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    • 9. 发明申请
    • PATTERNABLE LIQUID CRYSTAL POLYMER COMPRISING THIO-ETHER UNITS
    • 包含THIO-ETHER单位的方形液晶聚合物
    • US20100059709A1
    • 2010-03-11
    • US12515918
    • 2007-12-11
    • Thomas BachelsIzabela BuryGuy MarckHubert SeiberlePeggy StuderStefano Tugulu
    • Thomas BachelsIzabela BuryGuy MarckHubert SeiberlePeggy StuderStefano Tugulu
    • C08G75/02C09K19/38
    • C09K19/3804C09K19/38C09K19/54C09K2019/0448C09K2219/03
    • The present invention relates to a photo-polymerized, patterned or unpatterned liquid crystal polymer, especially a liquid crystal polymer film or a liquid crystal polymer network, comprising thio-ether units of formula (I) * covalent bond, which links the unit of formula (I) to the residue of the polymer wherein LC1 is selected from the group of liquid crystal residues, X1 is selected from the group of aliphatic organic residues, and n1 is an integer ≧0 and m1 is an integer ≧0; with the proviso that if n1 is 0, then m1 is >0, and if m1 is 0, then n1>0; which is prepared in an atmosphere containing oxygen, preferably with an amount of 0.1≦oxygen 50%, more preferably 1≦oxygen≦25%, most preferably in air; with the proviso that polymer dispersed liquid crystals are excluded. Further, this invention relates to a composition used for the preparation of that photo-polymerized liquid crystal polymer of the invention, to processes of the preparation of that liquid crystal polymer and to its use.
    • 本发明涉及光聚合,图案化或未图案化的液晶聚合物,特别是液晶聚合物膜或液晶聚合物网络,其包含式(I)*共价键的硫醚单元,其将式 (I)所示的聚合物残基,其中LC1选自液晶残基,X1选自脂族有机残基,n1为整数≥0,m1为整数≥0; 条件是如果n1为0,则m1> 0,如果m1为0,则n1> 0; 其在含有氧气的气氛中制备,优选为0.1< NlE;氧气50%,更优选1& NlE;氧气& 25%,最优选在空气中; 条件是排除聚合物分散的液晶。 此外,本发明涉及用于制备本发明的光聚合液晶聚合物的组合物,该液晶聚合物的制备方法及其用途。