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1. 发明授权

US4968443A Antistatic laundry detergent composition and processes therefor 失效
标题翻译：抗静电洗衣用洗涤剂组合物及其工艺
公开(公告)号：US4968443A
公开(公告)日：1990-11-06
申请号：US222992
申请日：1988-07-22
申请人： Pierre M. Lambert , Eduardo E. Puentes-Bravo , Marcel J. Gillis , Harold E. Wixon , Alain M. Gourgue , Genevieve P. Bonnechere
发明人： Pierre M. Lambert , Eduardo E. Puentes-Bravo , Marcel J. Gillis , Harold E. Wixon , Alain M. Gourgue , Genevieve P. Bonnechere
IPC分类号： C11D3/28 , C09K3/16 , C11D1/22 , C11D1/58 , C11D1/62 , C11D1/65 , C11D1/72 , C11D1/86 , C11D11/00 , C11D11/02 , D06M13/02 , D06M13/244 , D06M13/248 , D06M13/256 , D06M13/262 , D06M13/282 , D06M13/292 , D06M13/322 , D06M13/35 , D06M13/352 , D06M13/463
CPC分类号： C11D11/02 , C09K3/16 , C11D1/58 , C11D1/65 , C11D1/86 , C11D1/22 , C11D1/62 , C11D1/72
摘要： An antistatic particulate laundry detergent composition comprises synthetic organic detergent, preferably sodium linear dodecylbenzene or sodium linear tridecylbenzene sulfonate, inorganic and/or organic builder for the detergent, preferably sodium tripolyphosphate and/or zeolite builder, and higher alkyl or alkylbenzene hydroxyethyl imidazoline of the formula ##STR1## wherein R is an alkyl or alkylbenzene of 8 to 24 carbon atoms preferably stearyl, which detergent composition is of improved detergency due to the presence therein of the higher alkyl or alkylbenzene hydroxyethyl imidazoline antistat. In preferred detergent compositions of this type bentonite is desirably present for its fabric softening activity, and such activity is improved by the presence of the higher alkyl or alkylbenzene hydroxyethyl imidazoline, which also possesses fabric softening properties. When low phosphorus contents of detergent compositions are not required by law or regulation, contents of zeolites and other non-phosphate builders may be omitted and increased proportions of tripolyphosphate may be employed, instead.The mentioned detergent compositions are useful to wash soiled laundry and to make it softer and static-free, whether such washing is with American or European washing machines and in accordance with such practices. Unexpected improvements in soil removal, as measured visually and by reflectometer, are noted after the washing of laundry that had been stained with oily soils, and the washed laundry is softer.Also described in a process for manufacturing detergent compositions comprising synthetic anionic organic detergent, zeolite, tripolyphosphate and the mentioned imidazoline, in which an aqueous crutcher mix is made, to which the zeolite is added before the tripolyphosphate, and the imidazoline is added immediately after the tripolyphosphate, thereby avoiding undesirable reaction of the imidazoline with the zeolite, which reaction has a negative effect on antistatic and fabric softening properties of the resulting product. The product is obtained in particulate solid form by spray drying of the crutcher mix in conventional manner. Various other active and adjuvant components of the detergent composition may be post-added with the spray dried beads or may be incorporated in the crutcher mix.

2. 发明授权

US5332513A Particulate fabric softening and detergent compositions 失效
标题翻译：颗粒织物软化和洗涤剂组合物
公开(公告)号：US5332513A
公开(公告)日：1994-07-26
申请号：US884499
申请日：1992-05-15
申请人： Jan R. P. Doms , Marcel J. E. G. Gillis , Pierre M. Lambert , Paul A. Heckles , Eduardo E. Puentes-Bravo , Anita Hermosilla M , Jean-Paul M. H. F. Grandmaire , Viviane E. A. Tack
发明人： Jan R. P. Doms , Marcel J. E. G. Gillis , Pierre M. Lambert , Paul A. Heckles , Eduardo E. Puentes-Bravo , Anita Hermosilla M , Jean-Paul M. H. F. Grandmaire , Viviane E. A. Tack
IPC分类号： C11D1/72 , C11D1/74 , C11D3/00 , C11D3/12 , C11D3/20 , C11D17/04 , D06M10/08
CPC分类号： C11D17/047 , C11D1/72 , C11D1/74 , C11D3/001 , C11D3/126 , C11D3/2093
摘要： A particulate fabric softening composition and a particulate fabric softening detergent composition are described, both of which include bentonite powder agglomerated into larger particulate bead or granule form with a normally solid co-melt of a pentaerythritol compound (PEC), such as pentaerythritol ditallowate (PEDT), and a nonionic surfactant, such as a condensation product of a mole of a C.sub.12-15 fatty alcohol with seven moles of ethylene oxide. The fabric softening composition described may be added to wash (or rinse water) but preferably is incorporated in a particulate built synthetic organic anionic and/or nonionic detergent composition to produce a fabric softening detergent composition. The invented detergent compositions are especially suitable for washing laundry in "cold" water, such as water at 40.degree. C. or thereabout, in which the nonionic surfactant increases the dispersibility of the PEC, improves fabric softening activity thereof, in conjunction with the bentonite, and also prevents excessive whitening or chalking of dark colored laundry by the particulate fabric softening composition. These improved results have been attributed to the nonionic surfactant lowering the co-melt's melting point to about 40.degree. C. or lower, at which temperature the softening composition disperses satisfactorily in the wash water. Additional advantages of the invention are a bonus effect of the nonionic surfactant in increasing detergency of the detergent composition and wash water, and in allowing a decrease in PEC content of the softening and detergent compositions without loss of softening effect.
摘要翻译：描述了颗粒织物软化组合物和颗粒织物软化洗涤剂组合物，它们都包括通过季戊四醇化合物（PEC）例如季戊四醇二桐油（PEDT）的通常固体共熔融物凝聚成较大颗粒珠粒或颗粒形式的膨润土粉末）和非离子表面活性剂，例如摩尔C 12-15脂肪醇与7摩尔环氧乙烷的缩合产物。可以加入所述的织物软化组合物以洗涤（或冲洗水），但优选加入颗粒状的合成有机阴离子和/或非离子洗涤剂组合物中以制备织物软化洗涤剂组合物。本发明的洗涤剂组合物特别适用于在“冷”水中洗涤衣物，例如40℃或其附近的水，其中非离子表面活性剂增加PEC的分散性，改善织物软化活性，与膨润土，并且还防止由微粒织物软化组合物过度漂白或粉化深色衣物。这些改进的结果归因于非离子表面活性剂将共熔体的熔点降低至约40℃或更低，在该温度下，软化组合物令人满意地分散在洗涤水中。本发明的另外的优点是非离子表面活性剂在增加洗涤剂组合物的洗涤性和洗涤水中以及允许软化和洗涤剂组合物的PEC含量的降低而不损失软化效果的附加效果。

3. 发明授权

US5358647A Fabric softening products based on a combination of pentaerythritol compound and bentonite 失效
标题翻译：基于季戊四醇化合物和膨润土组合的织物软化产品
公开(公告)号：US5358647A
公开(公告)日：1994-10-25
申请号：US107434
申请日：1993-08-16
申请人： Eduardo Puentes-Bravo , Anita M. Hertmosilla , Jean-Paul M. H. F. Grandmaire , Viviane E. A. Tack , Jan R. P. Doms , Marcel J. E. G. Gillis , Pierre M. Lambert , Paul A. Heckles
发明人： Eduardo Puentes-Bravo , Anita M. Hertmosilla , Jean-Paul M. H. F. Grandmaire , Viviane E. A. Tack , Jan R. P. Doms , Marcel J. E. G. Gillis , Pierre M. Lambert , Paul A. Heckles
IPC分类号： C11D1/66 , C11D1/74 , C11D3/00 , C11D3/12 , C11D3/20 , C11D17/04 , D06M10/08
CPC分类号： C11D17/047 , C11D1/667 , C11D1/74 , C11D3/001 , C11D3/1253 , C11D3/126 , C11D3/2093
摘要： A fabric softening product is a composition or article that is effective for its fabric softening purpose but preferably excludes ecotoxic quaternary ammonia salt, includes, as a fabric softening component, a PEC, which is an ester of pentaerythritol, an ester of an oligomer of pentaerythritol, an ester of a lower alkoxylated pentaerythritol or an ester of a lower alkoxylated pentaerythritol oligomer, with bentonite, which increases its fabric softening effect remarkably. The PEC is preferably a partial higher fatty acid ester of pentaerythritol or a partial higher fatty acid ester of a pentaerythritol oligomer, the bentonite is preferably sodium bentonite or swellable calcium bentonite, the fabric softening composition is a softergent or a non-detersive composition, both of which may be in solid (preferably particulate solid) or liquid state or form (preferably in aqueous suspension or gel), and the fabric softening article is an absorbent material with bentonite and PEC deposited on it or absorbed by it. Also within the invention are processes for softening fibrous materials of laundry contacting them with such compositions and/or articles during washing, rinsing and/or drying operations.
摘要翻译：织物软化产品是对其织物软化目的有效的组合物或制品，但优选排除生态毒性季铵盐，包括作为织物软化组分的作为季戊四醇酯的PEC，季戊四醇的低聚物的酯，低级烷氧基化季戊四醇的酯或低级烷氧基化季戊四醇低聚物的酯与膨润土显着增加其织物柔软效果。 PEC优选为季戊四醇的部分高级脂肪酸酯或季戊四醇低聚物的部分高级脂肪酸酯，膨润土优选为膨润土钠或膨润性钙膨润土，织物柔软组合物为较柔软或非洗涤组合物其可以是固体（优选颗粒状固体）或液态或形式（优选在水性悬浮液或凝胶中），并且织物软化制品是具有膨润土和PEC沉积在其上或由其吸收的吸收材料。本发明还涉及使洗涤，漂洗和/或干燥操作期间与这些组合物和/或制品接触的衣物的纤维材料软化的方法。

4. 发明授权

US4602080A Organic salts of polyisocyanate derivatives and the preparation thereof 失效
标题翻译：多异氰酸酯衍生物的有机盐及其制备方法
公开(公告)号：US4602080A
公开(公告)日：1986-07-22
申请号：US507639
申请日：1983-06-27
申请人： Pierre M. Lambert , Ignacio De Aguirre-Otegui
发明人： Pierre M. Lambert , Ignacio De Aguirre-Otegui
IPC分类号： C08G18/00 , C08G18/02 , C08G18/79 , C07D403/02 , C07D403/14
CPC分类号： C08G18/791 , C08G18/022 , C08G18/027
摘要： This invention relates to new salts of organic polyisocyanates containing at least one isocyanurate ring carrying a negative charge and at least one non-metal ion having a positive charge, these new salts being organic salts of mono- or polyisocyanurates containing at least two free isocyanate functions.The new organic salts according to this invention may be represented by the following general formula (I) ##STR1## in which R is a bivalent aliphatic, cycloaliphatic, aromatic or heterocyclic radical which may be substituted, Q is an onium cation substituted by four identical or different radicals which may be aliphatic, cycloaliphatic, aromatic or heterocyclic possibly substituted radicals, a is the average number of molecular isocyanurate rings which may be equal to zero or to more than zero, b is the number of tetrasubstituted heteroatoms of Q which is of at least 1 and n is the average number of ionic isocyanurate rings which is of at least 1.
摘要翻译：本发明涉及含有至少一个带有负电荷的异氰脲酸酯环和至少一种具有正电荷的非金属离子的有机多异氰酸酯的新盐，这些新的盐是含有至少两个游离异氰酸酯官能团的单或多异氰酸酯的有机盐。根据本发明的新的有机盐可以由以下通式（I）表示：其中R是可被取代的二价脂族，脂环族，芳族或杂环基团，Q是由四个相同或不同的基团取代的鎓阳离子，其可以是脂族，脂环族，芳族或杂环的可能取代的基团，a是分子异氰脲酸酯环的平均数，其可以等于零或大于零，b是四取代的至少为1的Q的杂原子，n是至少为1的离子型异氰脲酸酯环的平均数。

5. 发明授权

US4544743A Salts of 1,3,5-oxadiazines-2,4,6-triones, 1,3,5-oxadiazines-2,4,6-triones and the preparation thereof 失效
标题翻译： 1,3,5-恶二嗪-2,4,6-三甲苯磺酸盐，1,3,5-恶二嗪-2,4,6-二硫杂的盐及其制备方法
公开(公告)号：US4544743A
公开(公告)日：1985-10-01
申请号：US507637
申请日：1983-06-27
申请人： Pierre M. Lambert , Ignacio De Aguirre-Otegui
发明人： Pierre M. Lambert , Ignacio De Aguirre-Otegui
IPC分类号： C07D273/04 , C07F9/00
CPC分类号： C07D273/04
摘要： This invention relates to new salts of 1,3,5-oxadiazines-2,4,6-triones, to new 1,3,5-oxadiazines-2,4,6-triones and to the preparation thereof.
摘要翻译：本发明涉及1,3,5-恶二嗪-2,4,6-二硫杂新的新的盐，新的1,3,5-恶二嗪-2,4,6-二硫杂及其制备。

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