汽重整反应的SR; 由此控制部分控制燃料供给装置,使得当燃料供给流量变化时,从ATR到SR的转变时的燃料供给流量与时间的变化率是最小的变化率 在能够产生电力的温度下。
    • 7. 发明申请
    • SOLID OXIDE FUEL CELL DEVICE
    • 固体氧化物燃料电池装置
    • US20120021319A1
    • 2012-01-26
    • US13262032
    • 2010-03-31
    • Katsuhisa TsuchiyaKiyotaka NakanoTsukasa ShigezumiToshiharu OoeYoshiyuki Kawamura
    • Katsuhisa TsuchiyaKiyotaka NakanoTsukasa ShigezumiToshiharu OoeYoshiyuki Kawamura
    • H01M8/04H01M8/24
    • H01M8/0612C01B3/382C01B3/384C01B2203/0233C01B2203/0244C01B2203/0261C01B2203/066C01B2203/1058C01B2203/1064C01B2203/1258C01B2203/1604C01B2203/1609C01B2203/1619C01B2203/1685H01M8/04365H01M8/04679H01M8/04731H01M8/04753H01M8/2428H01M8/243H01M2008/1293Y02E60/50Y02E60/525
    • The SOFC of the present invention has a plurality of individual solid oxide fuel cells (84) disposed within an generating chamber (10), a fuel supply unit (38) for supplying fuel to the individual solid oxide fuel cells, a temperature sensor (142) for measuring the temperature of the generating chamber (T1), and a control section (110) for changing the amount of fuel supplied in response to an amount of generation required based on control characteristics for supplying fuel, wherein the control section is furnished with a temperature band for monitoring purposes, having a minimum temperature value (Ta) and a maximum temperature value (Tb) for adaptive control, predetermined based on a minimum amount and maximum amount of rated electrical generation, and a maximum temperature value for adaptive control in response to anomalies, which is higher than the maximum temperature value (Tb) of the adaptive control temperature band, and a minimum temperature value for adaptive control in response to anomalies, which is lower than the minimum temperature value (Ta) of the adaptive control temperature band, and the control section is furnished with: an anomaly response control section for executing anomaly response control by restricting operation of the fuel cell when the generating chamber temperature (T1) is higher than the maximum temperature value for anomaly response control or lower than the minimum temperature value for anomaly response control, and with an adaptive control section for executing adaptive control by correcting the amount of fuel supplied based on a temperature signal from the temperature measurement sensor so that the generating chamber temperature (T1) is kept within the temperature band when the generating chamber temperature (T1) exceeds the minimum temperature value (Ta) or maximum temperature (Tb) for adaptive control and goes outside the temperature band.
    • 本发明的SOFC具有设置在发电室(10)内的多个单独的固体氧化物燃料电池(84),用于向各固体氧化物燃料电池供应燃料的燃料供给单元(38),温度传感器 ),以及控制部(110),其根据供给燃料的控制特性,响应于所需的发电量而改变供给量,其特征在于,所述控制部配备有 用于监视目的的温度带,具有基于最小量和最大额定发电量预定的用于自适应控制的最小温度值(Ta)和最大温度值(Tb)以及用于自适应控制的最大温度值 响应于异常,其高于自适应控制温度带的最大温度值(Tb),以及响应中的自适应控制的最小温度值 e到低于自适应控制温度带的最低温度值(Ta)的异常,并且控制部分具有:异常响应控制部分,用于通过限制燃料电池的运行来执行异常响应控制 室温(T1)高于异常响应控制的最大温度值或低于异常响应控制的最小温度值,并且具有用于通过基于温度信号校正燃料量来执行自适应控制的自适应控制部分 当发电室温度(T1)超过用于自适应控制的最低温度值(Ta)或最高温度(Tb)时,发电室温度(T1)保持在温度带内,并且超出温度 带。
    • 8. 发明授权
    • Solid oxide fuel cell device
    • 固体氧化物燃料电池装置
    • US09184457B2
    • 2015-11-10
    • US13262032
    • 2010-03-31
    • Katsuhisa TsuchiyaKiyotaka NakanoTsukasa ShigezumiToshiharu OoeYoshiyuki Kawamura
    • Katsuhisa TsuchiyaKiyotaka NakanoTsukasa ShigezumiToshiharu OoeYoshiyuki Kawamura
    • H01M8/06C01B3/38H01M8/04H01M8/24H01M8/12
    • H01M8/0612C01B3/382C01B3/384C01B2203/0233C01B2203/0244C01B2203/0261C01B2203/066C01B2203/1058C01B2203/1064C01B2203/1258C01B2203/1604C01B2203/1609C01B2203/1619C01B2203/1685H01M8/04365H01M8/04679H01M8/04731H01M8/04753H01M8/2428H01M8/243H01M2008/1293Y02E60/50Y02E60/525
    • The SOFC of the present invention has a plurality of individual solid oxide fuel cells (84) disposed within an generating chamber (10), a fuel supply unit (38) for supplying fuel to the individual solid oxide fuel cells, a temperature sensor (142) for measuring the temperature of the generating chamber (T1), and a control section (110) for changing the amount of fuel supplied in response to an amount of generation required based on control characteristics for supplying fuel, wherein the control section is furnished with a temperature band for monitoring purposes, having a minimum temperature value (Ta) and a maximum temperature value (Tb) for adaptive control, predetermined based on a minimum amount and maximum amount of rated electrical generation, and a maximum temperature value for adaptive control in response to anomalies, which is higher than the maximum temperature value (Tb) of the adaptive control temperature band, and a minimum temperature value for adaptive control in response to anomalies, which is lower than the minimum temperature value (Ta) of the adaptive control temperature band, and the control section is furnished with: an anomaly response control section for executing anomaly response control by restricting operation of the fuel cell when the generating chamber temperature (T1) is higher than the maximum temperature value for anomaly response control or lower than the minimum temperature value for anomaly response control, and with an adaptive control section for executing adaptive control by correcting the amount of fuel supplied based on a temperature signal from the temperature measurement sensor so that the generating chamber temperature (T1) is kept within the temperature band when the generating chamber temperature (T1) exceeds the minimum temperature value (Ta) or maximum temperature (Tb) for adaptive control and goes outside the temperature band.
    • 本发明的SOFC具有设置在发电室(10)内的多个单独的固体氧化物燃料电池(84),用于向各固体氧化物燃料电池供应燃料的燃料供给单元(38),温度传感器 ),以及控制部(110),其根据供给燃料的控制特性,响应于所需的发电量而改变供给量,其特征在于,所述控制部配备有 用于监视目的的温度带,具有基于最小量和最大额定发电量预定的用于自适应控制的最小温度值(Ta)和最大温度值(Tb)以及用于自适应控制的最大温度值 响应于异常,其高于自适应控制温度带的最大温度值(Tb),以及响应中的自适应控制的最小温度值 e到低于自适应控制温度带的最低温度值(Ta)的异常,并且控制部分具有:异常响应控制部分,用于通过限制燃料电池的运行来执行异常响应控制 室温(T1)高于异常响应控制的最大温度值或低于异常响应控制的最小温度值,并且具有用于通过基于温度信号校正燃料量来执行自适应控制的自适应控制部分 当发电室温度(T1)超过用于自适应控制的最低温度值(Ta)或最高温度(Tb)时,发电室温度(T1)保持在温度带内,并且超出温度 带。
    • 9. 发明授权
    • Solid oxide fuel cell
    • 固体氧化物燃料电池
    • US08968953B2
    • 2015-03-03
    • US13262152
    • 2010-03-31
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • Tsukasa ShigezumiToshiharu OoeKatsuhisa TsuchiyaKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/04
    • H01M8/04679H01M8/04365H01M8/04731H01M8/04753H01M8/2428H01M8/243H01M2008/1293
    • A solid oxide fuel cell capable of maintaining performance over a long time period by appropriately changing fuel cell module operating conditions. The present invention is a solid oxide fuel cell (1), having a fuel cell module (2), a fuel supply device (38), an oxidant gas supply device (45), and a controller (110) for controlling the amount of fuel supplied from the fuel supply device; the controller is furnished with a degradation determining circuit (110a) for determining degradation in the fuel cell module and a degradation response circuit (110b) for changing fuel cell module operating conditions based on the degradation determination by the degradation determining circuit; the degradation determination stores fuel cell module operating results arising from the operating conditions changed by the degradation response circuit, and executes further degradation determination based on the stored operating results.
    • 一种固体氧化物燃料电池,能够通过适当地改变燃料电池模块的运行条件来维持长时间的性能。 本发明是一种固体氧化物燃料电池(1),具有燃料电池模块(2),燃料供给装置(38),氧化剂气体供给装置(45)和控制器 从燃料供给装置供应的燃料; 控制器配备有用于确定燃料电池模块的劣化的劣化判定电路(110a)和用于根据劣化判定电路的劣化判定来改变燃料电池模块工作条件的劣化响应电路(110b); 劣化判定存储由劣化响应电路改变的工作条件引起的燃料电池模块运行结果,并且根据存储的运算结果进行进一步的劣化判定。
    • 10. 发明授权
    • Solid oxide fuel cell device
    • 固体氧化物燃料电池装置
    • US08592093B2
    • 2013-11-26
    • US12788857
    • 2010-05-27
    • Katsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • Katsuhisa TsuchiyaTsukasa ShigezumiToshiharu OoeKiyotaka NakanoYoshiyuki Kawamura
    • H01M8/06
    • H01M8/04679H01M8/04007H01M8/04365H01M8/04373H01M8/04686H01M8/0618H01M8/12H01M2008/1293
    • A solid oxide fuel cell (SOFC) device comprises a fuel cell assembly, a reformer, a fuel gas supply device, a reforming air supply device, a power generating air supply device, an ignition device, a temperature detection devices for detecting the temperature caused by combustion of fuel gas, and a control section for sequentially conducting a combustion operation in which fuel gas is ignited by the ignition device and combusted using the power generating air, a POX operation, an ATR operation, and an SR combination, wherein the control section determines that a flameout has occurred when the amount by which the temperature caused by combustion of fuel gas and detected by the temperature detection device drops within a predetermined time is equal to or greater than a preset, predetermined temperature drop threshold, and the predetermined temperature drop threshold is set as a plurality of predetermined temperature drop thresholds in accordance with temperature bands caused by the combustion of fuel gas, the lower the temperature induced by the combustion of fuel gas, the higher is the temperature drop threshold.
    • 固体氧化物燃料电池(SOFC)装置包括燃料电池组件,重整器,燃料气体供应装置,重整供气装置,发电空气供应装置,点火装置,用于检测温度的温度检测装置 通过燃料气体的燃烧,以及控制部分,用于依次进行其中燃料气体被点火装置点燃并使用发电空气燃烧的燃烧操作,POX操作,ATR操作和SR组合,其中控制 当确定由燃料气体燃烧产生的温度并由温度检测装置检测到的温度在预定时间内下降的量等于或大于预设的预定温度下降阈值时,发生熄火,并且预定温度 根据由该控制引起的温度带,将下降阈值设定为多个预定的温度下降阈值 燃料气体的燃烧导致的温度越低,温度下降阈值越高。