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    • 1. 发明申请
    • Fungicidal mixtures II
    • 杀菌混合物II
    • US20100267555A1
    • 2010-10-21
    • US12742756
    • 2008-11-14
    • Jens RennerSarah UlmschhneiderJochen DietzEgon Haden
    • Jens RennerSarah UlmschhneiderJochen DietzEgon Haden
    • A01C1/06A01N43/40A01N43/54A01N43/88A01P3/00A01P7/04
    • A01N43/40A01N37/34A01N43/50A01N43/54A01N43/653A01N43/88A01N47/12A01N47/18A01N47/38A01N2300/00
    • The present invention relates to mixtures of fungicidally active compounds comprising at least one substituted 3-hydroxyl-3-(3-pyridyl)propanoate compound of the formula I wherein: X1 and X2 are hydrogen or X1 together with X2 form a covalent bond; R1 is H, CN, C1-C6-alkyl, C2-C6-alkynyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl, hetaryl-C1-C4-alkyl, hetaryloxy-C1-C4-alkyl, hetarylthio-C1-C4-alkyl or heteroaryl, wherein the cyclic moieties of the last eight radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro; A is a covalent bond or C1-C4-alkylen, which is unsubstituted or which may carry a substitutent selected from C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and cyano; Ar is aryl or heteroaryl, wherein the cyclic moieties of the aromatic radicals are unsubstituted or substituted with 1, 2 or 3 radicals Ra, where the radicals Ra are identical or different and selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano, nitro, aryl, hetaryl, aryloxy, hetaryloxy, aryloxy-C1-C4-alkyl and hetaryloxy-C1-C4-alkyl, wherein the cyclic moieties of the six last mentioned radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, cyano and nitro; or a tautomer or a salt thereof. and at least one further fungicidally active compound II.
    • 本发明涉及杀真菌活性化合物的混合物,其包含至少一种式I的取代的3-羟基-3-(3-吡啶基)丙酸酯化合物,其中:X 1和X 2是氢或X 1与X 2一起形成共价键; R 1是H,CN,C 1 -C 6烷基,C 2 -C 6炔基,C 1 -C 6烷氧基-C 1 -C 6烷基,C 1 -C 6烷硫基-C 1 -C 6烷基,C 1 -C 6卤代烷基, C 1 -C 4烷基,芳氧基-C 1 -C 4 - 烷基,芳硫基-C 1 -C 4 - 烷基,芳基,杂芳基-C 1 -C 4烷基,芳氧基-C 1 -C 4 - 烷基,杂芳硫基-C 1 -C 4 - C4-烷基或杂芳基,其中最后八个基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 2 -C 4 - 炔基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基,C 1 -C 4烷基磺酰基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基和硝基; A是共价键或C1-C4-亚烷基,其是未取代的或可以携带选自C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基和氰基的取代基; Ar是芳基或杂芳基,其中芳族基团的环状部分是未取代的或被1,2或3个基团R a取代,其中基团R a相同或不同并且选自卤素,C 1 -C 4烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基,硝基,芳基,杂芳基,芳氧基, 芳氧基-C 1 -C 4烷基和芳基氧基-C 1 -C 4烷基,其中六个最后提到的基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 1 -C 4 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,氰基和硝基; 或其互变异构体或其盐。 和至少一种其它杀真菌活性化合物II。
    • 5. 发明申请
    • Fungicidal Mixtures III
    • 杀菌混合物III
    • US20100273649A1
    • 2010-10-28
    • US12742487
    • 2008-11-14
    • Jens RennerSarah UlmschneiderJochen DietzEgon Haden
    • Jens RennerSarah UlmschneiderJochen DietzEgon Haden
    • A01N25/26A01N43/40A01N43/54A01P3/00
    • A01N43/40A01N37/34A01N37/50A01N43/50A01N43/54A01N43/653A01N47/04A01N47/12A01N47/14A01N47/24A01N61/00A01N2300/00
    • The present invention relates to mixtures of fungicidally active compounds comprising at least one substituted 2-[hydroxyl(pyridine-3-yl)methyl]acrylate compound of the formula I wherein: R1 is H, C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl or heteroaryl, wherein the cyclic moieties of the last two radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, cyano and nitro; A is a covalent bond or C1-C4-alkylen, which is unsubstituted or which may carry a substitutent selected from C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and cyano; Ar is aryl or heteroaryl, wherein the cyclic moieties of the aromatic radicals are unsubstituted or substituted with 1, 2 or 3 radicals Ra, where the radicals Ra are identical or different and selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano, nitro, aryl, hetaryl, aryloxy, hetaryloxy, aryloxy-C1-C4-alkyl and hetaryloxy-C1-C4-alkyl, wherein the cyclic moieties of the six last mentioned radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, cyano and nitro; or a salt thereof; and at least one further fungicidally active compound II.
    • 本发明涉及包含至少一种式I的取代的2- [羟基(吡啶-3-基)甲基]丙烯酸酯化合物的杀真菌活性化合物的混合物,其中:R1是H,C1-C6-烷基,C1-C6- 烷氧基-C 1 -C 6 - 烷基,C 1 -C 6卤代烷基,芳基或杂芳基,其中最后两个基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基, C 4 - 炔基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,氰基和硝基; A是共价键或C1-C4-亚烷基,其是未取代的或可以携带选自C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基和氰基的取代基; Ar是芳基或杂芳基,其中芳族基团的环状部分是未取代的或被1,2或3个基团R a取代,其中基团R a相同或不同并且选自卤素,C 1 -C 4烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基,硝基,芳基,杂芳基,芳氧基, 芳氧基-C 1 -C 4烷基和芳基氧基-C 1 -C 4烷基,其中六个最后提到的基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 1 -C 4 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,氰基和硝基; 或其盐; 和至少一种其它杀真菌活性化合物II。
    • 6. 发明申请
    • Fungicidal Mixtures Comprising a Substituted 3-Hydroxymethylpyridine and a Further Fungicidal Compound
    • 包含取代的3-羟甲基吡啶和另外的杀真菌化合物的杀真菌混合物
    • US20100273650A1
    • 2010-10-28
    • US12742717
    • 2008-11-14
    • Jens RennerSarah UlmschneiderJochen DietzEgon Haden
    • Jens RennerSarah UlmschneiderJochen DietzEgon Haden
    • A01C1/06A61K31/4427A61K31/535
    • A01N43/40A01N2300/00
    • The present invention relates to mixtures of fungicidally active compounds comprising at least one substituted 3-hydroxymethylpyridin compound formula I and at least one further fungicidally active compound II. wherein: X is O, S or NR4; R1 is C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro; R2 is H or C1-C4-alkyl; R3 is C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro; R4 is H, C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C1-C6-haloalkyl, aryl-C1-C4-alkyl, aryloxy-C1-C4-alkyl, arylthio-C1-C4-alkyl, aryl or heteroaryl, wherein the cyclic moieties of the last five radicals are unsubstituted or substituted with 1, 2 or 3 radicals selected from halogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, C1-C4-haloalkoxy, C1-C4-haloalkylthio, cyano and nitro;
    • 本发明涉及杀真菌活性化合物的混合物,其包含至少一种取代的3-羟甲基吡啶化合物式I和至少一种其它杀真菌活性化合物II。 其中:X是O,S或NR4; R 1是C 1 -C 6烷基,C 1 -C 6烷氧基-C 1 -C 6烷基,C 1 -C 6卤代烷基,芳基-C 1 -C 4烷基,芳氧基-C 1 -C 4烷基,芳硫基-C 1 -C 4烷基, 芳基或杂芳基,其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基和硝基; R2是H或C1-C4-烷基; R 3是C 1 -C 6烷基,C 1 -C 6烷氧基-C 1 -C 6烷基,C 1 -C 6卤代烷基,芳基-C 1 -C 4烷基,芳氧基-C 1 -C 4烷基,芳硫基-C 1 -C 4烷基, 芳基或杂芳基,其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基和硝基; R 4是H,C 1 -C 6烷基,C 1 -C 6烷氧基-C 1 -C 6烷基,C 1 -C 6卤代烷基,芳基-C 1 -C 4烷基,芳氧基-C 1 -C 4烷基,芳硫基-C 1 -C 4 - 烷基,芳基或杂芳基,其中最后五个基团的环状部分是未取代的或被1,2或3个选自卤素,C 1 -C 4 - 烷基,C 2 -C 4 - 烯基,C 2 -C 4 - 炔基,C 1 -C 4 - C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,氰基和硝基;