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1. 发明授权

US06759107B1 Oxygen absorbing compositions and articles 失效
标题翻译：吸氧组合物和制品
公开(公告)号：US06759107B1
公开(公告)日：2004-07-06
申请号：US09612259
申请日：2000-07-07
申请人： Shinji Tai , Masakazu Nakaya , Hiroyuki Shimo , Toshiaki Sato , Takashi Yamashita , Yoshiki Mukoo
发明人： Shinji Tai , Masakazu Nakaya , Hiroyuki Shimo , Toshiaki Sato , Takashi Yamashita , Yoshiki Mukoo
IPC分类号： B32B2704
CPC分类号： B32B27/08 , B32B27/18 , B32B27/306 , B32B27/34 , B32B27/36 , B32B2367/00 , B32B2377/00 , B32B2439/00 , C08K5/098 , C08K2201/012 , C08L29/04 , C08L51/00 , C08L51/003 , C08L51/04 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/1372 , Y10T428/1379 , Y10T428/254 , Y10T428/2998 , C08L2666/24 , C08L2666/02 , C08L2666/14 , C08L53/00
摘要： The present invention provides a thermoplastic resin composition having excellent oxygen absorption property. This thermoplastic resin composition comprises a thermoplastic resin (A), a multilayered polymer particle (B) and a transition metal salt (C), wherein the multilayered polymer particle (B) has at least one oxygen absorption layer, the oxygen absorption layer comprises a diene polymer (B1) containing a conjugated diene monomer as a polymerization component, and the transition metal salt (C) is contained in an amount of 1 to 5000 ppm in terms of a metal element thereof.
摘要翻译：本发明提供具有优异的氧吸收性能的热塑性树脂组合物。该热塑性树脂组合物包含热塑性树脂（A），多层聚合物颗粒（B）和过渡金属盐（C），其中多层聚合物颗粒（B）具有至少一个氧吸收层，氧吸收层包含含有共轭二烯单体作为聚合组分的二烯聚合物（B1）和其金属元素的含量为1至5000ppm的过渡金属盐（C）。

2. 发明授权

US06447858B1 Pipe for hot-water circulation 有权
标题翻译：管道热水循环
公开(公告)号：US06447858B1
公开(公告)日：2002-09-10
申请号：US09856478
申请日：2001-06-08
申请人： Hiroyuki Shimo , Takashi Yamashita
发明人： Hiroyuki Shimo , Takashi Yamashita
IPC分类号： C09K500
CPC分类号： F16L9/12 , C08L29/04 , C08L51/04 , Y10T428/1352 , C08L2666/02 , C08L2666/24
摘要： The present invention provides a multilayered pipe for hot water circulation having excellent oxygen barrier properties and anti-crack properties, in particular, excellent anti-crack properties at low temperatures by using a thermoplastic resin composition comprising 50 to 99% by weight of an ethylene-vinyl alcohol copolymer (A) and 1 to 50% by weight of multilayered polymer particles (B).
摘要翻译：本发明提供一种热水循环用多层管，其具有优异的氧阻隔性和抗裂性，特别是通过使用包含50-99重量％的乙烯 - 丙烯酸酯的热塑性树脂组合物在低温下具有优异的抗裂纹性能，乙烯醇共聚物（A）和1〜50重量％的多层聚合物粒子（B）。

3. 发明申请

US20070243351A1 POLYVINYL ALCOHOL RESIN COMPOSITION AND MULTILAYER PACKAGES 有权
标题翻译：聚乙烯醇树脂组合物和多层包装
公开(公告)号：US20070243351A1
公开(公告)日：2007-10-18
申请号：US11768617
申请日：2007-06-26
申请人： Shinji TAI , Hiroyuki Shimo , Masakazu Nakaya , Mizuho Maeda
发明人： Shinji TAI , Hiroyuki Shimo , Masakazu Nakaya , Mizuho Maeda
IPC分类号： B32B27/08 , B32B27/28 , C08L29/04
CPC分类号： B32B27/08 , B32B27/28 , B32B27/36 , B32B2307/7242 , C08L29/04 , C08L53/02 , Y10T428/1355 , Y10T428/1379 , Y10T428/1383 , Y10T428/249921 , Y10T428/254 , Y10T428/31504 , Y10T428/31794 , C08L2666/24
摘要： The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.
摘要翻译：本发明提供了具有除氧功能的树脂组合物。树脂组合物包含聚乙烯醇树脂（A）70至99.9重量％和聚乙烯醇树脂（A）以外的热塑性树脂（B）0.1至30重量％，其中热塑性树脂（B）具有碳碳双键和包含杂原子的官能团，并且树脂组合物的氧吸收速率为0.001ml / m 2以上。

4. 发明授权

US06720053B2 Coinjection stretch blow molded container 有权
标题翻译：共注射拉伸吹塑容器
公开(公告)号：US06720053B2
公开(公告)日：2004-04-13
申请号：US09909832
申请日：2001-07-23
申请人： Shinji Tai , Hiroyuki Shimo , Nahoto Hayashi , Masako Chigami
发明人： Shinji Tai , Hiroyuki Shimo , Nahoto Hayashi , Masako Chigami
IPC分类号： B32B2730
CPC分类号： B32B27/08 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/14126 , B29B2911/14146 , B29B2911/14153 , B29B2911/14593 , B29B2911/14633 , B29B2911/14646 , B29B2911/14653 , B29B2911/14713 , B29B2911/14906 , B29B2911/14926 , B29B2911/14986 , B29C49/0005 , B29C49/06 , B29C49/221 , B29K2995/004 , B32B27/306 , B32B27/36 , B32B2307/7246 , B32B2329/04 , B32B2367/00 , B32B2439/70 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： Coinjection stretch blow molded containers containing thermoplastic polyester resin and an EVOH resin are obtained, which have greatly improved impact delamination resistance. The containers comprise a thermoplastic polyester layer (layer a) and an ethylene-vinyl alcohol copolymer layer (layer b), with the layer a being kept in direct contact with the both surfaces of the layer b, wherein the ethylene-vinyl alcohol copolymer satisfies the following formulae (1) and (2) and its differential scanning calorimetry (DSC) gives a single peak f or crystal fusion: 25≦ETb≦48 (1) 92≦SDb≦99 (2) wherein ETb indicates the ethylene content (mol %) of the ethylene-vinyl alcohol copolymer, and SDb indicates the degree of saponification (%) of the ethylene-vinyl alcohol copolymer.
摘要翻译：得到含有热塑性聚酯树脂和EVOH树脂的共注射拉伸吹塑容器，其耐冲击剥离性大大提高。容器包括热塑性聚酯层（层a）和乙烯 - 乙烯醇共聚物层（层b），其中层a与层b的两个表面保持直接接触，其中乙烯 - 乙烯醇共聚物满足以下式（1）和（2）及其差示扫描量热法（DSC）给出单峰f或晶体熔融：其中ETb表示乙烯 - 乙烯醇共聚物的乙烯含量（mol％），SDb表示的乙烯 - 乙烯醇共聚物的皂化（％）。

5. 发明授权

US06822031B2 Resin composition and a multilayered container 失效
标题翻译：树脂组合物和多层容器
公开(公告)号：US06822031B2
公开(公告)日：2004-11-23
申请号：US10111912
申请日：2002-05-01
申请人： Shinji Tai , Hiroyuki Shimo , Masakazu Nakaya , Kaoru Ikeda
发明人： Shinji Tai , Hiroyuki Shimo , Masakazu Nakaya , Kaoru Ikeda
IPC分类号： C08K504
CPC分类号： B32B27/08 , B32B7/02 , B32B27/18 , B32B27/28 , B32B27/36 , B32B2307/7244 , B32B2439/70 , B32B2439/80 , C08L23/08 , C08L29/04 , C08L53/02 , Y10T428/1334 , Y10T428/1355 , C08L2666/24 , C08L2666/02
摘要： The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises a gas barrier resin (A), a thermoplastic resin (B) other than the gas barrier resin (A), and a compatibilizer (C), wherein the gas barrier resin (A) has an oxygen transmission rate of 500 ml·20 &mgr;m/m2·days·atm (20° C., 65% RH) or less, the thermoplastic resin (B) has a carbon—carbon double bond, and an oxygen absorption rate of the resin composition is 0.001 m/m2·day or more.
摘要翻译：本发明提供了具有除氧功能的树脂组合物。树脂组合物包含阻气性树脂（A），除阻气性树脂（A）以外的热塑性树脂（B）和增容剂（C），其中，阻气性树脂（A）的氧气透过率为500 （20℃，65％RH）以下，热塑性树脂（B）具有碳 - 碳双键，树脂组合物的氧吸收速率为 0.001 m / m 2天以上。

6. 发明授权

US06395358B1 Coinjection stretch blow molded container 有权
标题翻译：共注射拉伸吹塑容器
公开(公告)号：US06395358B1
公开(公告)日：2002-05-28
申请号：US09288853
申请日：1999-04-09
申请人： Shinji Tai , Hiroyuki Shimo , Nahoto Hayashi , Masako Chigami
发明人： Shinji Tai , Hiroyuki Shimo , Nahoto Hayashi , Masako Chigami
IPC分类号： B32B2730
CPC分类号： B32B27/08 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/14126 , B29B2911/14146 , B29B2911/14153 , B29B2911/14593 , B29B2911/14633 , B29B2911/14646 , B29B2911/14653 , B29B2911/14713 , B29B2911/14906 , B29B2911/14926 , B29B2911/14986 , B29C49/0005 , B29C49/06 , B29C49/221 , B29K2995/004 , B32B27/306 , B32B27/36 , B32B2307/7246 , B32B2329/04 , B32B2367/00 , B32B2439/70 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： Coinjection stretch blow molded containers containing thermoplastic polyester resin and an EVOH resin are obtained, which have greatly improved impact delamination resistance. The containers comprise a thermoplastic polyester layer (layer a) and an ethylene-vinyl alcohol copolymer layer (layer b), with the layer a being kept in direct contact with the both surf aces of the layer b, wherein the ethylene-vinyl alcohol copolymer satisfies the following formulae (1) and (2) and its differential scanning calorimetry (DSC) gives a single peak f or crystal fusion: 25≦ETb≦48 (1) 92≦SDb≦99 (2) wherein ETb indicates the ethylene content (mol %) of the ethylene-vinyl alcohol copolymer, and SDb indicates the degree of saponification (%) of the ethylene-vinyl alcohol copolymer.
摘要翻译：得到含有热塑性聚酯树脂和EVOH树脂的共注射拉伸吹塑容器，其耐冲击剥离性大大提高。容器包括热塑性聚酯层（层a）和乙烯 - 乙烯醇共聚物层（层b），其中层a与层b的两个冲洗表面保持直接接触，其中乙烯 - 乙烯醇共聚物满足下列公式（1）和（2），差示扫描量热法（DSC）给出单峰f或晶体熔融：其中ETb表示乙烯 - 乙烯醇共聚物的乙烯含量（mol％），SDb表示乙烯 - 乙烯醇共聚物的皂化度（％）。

7. 发明授权

US5972447A Thermoformable multilayer film and thermoformed container 失效
标题翻译：可热成型多层膜和热成型容器
公开(公告)号：US5972447A
公开(公告)日：1999-10-26
申请号：US927266
申请日：1997-09-11
申请人： Nobihiro Hata , Hiroyuki Shimo
发明人： Nobihiro Hata , Hiroyuki Shimo
IPC分类号： B32B27/08 , C08L23/08 , C08L29/04 , B32B27/30 , B32B1/02 , B65D1/22
CPC分类号： C08L23/08 , B32B27/08 , C08L29/04 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/2495 , Y10T428/24967 , Y10T428/3175 , Y10T428/3192
摘要： Disclosed herein is a thermoformable film or sheet superior in gas barrier properties, mechanical properties, and appearance, a thermoformed container produced therefrom, and a resin composition suitable therefor. A thermoformable multilayer film with a total thickness of 50-300 .mu.m, comprising a layer of a resin composition with a thickness of 3-50 .mu.m, said resin composition comprising 60-99 wt % of ethylene-vinyl alcohol copolymer and 40-1 wt % of ethylene-(meth)acrylic acid copolymer, said ethylene-(meth)acrylic acid copolymer being dispersed in the form of particles in the matrix of said ethylene-vinyl alcohol copolymer, wherein said ethylene-vinyl alcohol copolymer having an ethylene content of 20-60 mol % and a degree of hydrolysis of not less than than 90%, and said ethylene-(meth)acrylic acid copolymer containing 1-30 wt % of (meth)acrylic acid.The EVOH may be a mixture of more than one kind of EVOH differing in ethylene content. The resin composition may contain each component dispersed in a specific manner.
摘要翻译：本文公开了一种耐气体阻隔性，机械性能和外观优异的热成型膜或由其制备的热成型容器以及适于其的树脂组合物。一种总厚度为50-300μm的可热成型多层膜，包括厚度为3-50μm的树脂组合物层，所述树脂组合物包含60-99wt％的乙烯 - 乙烯醇共聚物和40-99wt％ 1重量％的乙烯 - （甲基）丙烯酸共聚物，所述乙烯 - （甲基）丙烯酸共聚物以所述乙烯 - 乙烯醇共聚物的基体中的颗粒形式分散，其中所述乙烯 - 乙烯醇共聚物具有乙烯含量为20-60摩尔％，水解度不低于90％，所述乙烯 - （甲基）丙烯酸共聚物含有1-30重量％的（甲基）丙烯酸。 EVOH可以是不同于乙烯含量的多种EVOH的混合物。树脂组合物可以含有以特定方式分散的各成分。

8. 发明授权

US08163212B2 Process for producing pellet of ethylene/vinyl alcohol copolymer 有权
标题翻译：制备乙烯/乙烯醇共聚物颗粒的方法
公开(公告)号：US08163212B2
公开(公告)日：2012-04-24
申请号：US10521468
申请日：2003-07-14
申请人： Naohiko Uchiumi , Noriyuki Kida , Hiroyuki Shimo , Kaoru Ikeda
发明人： Naohiko Uchiumi , Noriyuki Kida , Hiroyuki Shimo , Kaoru Ikeda
IPC分类号： B29B9/06
CPC分类号： C08J3/12 , B29B9/06 , B29B9/065 , B29B9/16 , B29C2791/001 , C08J3/14 , C08J2329/08
摘要： The present invention provides a process for producing pellet of EVOH comprising the steps of introducing an EVOH solution containing alcohol into an apparatus, contacting the solution with water in the apparatus to let out the alcohol with water and then letting out an EVOH hydrous composition from the above-mentioned apparatus (step 1); cutting the EVOH hydrous composition let out therefrom to obtain EVOH hydrous composition pellets (step 2); introducing the obtained EVOH hydrous composition pellets into a dryer to reduce a water content thereof (step 3); melt-kneading the pellets, whose water content is reduced, in an extruder (step 4); and cutting EVOH discharged from the extruder to obtain the pellet of EVOH (step 5). Thus, the EVOH hydrous composition obtained by removing alcohol without deteriorating the environment can be efficiently dried, and pellets having less thermal degradation in drying and a uniform shape can be obtained.
摘要翻译：本发明提供了一种制备EVOH颗粒的方法，包括以下步骤：将含有醇的EVOH溶液引入设备中，使该溶液与设备中的水接触，以便用水排出酒精，然后从其中提取出EVOH含水组合物上述装置（步骤1）; 从中排出EVOH含水组合物，得到EVOH含水组合物颗粒（步骤2）; 将获得的EVOH含水组合物颗粒引入干燥器中以降低其含水量（步骤3）; 在挤出机中熔融捏合含水量降低的颗粒（步骤4）; 并从挤出机中排出EVOH以获得EVOH颗粒（步骤5）。因此，可以有效地干燥除去醇而不使环境恶化得到的EVOH含水组合物，并且可以获得干燥热降低和均匀形状的颗粒。

9. 发明授权

US07820261B2 Polyvinyl alcohol resin composition and multilayer packages 有权
标题翻译：聚乙烯醇树脂组合物和多层包装
公开(公告)号：US07820261B2
公开(公告)日：2010-10-26
申请号：US11768617
申请日：2007-06-26
申请人： Shinji Tai , Hiroyuki Shimo , Masakazu Nakaya , Mizuho Maeda
发明人： Shinji Tai , Hiroyuki Shimo , Masakazu Nakaya , Mizuho Maeda
IPC分类号： B32B27/08
CPC分类号： B32B27/08 , B32B27/28 , B32B27/36 , B32B2307/7242 , C08L29/04 , C08L53/02 , Y10T428/1355 , Y10T428/1379 , Y10T428/1383 , Y10T428/249921 , Y10T428/254 , Y10T428/31504 , Y10T428/31794 , C08L2666/24
摘要： The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.
摘要翻译：本发明提供了具有除氧功能的树脂组合物。树脂组合物包含聚乙烯醇树脂（A）70至99.9重量％和聚乙烯醇树脂（A）以外的热塑性树脂（B）0.1至30重量％，其中热塑性树脂（B）具有碳碳双键和包含杂原子的官能团，并且树脂组合物的氧吸收速率为0.001ml / m 2·天或更多。

10. 发明申请

US20070275197A1 Resin composition and multilayer structure 审中-公开
标题翻译：树脂组成和多层结构
公开(公告)号：US20070275197A1
公开(公告)日：2007-11-29
申请号：US11440112
申请日：2006-05-25
申请人： Edgard Chow , Hiroyuki Shimo
发明人： Edgard Chow , Hiroyuki Shimo
IPC分类号： B32B1/02 , B32B27/00
CPC分类号： B32B27/32 , B32B27/08 , B32B27/18 , B32B27/306 , B32B2250/24 , B32B2250/40 , B32B2272/00 , B32B2307/306 , B32B2307/7242 , B32B2439/70 , Y10T428/1352 , Y10T428/31855
摘要： To provide a resin composition including: an ethylene-vinyl alcohol copolymer (A) having an ethylene content of from 15 to 65 mol % and a saponification degree of at least 95 mol %, a phosphoric acid salt (B) which can form a hydrate, and a conjugated polyene compound (C) having a boiling point of at least 150° C., wherein the resin composition comprises from 50 to 99 parts by weight of (A), from 1 to 50 parts by weight of (B) and from 0.00001 to 1 parts by weight of (C), based on 100 parts by weight of the total amounts of (A) and (B). This resin composition excels in gas barrier property and also in moisture resistance at high temperatures and high humidities. Therefore, it is suitable for food packaging containers to be retorted.
摘要翻译：提供一种树脂组合物，其包含：乙烯含量为15〜65摩尔％，皂化度为95摩尔％以上的乙烯 - 乙烯醇共聚物（A），可形成水合物的磷酸盐（B），和沸点为至少150℃的共轭多烯化合物（C），其中所述树脂组合物包含50至99重量份的（A），1至50重量份的（B）和基于（A）和（B）的总量的100重量份，从（C）0.00001到1重量份。该树脂组合物的气体阻隔性以及高温和高湿度下的耐湿性均优异。因此，适合食品包装容器被蒸煮。

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