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1. 发明申请

US20060166095A1 Alkaline battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20060166095A1
公开(公告)日：2006-07-27
申请号：US10562440
申请日：2005-02-17
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/32 , H01M4/50 , H01M4/62
CPC分类号： H01M4/08 , C01G31/006 , C01G53/00 , C01G53/04 , C01P2002/52 , C01P2002/54 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01M4/42 , H01M4/50 , H01M4/52 , H01M4/62 , H01M4/625 , H01M6/04 , H01M2004/021
摘要： An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, the positive electrode including a positive electrode material mixture containing a nickel oxyhydroxide, electrolytic manganese dioxide and a graphite conductive material, wherein the nickel oxyhydroxide includes a crystal having manganese dissolved therein and having a β type structure, and the amount of the manganese contained in the nickel oxyhydroxide is 0.5 to 10 mol % relative to the total amount of nickel and the manganese in the nickel oxyhydroxide.
摘要翻译：包括正极，负极和碱性电解质的碱性电池，所述正极包括含有氢氧化正镍，电解二氧化锰和石墨导电材料的正极材料混合物，其中所述氢氧化镍包括其中溶解有锰的晶体并且具有β型结构，并且在氢氧化正镍中所含的锰的量相对于镍的总量和羟基氧化镍中的锰为0.5〜10摩尔％。

2. 发明授权

US07569306B2 Alkaline battery and manufacturing method of positive electrode material therefor 失效
标题翻译：碱性电池及其正极材料的制造方法
公开(公告)号：US07569306B2
公开(公告)日：2009-08-04
申请号：US11587206
申请日：2005-03-24
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/52 , H01M4/08
CPC分类号： C01G53/00 , C01G53/04 , C01P2002/50 , C01P2002/74 , C01P2004/32 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01M4/02 , H01M4/06 , H01M4/52 , H01M6/06
摘要： An alkaline battery of the present invention includes a positive electrode material mixture including nickel oxyhydroxide. The nickel oxyhydroxide includes a secondary particle with a crystal structure mainly composed of γ-type at least a portion of the surface layer of the secondary particle, and with a crystal structure mainly composed of β-type in the inner portion of the secondary particle. Based on the present invention, the advantage of the alkaline battery, i.e., excellence in discharge performance under high-load, can be kept and the conventional problem of storage characteristics can be improved.
摘要翻译：本发明的碱性电池包括含有氢氧化正镍的正极合剂混合物。羟基氧化镍包括主要由γ型至少部分二次粒子的表面层构成的晶体结构的二次粒子，以及在二次粒子的内部主要由β型构成的晶体结构。基于本发明，可以保持碱性电池的优点，即在高负载下的放电性能优异，并且可以提高传统的存储特性问题。

3. 发明申请

US20070166614A1 Alkaline battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20070166614A1
公开(公告)日：2007-07-19
申请号：US10588036
申请日：2005-06-16
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/52 , H01M4/50
CPC分类号： H01M4/32 , C01G53/04 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01M4/364 , H01M4/50 , H01M4/52 , H01M2004/021
摘要： Disclosed is an alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, (1) the positive electrode having a positive electrode material mixture containing electrolytic manganese doxide and nickel oxyhydroxide, (2) the nickel oxyhydroxide having a crystal in which at least Mg is dissolved, and (3) the nickel oxyhydroxide having a tap density determined after 500 taps of not less than 2 g/cm3, an average particle size based on volume of 8 to 20 μm, and an average nickel valence of 2.95 to 3.05.
摘要翻译：公开了一种包括正极，负极和碱性电解质的碱性电池，（1）正极具有含有电解锰氧化锰和氢氧化正镍的正极材料混合物，（2）具有晶体的氢氧化正镍，溶解最少量的Mg，（3）在500次抽头后测定的振实密度不小于2g / cm 3的氢氧化正镍，基于体积为8〜20μm的平均粒径，平均镍价为2.95〜3.05。

4. 发明申请

US20070218358A1 Alkaline Battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20070218358A1
公开(公告)日：2007-09-20
申请号：US11587213
申请日：2005-09-20
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/52 , H01M4/50
CPC分类号： H01M4/625 , H01M2/0235 , H01M4/02 , H01M4/32 , H01M4/364 , H01M4/50 , H01M2004/021 , H01M2004/028
摘要： An alkaline battery includes a positive electrode mixture, a negative electrode, and a separator interposed between the positive electrode mixture and the negative electrode. The positive electrode mixture contains a nickel oxyhydroxide, manganese dioxide and a conductive agent. (1) The nickel oxyhydroxide includes at least manganese dissolved therein, and the manganese accounts for 0.5 to 10% by mole of the total amount of metal elements contained in the nickel oxyhydroxide. (2) The nickel oxyhydroxide mainly has a β-type crystal structure. (3) The nickel oxyhydroxide has a volume-basis mean particle size of 8 to 15 μm. The use of this positive electrode mixture makes it possible to heighten the capacity of the alkaline battery and improve its storage characteristics. Also, the above-mentioned properties of the nickel oxyhydroxide including manganese enable a significant improvement in the productivity of the nickel oxyhydroxide.
摘要翻译：碱性电池包括正电极混合物，负电极和置于正电极混合物和负电极之间的隔膜。正极混合物含有氢氧化正镍，二氧化锰和导电剂。（1）羟基氧化镍至少含有锰，其中锰占羟基氧化镍中所含金属元素总量的0.5〜10摩尔％。（2）羟基氧化镍主要具有β型晶体结构。（3）羟基氧化镍的体积基准平均粒径为8〜15μm。使用该正极混合物可以提高碱性电池的容量并提高其储存特性。此外，包括锰的羟基氧化镍的上述性质能够显着提高羟基氧化镍的生产率。

5. 发明申请

US20070212612A1 Alkaline Battery and Manufacturing Method of Positive Electrode Material Therefor 失效
标题翻译：碱性电池及正极材料的制造方法
公开(公告)号：US20070212612A1
公开(公告)日：2007-09-13
申请号：US11587206
申请日：2005-03-24
申请人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Tadaya Okada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/62 , H01M4/32
CPC分类号： C01G53/00 , C01G53/04 , C01P2002/50 , C01P2002/74 , C01P2004/32 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , H01M4/02 , H01M4/06 , H01M4/52 , H01M6/06
摘要： An alkaline battery of the present invention includes a positive electrode material mixture including nickel oxyhydroxide. The nickel oxyhydroxide includes a secondary particle with a crystal structure mainly composed of γ-type at at least a portion of the surface layer of the secondary particle, and with a crystal structure mainly composed of β-type in the inner portion of the secondary particle. Based on the present invention, the advantage of the alkaline battery, i.e., excellence in discharge performance under high-load, can be kept and the conventional problem of storage characteristics can be improved.
摘要翻译：本发明的碱性电池包括含有氢氧化正镍的正极合剂混合物。羟基氧化镍包括在二次粒子的表面层的至少一部分上主要由γ型构成的晶体结构的二次粒子，在二次粒子的内部具有主要由β型构成的晶体结构。基于本发明，可以保持碱性电池的优点，即在高负载下的放电性能优异，并且可以提高传统的存储特性问题。

6. 发明申请

US20080026285A1 Alkaline Battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20080026285A1
公开(公告)日：2008-01-31
申请号：US11629912
申请日：2005-06-22
申请人： Katsuya Sawada , Tadaya Okada , Hidekatsu Izumi , Yasuo Mukai , Shigeto Noya
发明人： Katsuya Sawada , Tadaya Okada , Hidekatsu Izumi , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M2/14
CPC分类号： H01M4/50 , H01M4/0433 , H01M4/38 , H01M4/42 , H01M4/52 , H01M4/625 , H01M6/04 , H01M6/08 , H01M2004/021 , H01M2004/028
摘要： An alkaline battery of this invention includes a positive electrode containing manganese dioxide powder and nickel oxyhydroxide powder with a mean particle size of 8 to 18 μm as positive electrode active materials and graphite powder with a mean particle size of 8 to 25 μm as a conductive material. The positive electrode contains 5 to 9 parts by weight of the graphite powder per 100 parts by weight of the positive electrode active materials.
摘要翻译：本发明的碱性电池包括平均粒径为8〜18μm的二氧化锰粉末和氢氧化正镍粉末的正极作为正极活性物质，平均粒径为8〜25μm的石墨粉末作为导电材料。该正极每100重量份的正极活性物质含有5〜9重量份的石墨粉末。

7. 发明授权

US07718315B2 Alkaline battery and positive electrode material for alkaline battery comprising nickel oxyhydroxide and manganese dioxide 失效
标题翻译：碱性电池和碱性电池用正极材料，包括氢氧化正镍和二氧化锰
公开(公告)号：US07718315B2
公开(公告)日：2010-05-18
申请号：US10554356
申请日：2004-11-04
申请人： Fumio Kato , Katsuya Sawada , Hidekatsu Izumi , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Hidekatsu Izumi , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M4/00 , H01M4/62 , C01G53/04 , H01M4/08
CPC分类号： H01M4/50 , C01G53/00 , C01G53/04 , C01P2002/72 , C01P2002/74 , C01P2004/51 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/40 , C01P2006/82 , H01M4/06 , H01M4/364 , H01M4/52 , H01M6/04 , H01M2004/021
摘要： There is disclosed an alkaline battery including a positive electrode material mixture, a negative electrode, a separator interposed between the positive electrode material mixture and the negative electrode, and an alkaline electrolyte, wherein the positive electrode material mixture includes a first active material comprising nickel oxyhydroxide and a second active material comprising manganese dioxide, the nickel oxyhydroxide includes a γ-type crystal structure, the content of nickel in the nickel oxyhydroxide is not less than 45 wt %, and the average particle diameter on a volume basis of the nickel oxyhydroxide measured with a laser diffraction particle size distribution analyzer is 3 to 20 μm.
摘要翻译：公开了一种碱性电池，其包括正极材料混合物，负极，夹在正极材料混合物和负极之间的隔板和碱性电解质，其中正极材料混合物包括含有氢氧化正镍的第一活性材料和包含二氧化锰的第二活性物质，羟基氧化镍包括γ型晶体结构，羟基氧化镍中的镍含量不小于45重量％，并且测量基于氢氧化镍的体积平均粒径激光衍射粒度分布分析仪为3〜20μm。

8. 发明申请

US20080070114A1 Alkaline Battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20080070114A1
公开(公告)日：2008-03-20
申请号：US11630335
申请日：2005-06-16
申请人： Fumio Kato , Katsuya Sawada , Yasuo Mukai , Shigeto Noya
发明人： Fumio Kato , Katsuya Sawada , Yasuo Mukai , Shigeto Noya
IPC分类号： H01M6/02
CPC分类号： H01M4/26 , C01G53/00 , C01P2002/52 , C01P2002/78 , C01P2006/10 , C01P2006/12 , C01P2006/40 , H01M4/50 , H01M4/52 , H01M4/625 , H01M2004/021 , H01M2010/4292
摘要： An alkaline battery including a positive electrode, a negative electrode and an alkaline electrolyte, wherein the positive electrode includes a positive electrode material mixture including nickel oxyhydroxide, electrolytic manganese dioxide and expanded graphite, the expanded graphite has an average particle diameter on a volume basis of 5 to 25 μm, a BET specific surface area of 4 to 10 m2/g, and a bulk specific gravity (apparent density) measured by a static method of 0.03 to 0.10 g/cm3, the nickel oxyhydroxide has an average nickel valence of not less than 3.05, and a content of the expanded graphite in a total amount of the nickel oxyhydroxide, the electrolytic manganese dioxide and the expanded graphite that are included in the positive electrode material mixture of 3 to 15 wt %.
摘要翻译：一种包括正极，负极和碱性电解质的碱性电池，其中所述正极包括包含羟基氧化镍，电解二氧化锰和膨胀石墨的正极材料混合物，所述膨胀石墨的平均粒径基于 5〜25μm，BET比表面积为4〜10m 2 / g，静态法测定的体积比重（表观密度）为0.03〜0.10g / cm 2， 3，氢氧化正镍的平均镍价不小于3.05，膨胀石墨的含量在正极中包含的氢氧化正镍，电解二氧化锰和膨胀石墨的总量电极材料混合物为3〜15重量％。

9. 发明申请

US20080063933A1 Alkaline Dry Battery 审中-公开
标题翻译：碱性干电池
公开(公告)号：US20080063933A1
公开(公告)日：2008-03-13
申请号：US11793592
申请日：2006-04-05
申请人： Tadaya Okada , Shigeto Noya , Yasuo Mukai , Michiko Fujiwara , Hidekatsu Izumi
发明人： Tadaya Okada , Shigeto Noya , Yasuo Mukai , Michiko Fujiwara , Hidekatsu Izumi
IPC分类号： H01M2/16
CPC分类号： H01M6/08 , H01M4/02 , H01M4/244 , H01M4/32 , H01M4/364 , H01M4/42 , H01M4/50 , H01M4/625 , H01M10/30 , H01M2004/021
摘要： To provide an alkaline dry battery that is excellent in discharge characteristics under a heavy load after storage at high temperature and suppresses polarization in pulse discharge under a heavy load, used is a nickel oxyhydroxide which is obtained by oxidizing a nickel hydroxide having a half width of a (101) face of 0.6 to 0.8 deg./2θ and a half width of a (001) face of 0.5 to 0.7 deg./2θ in powder X-ray diffraction, and which has an average nickel valence of 2.95 or more and an average particle diameter of 8 to 18 μm.
摘要翻译：为了提供在高温下储存后在重负荷下的放电特性优异的碱性干电池，并且在重负荷下抑制脉冲放电中的极化，使用的是氢氧化镍，其通过将具有半值宽度的氢氧化镍氧化（101）面为0.6〜0.8度/2θ，粉末X射线衍射中（001）面的半宽度为0.5〜0.7度/2θ，平均镍价为2.95以上，平均粒径为8〜18μm。

10. 发明申请

US20090098462A1 Alkaline dry battery 审中-公开
标题翻译：碱性干电池
公开(公告)号：US20090098462A1
公开(公告)日：2009-04-16
申请号：US11919885
申请日：2006-08-25
申请人： Michiko Fujiwara , Tadaya Okada , Yasuo Mukai , Hidekatsu Izumi , Shigeto Noya
发明人： Michiko Fujiwara , Tadaya Okada , Yasuo Mukai , Hidekatsu Izumi , Shigeto Noya
IPC分类号： H01M4/32
CPC分类号： H01M4/32 , H01M4/24 , H01M4/364 , H01M4/42 , H01M4/62 , H01M6/08
摘要： In order to provide an alkaline dry battery which enables to improve the operational stability of digital equipment by suppressing the progress of polarization during heavy load pulse discharge while maintaining the excellent heavy load discharge characteristics, and has an excellent reliability in terms of the leakage resistance and the safety under short-circuit conditions, the alkaline dry battery includes a positive electrode including a nickel oxyhydroxide powder and a manganese dioxide powder as positive electrode active materials, and including graphite as a conductive material; a negative electrode including zinc or a zinc alloy as a negative electrode active material; a separator interposed between the positive electrode and the negative electrode; a negative electrode current collector inserted in the negative electrode; an aqueous alkaline solution included in the separator; a battery case housing the positive electrode, the negative electrode, the separator, the negative electrode current collector and the aqueous alkaline solution; a sealing member for sealing an opening of the battery case, wherein the positive electrode includes a calcium compound in an amount of 0.1 to 10 mol % relative to a total amount of the positive electrode active material, and the content of iron element in the calcium compound is 150 ppm or less.
摘要翻译：为了提供一种碱性干电池，其能够通过抑制重负载脉冲放电期间的极化进行而提高数字设备的操作稳定性，同时保持优异的重负载放电特性，并且在耐漏电性方面具有优异的可靠性，在短路条件下的安全性，碱性干电池包括含有氢氧化正镍粉末和二氧化锰粉末的正极作为正极活性物质，并且包括石墨作为导电材料; 包含锌或锌合金的负极作为负极活性物质; 夹在正极和负极之间的隔膜; 负极集电体插入负极中; 包含在隔膜中的碱性水溶液; 容纳正极，负极，隔膜，负极集电体和碱性水溶液的电池壳体; 用于密封电池壳体的开口的密封构件，其中所述正极包含相对于所述正极活性物质的总量为0.1〜10摩尔％的钙化合物，所述钙元素的含量化合物为150ppm以下。

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