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1. 发明授权

US4294806A Method for preventing the wear of a monolithic catalyst by dusts 失效
标题翻译：防止整体式催化剂磨损的方法
公开(公告)号：US4294806A
公开(公告)日：1981-10-13
申请号：US96561
申请日：1979-11-21
申请人： Kazunobu Abe , Shoichi Tamura , Tadao Nakatsuji
发明人： Kazunobu Abe , Shoichi Tamura , Tadao Nakatsuji
IPC分类号： B01D53/86 , B01J35/04 , C04B38/00 , C04B41/50 , B01D53/36
CPC分类号： C04B41/009 , B01D53/86 , B01D53/8628 , B01D53/8631 , B01J35/04 , C04B38/0006 , C04B41/5022 , B01J2219/32272 , B01J2219/32296 , B01J2219/32466 , Y10T428/24149
摘要： In a method for treating a gas containing dusts therein under a monolithic catalyst consisting of a ceramic support which is substantially porous throughout the structure, and has active ingredients uniformly dispersed therein and passages therethrough parallel to the flow of the gas for allowing the gas to pass therethrough, the improvement in which the catalyst has the sintered front portion or has a vitreous coating on the front portion. Alternatively, the improvement in which a metal or sintered ceramic lid having openings therethrough is fixed onto the front face of the catalyst with the passages in alignment with the openings of the lid.
摘要翻译：在由整体式催化剂组成的整体式催化剂处理含有灰尘的气体的方法中，所述整体催化剂由整个结构中基本上是多孔的陶瓷载体组成，并且具有均匀分散在其中的活性成分和与气体流平行的通道，以允许气体通过其中催化剂具有烧结前部分或在前部具有玻璃质涂层的改进。或者，其中具有开口的金属或烧结陶瓷盖的固定在催化剂的正面上，其中通道与盖的开口对准。

2. 发明授权

US4520124A Method for producing a catalytic structure for the reduction of nitrogen oxides 失效
标题翻译：制备用于还原氮氧化物的催化结构的方法
公开(公告)号：US4520124A
公开(公告)日：1985-05-28
申请号：US531468
申请日：1983-09-12
申请人： Kazunobu Abe , Tadao Nakatsuji
发明人： Kazunobu Abe , Tadao Nakatsuji
IPC分类号： B01D53/94 , B01J21/06 , B01J23/22 , B01J23/30 , B01J35/06 , B01J37/02 , B01J35/04 , B01J21/12 , B01J21/14 , B01J31/28
CPC分类号： B01J23/30 , B01D53/9418 , B01J35/06 , B01J37/024 , B01D2251/2062 , B01D2255/20707 , B01D2255/9202 , B01D2255/9207 , B01J21/063 , B01J23/22
摘要： A method is provided for producing a catalytic structure in the form of sheet or honeycomb for the gas phase reduction of nitrogen oxides. The method comprises: beating an inorganic fiber in water to form a slurry; forming the slurry into a sheet by paper-making means and drying the sheet; impregnating the sheet or a honeycomb structure manufactured therefrom which has a porosity of 60-85% with an impregnating slurry which contains titanium dioxide or its precursor in a concentration at least of 100 g/l and has a viscosity of 5-250 cps. at normal temperatures, drying, and when necessary calcining the structure; and then immersing the structure in a solution containing a catalytically active agent or its precursor, drying and calcining the structure, thereby to provide a porous catalytic structure having titanium dioxide and the catalytically active agent substantially uniformly dispersed and supported therein.
摘要翻译：提供了一种制备用于氮氧化物气相还原的片状或蜂窝形式的催化结构的方法。该方法包括：在水中打无机纤维以形成浆料; 通过造纸装置将浆料形成片材并干燥片材; 用含有二氧化钛或其前体的含有二氧化钛或其前体的浓度至少为100g / l且具有5-250cps的粘度的孔隙率为60-85％的片材或蜂窝状结构浸渍。在正常温度下干燥，并在必要时煅烧结构物; 然后将结构物浸渍在含有催化活性剂或其前体的溶液中，干燥并煅烧该结构，从而提供具有二氧化钛和催化活性剂的多孔催化结构，其基本均匀地分散并负载在其中。

3. 发明授权

US4297248A Method for packing catalysts 失效
标题翻译：填料催化剂的方法
公开(公告)号：US4297248A
公开(公告)日：1981-10-27
申请号：US167099
申请日：1980-07-08
申请人： Kazunobu Abe , Tadao Nakatsuji , Toshikatsu Umaba
发明人： Kazunobu Abe , Tadao Nakatsuji , Toshikatsu Umaba
IPC分类号： B01D53/94 , B01D53/86 , B01J19/32 , B01J35/04
CPC分类号： B01J19/32 , B01J35/04 , B01J2219/32268 , B01J2219/32272 , B01J2219/32275 , B01J2219/32296 , B01J2219/32466
摘要： A method for packing catalysts comprising packing the catalysts having through-holes in the direction of the flow of the gas with plurality of them being arranged in the direction of the flow of the gas through the catalyst-packed layers, characterized by arranging the catalysts in such manner that the sections of the connecting parts in the direction of the flow of the gas do not lie on the same plane as at least one of the above sections of the connecting parts formed by the adjacent catalysts.
摘要翻译：一种用于包装催化剂的方法，包括在气体流动方向上填充具有通孔的催化剂，其中多个催化剂沿着气体流过催化剂填充层的方向排列，其特征在于将催化剂连接部分在气体流动方向上的部分不与由相邻催化剂形成的连接部分的至少一个上述部分位于同一平面上。

4. 发明授权

US4280926A Method for producing a catalyst and a carrier therefor 失效
标题翻译：催化剂及其载体的制造方法
公开(公告)号：US4280926A
公开(公告)日：1981-07-28
申请号：US72599
申请日：1979-09-05
申请人： Kazunobu Abe , Tadao Nakatsuji
发明人： Kazunobu Abe , Tadao Nakatsuji
IPC分类号： B01D53/94 , B01J35/04 , B01J35/06 , F01N3/28 , B01J21/12 , B01J21/14 , B01J31/28
CPC分类号： F01N3/2828 , B01D53/9418 , B01J35/04 , B01J35/06 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2255/9202 , F01N2330/06 , Y10T428/24149
摘要： A method is provided for producing a catalyst and a carrier therefor in the form of sheet or honeycomb. The method comprises: beating a heat-resistant fiber such as asbesto fiber in water to form a slurry; mixing the slurry with a catalytically active agent, a carrier material therefor and/or their precursors to fix such materials in the fiber, thus forming a stock; and forming the stock into a sheet and drying the same. The sheet thus obtained may be formed into a honeycomb structure with an improved adhesive.
摘要翻译：提供了一种用于以片状或蜂窝形式制备催化剂及其载体的方法。该方法包括：将水中的耐热纤维如石棉纤维打浆以形成浆料; 将浆料与催化活性剂，其载体材料和/或其前体混合以将这些材料固定在纤维中，从而形成原料; 并将原料形成片材并使其干燥。由此获得的片可以形成为具有改进的粘合剂的蜂窝结构。

5. 发明授权

US4416800A Method for producing a catalyst and a carrier therefor including heat-resistant fibers 失效
标题翻译：用于制造包含耐热纤维的催化剂及其载体的方法
公开(公告)号：US4416800A
公开(公告)日：1983-11-22
申请号：US245687
申请日：1981-03-19
申请人： Kazunobu Abe , Tadao Nakatsuji
发明人： Kazunobu Abe , Tadao Nakatsuji
IPC分类号： B01D53/94 , B01J35/04 , B01J35/06 , F01N3/28 , B01J21/12 , B01J21/14 , B01J31/28
CPC分类号： F01N3/2828 , B01D53/9418 , B01J35/04 , B01J35/06 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2255/9202 , F01N2330/06 , Y10T428/24149
摘要： A method is provided for producing a catalyst and a carrier therefor in the form of sheet or honeycomb. The method comprises: beating a heat-resistant fiber such as asbesto fiber in water to form a slurry; mixing the slurry with a catalytically active agent, a carrier material therefor and/or their precursors to fix such materials in the fiber, thus forming a stock; and forming the stock into a sheet and drying the same. The sheet thus obtained may be formed into a honeycomb structure with an improved adhesive.
摘要翻译：提供了一种用于以片状或蜂窝形式制备催化剂及其载体的方法。该方法包括：将水中的耐热纤维如石棉纤维打浆以形成浆料; 将浆料与催化活性剂，其载体材料和/或其前体混合以将这些材料固定在纤维中，从而形成原料; 并将原料形成片材并使其干燥。由此获得的片可以形成为具有改进的粘合剂的蜂窝结构。

6. 发明授权

US08673809B2 Low level noble metal-supporting three-way catalyst 有权
标题翻译：低级贵金属支撑三元催化剂
公开(公告)号：US08673809B2
公开(公告)日：2014-03-18
申请号：US13050702
申请日：2011-03-17
申请人： Tadao Nakatsuji , Kazuya Inada , Yuji Isogai , Kiyoshi Tanaami
发明人： Tadao Nakatsuji , Kazuya Inada , Yuji Isogai , Kiyoshi Tanaami
IPC分类号： B01J23/00 , B01J21/00
CPC分类号： F01N3/101 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/2068 , B01D2255/207 , B01D2255/20707 , B01D2255/20715 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/9022 , B01D2255/911 , B01D2258/014 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/20 , B01J23/30 , B01J23/40 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J37/0244 , B01J37/038 , B01J2523/36 , B01J2523/3718 , B01J2523/3725 , B01J2523/41 , B01J2523/48 , B01J2523/56 , B01J2523/69 , B01J2523/822 , B01J2523/824 , B01J2523/828 , F01N3/10 , F01N2370/02 , F01N2510/0684 , Y02T10/22
摘要： The invention provides a catalyst for catalytically removing three components, which are carbon monoxide, hydrocarbons and nitrogen oxides, from combustion exhaust gas generated by combusting fuel at around the stoichiometric air to fuel ratio. The catalyst includes: (A) a first catalyst component including at least rhodium, platinum, or palladium in a content of 0.01 to 0.5% by weight; and (B) a second catalyst component, which is the remainder, including a composite oxide or a mixed oxide including (a) at least zirconium oxide or titanium oxide, and (b) an oxide of at least praseodymium, yttrium, neodymium, tungsten, niobium, silicon, or aluminum, wherein the content of the oxide (a) in the composite oxide or the mixed oxide is in a range of 70 to 95% by weight. The invention further provides a two-layer catalyst that includes a surface catalyst layer containing the above-mentioned catalyst.
摘要翻译：本发明提供了一种用于催化除去三氧化碳，碳氢化合物和氮氧化物的三种组分的催化剂，所述燃烧废气是通过在化学计量空气燃料比附近燃烧燃料而产生的。所述催化剂包括：（A）至少包含含量为0.01至0.5重量％的铑，铂或钯的第一催化剂组分; 和（B）第二催化剂组分，其余为包括复合氧化物或混合氧化物，其包括（a）至少氧化锆或氧化钛，和（b）至少镨，钇，钕，钨的氧化物，铌，硅或铝，其中复合氧化物或混合氧化物中的氧化物（a）的含量在70至95重量％的范围内。本发明还提供一种包含含有上述催化剂的表面催化剂层的双层催化剂。

7. 发明授权

US07794679B2 Catalyst and method for purification of diesel engine exhaust gas 有权
标题翻译：催化剂和柴油发动机废气净化方法
公开(公告)号：US07794679B2
公开(公告)日：2010-09-14
申请号：US12008609
申请日：2008-01-11
申请人： Tadao Nakatsuji , Naoki Oya , Naohiro Sato
发明人： Tadao Nakatsuji , Naoki Oya , Naohiro Sato
IPC分类号： B01D53/56 , B01D53/94 , B01J29/00
CPC分类号： F01N3/0807 , F01N2570/14 , Y02A50/2344 , Y02T10/20
摘要： The invention provides a catalyst for catalytically reducing nitrogen oxides in diesel engine exhaust gas by use of unburnt carbon contained in the diesel engine exhaust gas as a reducing agent, the catalyst comprising: (a) an acid zeolite, or (b) an alkali metal- and/or alkaline earth metal-containing zeolite, or (c) a rare earth metal-containing zeolite, or (d) a zeolite containing at least one transition metal selected from Fe, Co, Ni and Cu.
摘要翻译：本发明提供了一种用于通过使用柴油机废气中所含的未燃烧碳作为还原剂来催化还原柴油发动机废气中的氮氧化物的催化剂，所述催化剂包含：（a）酸性沸石，或（b）碱金属 - 和/或含碱土金属的沸石，或（c）含稀土金属的沸石，或（d）含有至少一种选自Fe，Co，Ni和Cu的过渡金属的沸石。

8. 发明授权

US07585477B2 Catalyst and method for catalytic reduction of nitrogen oxides 失效
标题翻译：用于催化还原氮氧化物的催化剂和方法
公开(公告)号：US07585477B2
公开(公告)日：2009-09-08
申请号：US10578664
申请日：2004-11-08
申请人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato , Tomoko Morita , Katsuji Wada
发明人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato , Tomoko Morita , Katsuji Wada
IPC分类号： B01D53/56 , B01D53/94 , B01J23/00 , B01J23/10 , B01J23/16 , B01J23/38
CPC分类号： B01D53/9422 , B01D2255/102 , B01D2255/20 , B01D2255/206 , B01J23/652 , B01J29/7415 , B01J29/7615 , B01J29/7815 , B01J35/0006
摘要： The invention provides a catalyst for catalytic reduction of nitrogen oxides contained in exhaust gases wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: (A) a catalyst component A comprising (c) ceria or (d) praseodymium oxide or (e) an oxide and/or a composite oxide of at least two elements selected from the group consisting of cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum; (B) a catalyst component B comprising (d) a noble metal catalyst component selected from the group consisting of platinum, rhodium, palladium and oxides thereof and (e) a carrier; and (C) a catalyst component C comprising (f) a solid acid, and (g) a solid acid supporting an oxide of at least one element selected from the group consisting of vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese.
摘要翻译：本发明提供一种用于催化还原废气中所含的氮氧化物的催化剂，其中燃料在周期性富/贫条件下被供应并经历燃烧，并使得到的废气与其接触，该催化剂包括：（A）催化剂组分 A包括（c）二氧化铈或（d）氧化镨或（e）选自铈，锆，镨，钕，铽，钐，钆和镧中的至少两种元素的氧化物和/或复合氧化物 ; （B）催化剂组分B，其包含（d）选自铂，铑，钯及其氧化物的贵金属催化剂组分和（e）载体; 和（C）包含（f）固体酸的催化剂组分C，和（g）支持选自钒，钨，钼，铜，铁，钴，镍，和锰。

9. 发明申请

US20090084090A1 Catalyst and Catalyst Structure for Reduction of Nitrogen Oxides, and Method for Catalytic Reduction of Nitrogen Oxides 审中-公开
标题翻译：用于还原氮氧化物的催化剂和催化剂结构，以及用于催化还原氮氧化物的方法
公开(公告)号：US20090084090A1
公开(公告)日：2009-04-02
申请号：US11918222
申请日：2006-04-06
申请人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato
发明人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato
IPC分类号： F01N3/20 , B01D53/86 , B01D53/94 , B01J23/10
CPC分类号： B01J23/63 , B01D53/9422 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/2063 , B01D2255/2065 , B01D2255/2066 , B01D2255/2068 , B01D2255/20715 , B01D2255/9022 , B01D2255/908 , B01D2255/91 , B01D2258/012 , B01J23/002 , B01J23/10 , B01J23/64 , B01J23/8933 , B01J29/18 , B01J29/7007 , B01J29/76 , B01J35/1019 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J37/033 , B01J2523/00 , B01J2523/37 , B01J2523/3712 , B01J2523/48
摘要： The invention provides a catalyst and a catalyst structure for catalytic reduction of nitrogen oxides contained in exhaust gas wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: an outer catalyst layer comprising an outer catalyst component A which comprises at least one selected from a solid acid, and a solid acid supporting oxides and/or ions of at least one element selected from vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese, and an inner catalyst layer comprising an inner catalyst component which comprises at least one noble metal catalyst component B selected from platinum, rhodium, palladium and an oxide thereof and a catalyst component C comprising ceria or praseodymium oxide or a mixture of oxides and/or a composite oxide of at least two elements selected from cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum. The invention further provides a method for catalytic reduction of nitrogen oxides by contacting the nitrogen oxides with the catalyst.
摘要翻译：本发明提供催化剂和用于催化还原废气中所含的氮氧化物的催化剂结构，其中在周期性富/贫条件下供应燃料并进行燃烧，并使所得废气与其接触，该催化剂包括：外部催化剂层，其包含外部催化剂组分A，其包含选自固体酸中的至少一种和支持选自钒，钨，钼，铜，铁，钴，镍中的至少一种元素的氧化物和/或离子的固体酸，和锰和包含内催化剂组分的内催化剂层，其包含至少一种选自铂，铑，钯及其氧化物的贵金属催化剂组分B和包含二氧化铈或氧化镨的催化剂组分C或氧化物和/ 或选自铈，锆，镨，钕，铽，钐中的至少两种元素的复合氧化物，钆和镧。本发明还提供了通过使氮氧化物与催化剂接触来还原氮氧化物的方法。

10. 发明申请

US20070274889A1 Catalyst and Method for Catalytic Reduction of Nitrogen Oxides 失效
标题翻译：用于催化还原氮氧化物的催化剂和方法
公开(公告)号：US20070274889A1
公开(公告)日：2007-11-29
申请号：US10578664
申请日：2004-11-08
申请人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato , Tomoko Morita , Katsuji Wada
发明人： Tadao Nakatsuji , Norio Suzuki , Hiroshi Ohno , Naohiro Sato , Tomoko Morita , Katsuji Wada
IPC分类号： B01D53/56 , B01J23/652 , B01J29/22 , B01J29/24 , B01J29/76
CPC分类号： B01D53/9422 , B01D2255/102 , B01D2255/20 , B01D2255/206 , B01J23/652 , B01J29/7415 , B01J29/7615 , B01J29/7815 , B01J35/0006
摘要： The invention provides a catalyst for catalytic reduction of nitrogen oxides contained in exhaust gases wherein fuel is supplied and subjected to combustion under periodic rich/lean conditions and the resulting exhaust gases are brought into contact therewith, which catalyst comprises: (A) a catalyst component A comprising (c) ceria or (d) praseodymium oxide or (e) an oxide and/or a composite oxide of at least two elements selected from the group consisting of cerium, zirconium, praseodymium, neodymium, terbium, samarium, gadolinium and lanthanum; (B) a catalyst component B comprising (d) a noble metal catalyst component selected from the group consisting of platinum, rhodium, palladium and oxides thereof and (e) a carrier; and (C) a catalyst component C comprising (f) a solid acid, and (g) a solid acid supporting an oxide of at least one element selected from the group consisting of vanadium, tungsten, molybdenum, copper, iron, cobalt, nickel and manganese. The catalyst reduces NOx contained in exhaust gases wherein fuel is supplied and subjected to combustion with a periodic rich/lean excursions, whereby NOx is generated in the exhaust gases, with high durability in a wide temperature range even in the presence of oxygen, sulfur oxides or water.
摘要翻译：本发明提供一种用于催化还原废气中所含的氮氧化物的催化剂，其中燃料在周期性富/贫条件下被供应并经历燃烧，并使得到的废气与其接触，该催化剂包括：（A）催化剂组分 A包括（c）二氧化铈或（d）氧化镨或（e）选自铈，锆，镨，钕，铽，钐，钆和镧中的至少两种元素的氧化物和/或复合氧化物 ; （B）催化剂组分B，其包含（d）选自铂，铑，钯及其氧化物的贵金属催化剂组分和（e）载体; 和（C）包含（f）固体酸的催化剂组分C，和（g）支持选自钒，钨，钼，铜，铁，钴，镍，和锰。催化剂还原废气中所含的NOx，其中燃料被供给并经历周期性的富/贫漂移的燃烧，从而在废气中产生NOx，即使在存在氧，硫氧化物的情况下，在宽温度范围内具有高耐久性或水。

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