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1. 发明授权

US5910600A Bisphosphite compound, process for its production and hydroformylation process employing the bisphosphite compound 失效
标题翻译：二亚磷酸酯化合物，其生产方法和使用双亚磷酸酯化合物的加氢甲酰化方法
公开(公告)号：US5910600A
公开(公告)日：1999-06-08
申请号：US845835
申请日：1997-04-28
申请人： Hisao Urata , Hiroaki Itagaki , Eitaro Takahashi , Yasuhiro Wada , Yoshiyuki Tanaka , Yasukazu Ogino
发明人： Hisao Urata , Hiroaki Itagaki , Eitaro Takahashi , Yasuhiro Wada , Yoshiyuki Tanaka , Yasukazu Ogino
IPC分类号： C07C45/50 , C07C45/72 , C07C45/74 , C07F9/145 , C07F9/572 , C07F9/58 , C07F9/60 , C07F9/64 , C07F9/6506 , C07F9/6509 , C07F9/6512 , C07F9/6541 , C07F9/655 , C07F9/12
CPC分类号： C07F9/65517 , C07C45/50 , C07C45/72 , C07C45/74 , C07F9/145 , C07F9/5728 , C07F9/585 , C07F9/60 , C07F9/64 , C07F9/65068 , C07F9/650994 , C07F9/65125 , C07F9/65128 , C07F9/6541
摘要： A bisphosphite compound of the following formula (A): ##STR1## wherein --Ar--Ar-- is a bisarylene group represented by any one of the formulae (A-I) to (A-III) defined in the specification, and each of Z.sub.1 to Z.sub.4 is a C.sub.4-20 aromatic or heteroaromatic group which may have a substituent, wherein each of substituents on carbon atoms of an aromatic ring adjacent to the carbon atom bonded to the oxygen atom in each of Z.sub.1 to Z.sub.4, is a C.sub.0-2 group, and each pair of Z.sub.1 and Z.sub.2, and Z.sub.3 and Z.sub.4, are not bonded to each other.
摘要翻译：下式（A）的双亚磷酸酯化合物：其中-Ar-Ar-是由说明书中定义的式（AI）至（A-III）中任一个表示的双亚芳基，Z1至Z4各自为可以具有取代基的C 4-20芳族或杂芳族基，其中与Z1〜Z4各自键合的氧原子上的碳原子相邻的芳香环的碳原子上的各取代基为C0-2基，各自为一对Z1和Z2以及Z3和Z4彼此不接合。

2. 发明授权

US4704458A Process for the epimerization of aminated phthalideisoquinolines 失效
标题翻译：胺化苯酞异喹啉的差向异构化方法
公开(公告)号：US4704458A
公开(公告)日：1987-11-03
申请号：US694160
申请日：1985-01-23
申请人： Yoshiyuki Takeda , Osamu Kawashima , Shiro Furukawa , Yasukazu Ogino
发明人： Yoshiyuki Takeda , Osamu Kawashima , Shiro Furukawa , Yasukazu Ogino
IPC分类号： C07D317/00 , C07D491/04 , C07D491/056 , C07D217/04 , C07D307/34
CPC分类号： C07D491/04
摘要： Disclosed herein is an improved process for preparing 1RS-3'RS epimer of aminated phthalideisoquinolines represented by the general formula (I): ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen atom or a lower alkoxy group, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently hydrogen atom, amino group or a lower alkoxy group with at least one of R.sup.3 -R.sup.6 being amino group, and R.sup.7 is a lower alkyl group. The improvement comprises, after having reduced a mixture of epimers of corresponding nitro compounds of the general formula (I) wherein the amino group is replaced by nitro group into the amino compounds (I), treating said amino compound at a temperature in the range of 20.degree.-100.degree. C. in an aliphatic lower alcohol in the presence of an alkali to epimerize 1RS-3'SR epimer of said amino compound into said 1RS-3'RS epimer thereof.
摘要翻译：本文公开了一种用于制备由通式（I）表示的胺化苯并二氮杂异喹啉的1RS-3'RS差向异构体的改进方法：其中R 1和R 2独立地为氢原子或低级烷氧基，R 3，R 4， R 5和R 6独立地为氢原子，氨基或低级烷氧基，其中R 3 -R 6为氨基，R7为低级烷基。改进之处在于将氨基被硝基替代为氨基化合物（I）的通式（I）的相应硝基化合物的差向异构体混合物在下列温度范围内处理： 20℃-100℃，在脂肪族低级醇中，在碱的存在下使所述氨基化合物的1RS-3'SR差向异构体差向异构化为所述1RS-3'RS差向异构体。

3. 发明授权

US5516929A Method for catalytic asymmetric dihydroxylation of olefins using heterocyclic chiral ligands 失效
标题翻译：使用杂环手性配体的烯烃催化不对称二羟基化的方法
公开(公告)号：US5516929A
公开(公告)日：1996-05-14
申请号：US17960
申请日：1993-02-12
申请人： K. Barry Sharpless , Matthias Beller , Brent Blackburn , Yasuhiro Kawanami , Hoi-Lun Kwong , Yasukazu Ogino , Tomoyuki Shibata , Tatsuzo Ukita , Lisa Wang
发明人： K. Barry Sharpless , Matthias Beller , Brent Blackburn , Yasuhiro Kawanami , Hoi-Lun Kwong , Yasukazu Ogino , Tomoyuki Shibata , Tatsuzo Ukita , Lisa Wang
IPC分类号： C07C29/48 , C07C67/31 , C07D453/02 , C07D453/04 , C07C29/04
CPC分类号： C07C67/31 , C07C29/48 , C07D453/02 , C07D453/04 , C07B2200/07 , C07C2101/14 , C07C2101/18 , C07C2102/10
摘要： Osmium-catalyzed methods of addition to an olefin are discussed. In the method of asymmetric dihydroxylation of the present invention, an olefin, a chiral ligand, an organic solvent, water, an oxidant and an osmium-containing compound are combined. In the method of asymmetric oxyamination of the present invention, an olefin, a chiral ligand, an organic solvent, water, a metallochloramine derivative, an osmium-containing compound and, optionally, a tetraalkyl ammonium compound are combined. In the method of asymmetric diamination of the present invention, an olefin, a chiral ligand, an organic solvent, a metallo-chloramine derivative, an amine and an osmium-containing compound are combined. In one embodiment, an olefin, a chiral ligand which is a polymeric dihydroquinidine derivative or a dihydroquinine derivative, acetone, water, a base, an oxidant and osmium tetroxide are combined to effect asymmetric dihydroxylation of the olefin.
摘要翻译：讨论了添加到烯烃中的锇催化方法。在本发明的不对称二羟基化方法中，合并烯烃，手性配体，有机溶剂，水，氧化剂和含锇化合物。在本发明的不对称氧化法的方法中，合并烯烃，手性配体，有机溶剂，水，金属氯胺衍生物，含锇化合物和任选的四烷基铵化合物。在本发明的不对称二氨基化方法中，合并烯烃，手性配体，有机溶剂，金属氯胺衍生物，胺和含锇化合物。在一个实施方案中，将烯烃，作为聚合二氢奎尼丁衍生物或二氢喹啉衍生物的手性配体，丙酮，水，碱，氧化剂和四氧化锇组合以实现烯烃的不对称二羟基化。

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