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1. 发明授权

US06248816B1 Thermoplastic polymer composition containing dye compositions 失效
标题翻译：含有染料组合物的热塑性聚合物组合物
公开(公告)号：US06248816B1
公开(公告)日：2001-06-19
申请号：US09309987
申请日：1999-05-11
申请人： Max Allen Weaver , Clarence Alvin Coates, Jr. , Jean Carroll Fleischer , Brian Edison Maxwell
发明人： Max Allen Weaver , Clarence Alvin Coates, Jr. , Jean Carroll Fleischer , Brian Edison Maxwell
IPC分类号： C08K534
CPC分类号： C09B5/52 , C08K5/0041
摘要： The present invention relates to a polymeric composition suitable for use in films, molded articles and fibers, including microdenier fibers. The polymeric composition comprises a thermoplastic resin in an amount from about 50 weight percent to about 99.9 weight percent of the polymeric composition, and a dye composition in an amount from about 0.1 weight percent to about 50 weight percent of the polymeric composition. The dye composition contains an indanthrone compound as a major component. As used herein, indanthrone compounds are defined as compounds having the general structure represented by Formula I: wherein R is hydrogen or at least one group independently selected from C1-C8 alkyl, C1-C8 alkoxy, halogen, hydroxy, trifluoromethyl, aryloxy, arylthio, arylamino, C1-C8 carbalkoxy, —CO2H, C1-C8 alkanoyloxy, arylazo, —CN, —NO2, —SO2-C1-C8 alkyl, —SO2N(R1)R2, and —CON(R1)R2, wherein R1 and R2 are independently selected from C1-C8 alkyl, C3-C8 cycloalkyl, aryl and hydrogen. A process for preparing the polymeric composition, processes for preparing the dye composition and articles formed from the polymeric composition are also disclosed.
摘要翻译：本发明涉及适用于薄膜，模制品和纤维的聚合物组合物，包括微旦尼尔纤维。聚合物组合物包含聚合物组合物的约50重量％至约99.9重量％的量的热塑性树脂，和聚合物组合物的约0.1重量％至约50重量％的量的染料组合物。染料组合物含有阴丹酮化合物作为主要成分。如本文所用，阴丹酮化合物定义为具有由式I表示的通式结构的化合物：其中R是氢或至少一个独立地选自C 1 -C 8烷基，C 1 -C 8烷氧基，卤素，羟基，三氟甲基，芳氧基，芳硫基，芳基氨基，C1-C8烷氧基，-CO2H，C1-C8烷酰氧基，芳基偶氮，-CN，-NO2，-SO2-C1-C8烷基，-SO2N（R1）R2和-CON（R1）R2，其中R1和 R 2独立地选自C 1 -C 8烷基，C 3 -C 8环烷基，芳基和氢。还公开了制备聚合物组合物的方法，制备染料组合物的方法和由聚合物组合物形成的制品。

2. 发明授权

US5973038A Thermoplastic polymer compositions containing black dye compositions 失效
标题翻译：含有黑色染料组合物的热塑性聚合物组合物
公开(公告)号：US5973038A
公开(公告)日：1999-10-26
申请号：US78227
申请日：1998-05-13
申请人： Max Allen Weaver , Clarence Alvin Coates, Jr. , Jean Carroll Fleischer , Brian Edison Maxwell
发明人： Max Allen Weaver , Clarence Alvin Coates, Jr. , Jean Carroll Fleischer , Brian Edison Maxwell
IPC分类号： C08K5/00 , C09B5/52 , C08K5/34 , C09F9/00
CPC分类号： C08K5/0041 , C09B5/52
摘要： The present invention relates to a black polymeric composition suitable for use in films, fibers and molded articles, where a soluble, easily dispersed colorant is desirable. The black polymeric composition provides a high black color quality and is small enough to function as a black colorant in microdenier fibers. The black polymeric composition comprises a thermoplastic resin in an amount between about 50 weight percent and about 99.9 weight percent of the black polymeric composition, and a black dye composition in an amount between about 0.1 weight percent and about 50 weight percent of the black polymeric composition. The black dye composition contains a black indanthrone compound as a major component. As used herein, black indanthrone compounds are defined as compounds having the general structure represented by Formula I: ##STR1## wherein R is hydrogen or at least one group independently selected from C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, halogen, hydroxy, trifluoromethyl, aryloxy, arylthio, arylamino, C.sub.1 -C.sub.8 carbalkoxy, --CO.sub.2 H, C.sub.1 -C.sub.8 alkanoyloxy, arylazo, --CN, --NO.sub.2, --SO.sub.2 --C.sub.1 -C.sub.8 alkyl, --SO.sub.2 N(R1)R2, and --CON(R1)R2, wherein R1 and R2 are independently selected from C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, aryl and hydrogen. The present invention further relates to a process for preparing the black polymeric composition, processes for preparing the black dye composition and articles formed from the black polymeric composition.
摘要翻译：本发明涉及适用于薄膜，纤维和模塑制品的黑色聚合物组合物，其中可溶性易分散的着色剂是期望的。黑色聚合物组合物提供高的黑色品质，并且足够小以用作微旦尼尔纤维中的黑色着色剂。黑色聚合物组合物包含的量为黑色聚合物组合物的约50重量％至约99.9重量％的热塑性树脂，黑色聚合物组合物的约0.1重量％至约50重量％的黑色染料组合物。黑色染料组合物含有黑色阴丹酮化合物作为主要成分。如本文所用，黑色阴丹酮化合物定义为具有由式I表示的一般结构的化合物：其中R是氢或至少一个独立地选自C 1 -C 8烷基，C 1 -C 8烷氧基，卤素，羟基，三氟甲基，芳氧基，芳基硫基，芳基氨基，C1-C8烷氧基，-CO2H，C1-C8烷酰氧基，芳基偶氮，-CN，-NO2，-SO2-C1-C8烷基，-SO2N（R1）R2和-CON（R1）R2，其中R1 并且R 2独立地选自C 1 -C 8烷基，C 3 -C 8环烷基，芳基和氢。本发明还涉及制备黑色聚合物组合物的方法，制备黑色染料组合物的方法和由黑色聚合物组合物形成的制品。

3. 发明授权

US6140517A Anthraquinone polysulfonamide colorants 失效
标题翻译：蒽醌多磺酰胺着色剂
公开(公告)号：US6140517A
公开(公告)日：2000-10-31
申请号：US906642
申请日：1997-08-07
申请人： Max Allen Weaver , James John Krutak, Sr. , Clarence Alvin Coates, Jr. , Gerry Foust Rhodes , Brian Edison Maxwell
发明人： Max Allen Weaver , James John Krutak, Sr. , Clarence Alvin Coates, Jr. , Gerry Foust Rhodes , Brian Edison Maxwell
IPC分类号： C07C309/88 , C07C323/66 , C08G75/30 , C09B1/32 , C09B1/514 , C09B1/58 , C09B69/10 , C07C311/37 , C07C303/38
CPC分类号： A61Q5/065 , A61K8/84 , C08G75/30 , C09B1/325 , C09B1/5145 , C09B1/585 , C09B69/101
摘要： The invention relates to anthraquinone polysulfonamide colorants derived from colored disulfonyl chlorides containing anthraquinone chromophores by reacting with various diamines. The anthraquinone polysulfonamide colorants are useful for coloring a wide variety of products such as plastics, fibers, films, cosmetics, skin creams or lotions, polishes, waxes, hair colorations, coatings, paints, inks, etc. and are particularly useful in end uses where sublimation, migration, extraction and exudation of presently used colorants are problems.
摘要翻译：本发明涉及通过与各种二胺反应而衍生自含有蒽醌发色团的着色二磺酰氯的蒽醌聚磺酰胺着色剂。蒽醌多磺酰胺着色剂可用于着色各种各样的产品，如塑料，纤维，薄膜，化妆品，护肤霜或乳液，抛光剂，蜡，头发着色剂，涂料，油漆，油墨等，并且在最终用途中特别有用其中目前使用的着色剂的升华，迁移，提取和渗出是问题。

4. 发明授权

US06776930B2 Method for preparing light-absorbing polymeric compositions 失效
标题翻译：光吸收聚合物组合物的制备方法
公开(公告)号：US06776930B2
公开(公告)日：2004-08-17
申请号：US09751766
申请日：2000-12-29
申请人： Max Allen Weaver , James John Krutak, Sr. , Brian Edison Maxwell , Gerry Foust Rhodes , Samuel David Hilbert , Jean Carroll Fleischer , William Whitfield Parham
发明人： Max Allen Weaver , James John Krutak, Sr. , Brian Edison Maxwell , Gerry Foust Rhodes , Samuel David Hilbert , Jean Carroll Fleischer , William Whitfield Parham
IPC分类号： F21V900
CPC分类号： C09B31/02 , C09B1/32 , C09B1/585 , C09B1/62 , C09B5/14 , C09B29/0007 , C09B29/0025 , C09B29/08 , C09B29/36 , C09B69/101 , C09B69/106 , C09B69/109
摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.
摘要翻译：本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团，形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

5. 发明授权

US06197851B1 Polyester compositions containing near infrared absorbing materials to improve reheat 失效
标题翻译：含有近红外吸收材料以改善再热的聚酯组合物
公开(公告)号：US06197851B1
公开(公告)日：2001-03-06
申请号：US08918086
申请日：1997-08-25
申请人： Brian Edison Maxwell , Max Allen Weaver , James John Krutak, Sr. , William Whitfield Parham , Gerry Foust Rhodes , Jean Carroll Fleischer
发明人： Brian Edison Maxwell , Max Allen Weaver , James John Krutak, Sr. , William Whitfield Parham , Gerry Foust Rhodes , Jean Carroll Fleischer
IPC分类号： C08K534
CPC分类号： C08K5/0041 , B29C35/02 , B29C49/00 , B29K2067/00 , B29K2105/253 , C08L67/02
摘要： The present invention relates to a container preform comprising: a polymer suitable for the production of a stretch blow molded bottle and at least one organic or metallated organic near infrared absorbing compound which absorbs at least twice as much light between about 700 nm and about 1200 nm as between about 400 mn and about 700 nm wherein said near infrared absorbing compound is present in an amount sufficient to improve reheat rate of said preform. Suitable near infrared absorbing compounds include phthalocyanines, 2,3-napthalocyanines, squaraines (squaric acid derivatives), croconic acid derivatives, substituted indanthrones and certain highly substituted anthraquinones. A process for improving the reheat rate of a container preform is also disclosed.
摘要翻译：本发明涉及一种容器预制件，其包括：适于制造拉伸吹塑成型瓶子的聚合物和至少吸收约700nm至约1200nm光的至少两倍的有机或金属化有机近红外吸收化合物的聚合物约400nm至约700nm，其中所述近红外吸收化合物的存在量足以提高所述预型件的再加热速率。合适的近红外吸收化合物包括酞菁，2,3-萘酞菁，方酸（方酸衍生物），克罗酸衍生物，取代的茚满酮和某些高度取代的蒽醌。还公开了一种用于改善容器预制件的再加热速率的方法。

6. 发明授权

US06197223B1 Method for preparing light-absorbing polymeric compositions 失效
标题翻译：光吸收聚合物组合物的制备方法
公开(公告)号：US06197223B1
公开(公告)日：2001-03-06
申请号：US09320002
申请日：1999-05-26
申请人： Max Allen Weaver , James John Krutak, Sr. , Brian Edison Maxwell , Gerry Foust Rhodes , Samuel David Hilbert , Jean Carroll Fleischer , William Whitfield Parham
发明人： Max Allen Weaver , James John Krutak, Sr. , Brian Edison Maxwell , Gerry Foust Rhodes , Samuel David Hilbert , Jean Carroll Fleischer , William Whitfield Parham
IPC分类号： F21V900
CPC分类号： C09B31/02 , C09B1/32 , C09B1/585 , C09B1/62 , C09B5/14 , C09B29/0007 , C09B29/0025 , C09B29/08 , C09B29/36 , C09B69/101 , C09B69/106 , C09B69/109
摘要： The present invention recites a method comprising reacting in a solvent in the presence of a base a) at least one diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1200 nm and 99-0 mole % of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm, with b) an organic compound of Formula II X—B—X1 wherein B is a divalent organic radical to form a light absorbing composition comprising a mixture of a polymer having the formula and a cyclic compound having the general formula wherein B is as defined above; n is at least 2, m is 1, 2, 3 or 4 and A comprises the residue of a diacidic monomer comprising about 1 to 100 mole % of at least one light-absorbing monomer having a light absorption maximum between about 300 nm and about 1000 nm and wherein the remaining portion of A comprises the residue of a non-light absorbing monomer which does not absorb significant light at wavelengths above 300 nm or has a light absorption maximum below 300 nm.
摘要翻译：本发明描述了一种方法，包括在碱的存在下在溶剂中反应至少一种二酸单体，其包含约1至100摩尔％的至少一种光吸收单体，其光吸收最大值在约300nm至约1200 nm和99-0摩尔％的非光吸收单体，其不吸收波长高于300nm的显着光或具有300nm以下的光吸收最大值，b）式II的有机化合物，其中B是二价有机基团，形成包含具有下式的聚合物和具有通式化合物B的环状化合物的混合物的光吸收组合物如上所定义; n至少为2，m为1,2,3或4，A包含二酸单体的残基，该二酸单体包含约1至100摩尔％的至少一种光吸收单体的光吸收最大值在约300nm至约 1000nm，并且其中A的剩余部分包含不吸收波长高于300nm或在300nm以下的光吸收最大值的不吸收光的非光吸收单体的残基。

7. 发明授权

US5962557A Polyesters containing copolymerized substituted 1,4-bis(2,6-dialkylanilino)-9, 10-anthraquinones as colorants 失效
标题翻译：含有共聚取代的1,4-双（2,6-二烷基苯胺基）-9,10-蒽醌作为着色剂的聚酯
公开(公告)号：US5962557A
公开(公告)日：1999-10-05
申请号：US906643
申请日：1997-08-07
申请人： Max Allen Weaver , Brian Edison Maxwell , Gerry Foust Rhodes , James John Krutak, Sr.
发明人： Max Allen Weaver , Brian Edison Maxwell , Gerry Foust Rhodes , James John Krutak, Sr.
IPC分类号： C08J5/00 , C08G63/68 , C08G63/685 , C08J5/18 , C08K5/18 , C08L67/02 , C08L101/00 , D01F6/84 , C08G63/688 , C08B69/10
CPC分类号： C08G63/6856 , C08G63/68 , C08L101/00
摘要： A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.
摘要翻译：一种着色的聚酯共聚物，其包含至少一种直链热塑性聚酯前体和至少十份（重量）至少一种1,4-二（2,6-二烷基苯胺基）-9,10-蒽醌的残余物的反应产物着色剂。可以形成包含共聚物与至少一种热塑性聚合物混合的组合物。共聚物可以通过使至少一种热塑性聚酯前体与具有聚酯反应性基团的1,4-双（2,6-二烷基苯胺基）-9,10-蒽醌着色剂反应形成。

8. 发明授权

US6022920A Method for the production of clear bottles having improved reheat 有权
标题翻译：用于生产具有改进的再加热的透明瓶的方法
公开(公告)号：US6022920A
公开(公告)日：2000-02-08
申请号：US232307
申请日：1999-01-15
申请人： Brian Edison Maxwell , Philip Edward Gibson
发明人： Brian Edison Maxwell , Philip Edward Gibson
IPC分类号： C08L101/00 , C08K3/22
CPC分类号： C08K3/22 , C08K2003/2275
摘要： Disclosed herein is a thermoplastic polymer composition comprising a blend of a thermoplastic polymer admixed with from about 5 to 50 ppm black iron oxide particles, based on the amount of said thermoplastic polymer. The black iron oxide is admixed with the polymer in order to speed up the process of reheating parisons formed from the polymer during bottle manufacturing. The composition has the beneficial combination of a large percent reheat rate improvement (RIV) with only a small decrease in transparency (.DELTA.L*). The ratio of RIV/.DELTA.L* is significantly better than carbon black--polymer blends having similar RIV.
摘要翻译：本文公开了一种热塑性聚合物组合物，其包含基于所述热塑性聚合物的量的与约5至50ppm黑色氧化铁颗粒混合的热塑性聚合物的共混物。将黑色氧化铁与聚合物混合，以便在瓶子制造过程中加速由聚合物形成的型坯的再加热过程。该组合物具有大幅度的再热率提高率（RIV）的有益组合，透明度仅有很小的降低（DELTA L *）。 RIV / DELTA L *的比例明显优于具有相似RIV的炭黑 - 聚合物共混物。

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