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    • 9. 发明授权
    • Propylene block copolymer compositions
    • 丙烯嵌段共聚物组合物
    • US06355736B1
    • 2002-03-12
    • US09693996
    • 2000-10-23
    • Takanori NakashimaShinichi AkitayaYoshitaka MorimotoYoshitaka Sumi
    • Takanori NakashimaShinichi AkitayaYoshitaka MorimotoYoshitaka Sumi
    • C08L2316
    • C08L53/00C08F210/06C08F297/08C08L2666/02C08L2666/04C08F210/16C08F2500/17
    • A propylene block copolymer composition is disclosed which comprises (A) a propylene-&agr;-olefin random copolymer with a propylene content of 99.4 to 99.9 mol % and (B) a propylene-&agr;-olefin random copolymer with a propylene content of 35 to 60 mol %, &agr;-olefin contained in the random copolymer (A) being ethylene and/or 1-butene, wherein the intrinsic viscosity ([&eegr;B]) of the propylene-&agr;-olefin random copolymer (B) ranges from 0.5 to 2.0 dl/g, the ratio ([&eegr;B]/[&eegr;A]) of the intrinsic viscosity ([&eegr;B]) of the propylene-&agr;-olefin random copolymer (B) to the intrinsic viscosity ([&eegr;A]) of the propylene-&agr;-olefin random copolymer (A) ranges from 0.3 to 1.2 and the product (([&eegr;B]/[&eegr;A])×(WA/WB)) of the intrinsic viscosity ratio ([&eegr;B]/[&eegr;A]) and the weight ratio (WA/WB) of both copolymers ranges from 1.0 to 3.0. The propylene block copolymer composition is suitable as a raw material for molded article having excellent see-through property, transparency, stress-whitening resistance, stiffness and heat resistance.
    • 公开了一种丙烯嵌段共聚物组合物,其包含(A)丙烯含量为99.4至99.9摩尔%的丙烯-α-烯烃无规共聚物和(B)丙烯含量为35至60的丙烯-α-烯烃无规共聚物 摩尔%,无规共聚物(A)中所含的α-烯烃为乙烯和/或1-丁烯,其中丙烯-α-烯烃无规共聚物(B)的特性粘度(η)为0.5-2.0dl 丙烯-α-烯烃无规共聚物(B)的特性粘度(η)与丙烯-α-烯烃无规共聚物(B)的特性粘度([η])的比值(η/η) 烯烃无规共聚物(A)的范围为0.3至1.2,特性粘度比(η/η[η])和重量比((η[η] 两种共聚物的WA / WB为1.0〜3.0。 丙烯嵌段共聚物组合物适合作为具有优异的透明性,透明性,耐应力增白性,刚性和耐热性的模制品的原料。
    • 10. 发明授权
    • Polypropylene resin composition and gas permeable film using the same
    • 聚丙烯树脂组合物和使用其的透气膜
    • US06815503B2
    • 2004-11-09
    • US10104303
    • 2002-03-20
    • Shinji NakataYasuhiro ShiraishiTakanori NakashimaShinichi Akitaya
    • Shinji NakataYasuhiro ShiraishiTakanori NakashimaShinichi Akitaya
    • C08J518
    • C08L23/10C08L23/16C08L2666/04
    • Provided are a novel polypropylene resin composition, a gas permeable film comprising the same and provided with satisfactory optical characteristics (transparency, gloss and see throughness) as well as an excellent gas permeability (water vapor, oxygen and ethylene gas) without damaging a rigidity and a vegetable and fruit freshness long term-maintaining method using the above gas permeable film for a wrapping film. The polypropylene resin composition described above comprises 40 to 95% by weight of a propylene polymer (A) and 5 to 60% by weight of an ethylene/propylene/butene random copolymer (B) having a butene content of 3 to 40% by weight and an ethylene content of 10 to 30% by weight, wherein a ratio (&eegr;B/&eegr;A) of an intrinsic viscosity &eegr;B of the component (B) described above to an intrinsic viscosity &eegr;A of the component (A) described above falls in a range of 0.5 to 1.3; and the &eegr;B described above falls in a range of 0.5 to 3.0 dl/g. The gas permeable film described above is a single layer or multilayer film comprising at least one layer of a film of the polypropylene resin composition described above and having a thickness of 10 to 100 &mgr;m, and it has the following characteristics: (1) a permeability TH2O of water vapor is 9 to 50 g/m2·24 h (based on JIS Z 0208), (2) a permeability TO2 of oxygen is 600 to 12500 nmol/m2·s·100 kPa (based on JIS K 7126-A) and (3) a permeability Tethylene of ethylene gas is 600 to 22500 nmol/m2·s·100 kPa (based on JIS K 7126-A).