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    • 10. 发明授权
    • Process for producing optical glass product
    • 光学玻璃制品生产工艺
    • US4528010A
    • 1985-07-09
    • US584968
    • 1984-02-29
    • Takao EdahiroNobuo InagakiShiro Kurosaki
    • Takao EdahiroNobuo InagakiShiro Kurosaki
    • C01B33/187C03B8/02C03B37/016C03C3/04C03C3/06C03C23/00G02B6/00C03B19/06
    • C03C23/008C03B37/016C03C3/06C03B2201/30C03B2201/50C03C2201/50C03C2203/24C03C2203/36Y10S65/901
    • A process for producing an optical glass product having a predetermined distribution of refractive index in the interior of the product is disclosed. The process comprises the steps of:(a) preparing an aqueous silicate solution containing from about 0.1 to about 0.6 mol/liter of Si (as SiO.sub.2) comprising silicic acid and at least one element selected from the group consisting of rubidium, thallium and cesium;(b) mixing the silicate solution with an acidic aqueous solution, and letting the two solutions react with each other for a period of time sufficient for polymerization to produce a porous gelled product wherein the silica particles are agglomerated;(c) leaching the gelled product with a liquid selected from the group consisting of water, a weakly acidic aqueous solution, an aqueous solution having an alkali metal salt dissolved therein and an aqueous solution of organic matter capable of dissolving Rb.sub.2 O, Cs.sub.2 O, or Tl.sub.2 O, unitl the center of the product starts to dissolve; and(d) drying the leached product in a predetermined atmosphere, and further heating the partially leached gelled product at a temperature sufficiently high to eliminate the particulate material but lower than the melting point of the silica.
    • 公开了一种在产品内部具有预定折射率分布的光学玻璃制品的制造方法。 该方法包括以下步骤:(a)制备含有约0.1至约0.6mol /升包含硅酸的Si(作为SiO 2)和选自铷,铊和铯中的至少一种元素的硅酸盐水溶液 ; (b)将硅酸盐溶液与酸性水溶液混合,并使两种溶液彼此反应一段足以聚合的时间以产生多孔凝胶产物,其中二氧化硅颗粒凝聚; (c)用选自水,弱酸性水溶液,溶解有碱金属盐的水溶液和能够溶解Rb 2 O,Cs 2 O或T 1/2的有机物水溶液的液体浸出凝胶状产品 ,产品中心开始溶解; 和(d)在预定的气氛中干燥浸出的产品,并且在足够高的温度下进一步加热部分浸出的凝胶产品以消除颗粒材料但低于二氧化硅的熔点。