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    • 9. 发明申请
    • LITHOGRAPHIC PRINTING PLATE PRECURSORS AND PROCESSES FOR PREPARING LITHOGRAPHIC PRINTING PLATES
    • 平版印刷板前驱体和制备平版印刷板的方法
    • US20130344440A1
    • 2013-12-26
    • US13975978
    • 2013-08-26
    • FUJIFILM Corporation
    • Hiroyuki SUZUKIJunya ABETakafumi NAKAYAMAKohei TAKESHITA
    • G03F7/09G03F7/30
    • G03F7/0388C08F2220/603C08F2220/606G03F7/00G03F7/004G03F7/027G03F7/033G03F7/038G03F7/085G03F7/09G03F7/092G03F7/11G03F7/30G03F7/3042G03F7/32G03F7/322
    • Provided is lithographic printing plates and processes for preparing the lithographic printing plates having excellent printing durability, staining resistance and staining resistance over time.A lithographic printing plate precursor comprising: a substrate; a photosensitive layer provided on the substrate; and an extra layer optionally provided between the substrate and the photosensitive layer; wherein the photosensitive layer or the extra layer adjacent to the substrate contains (A) a copolymer; and wherein the copolymer (A) comprises: (a1) a repeating unit having a structure represented by formula (a1-1) below in a side chain, and (a2) a repeating unit having at least one of the structures represented by formulae (a2-1) to (a2-6) below in a side chain. L1 represents a single bond, a divalent aromatic group containing 6 to 14 carbon atoms, —C(═O)—O—, or —C(—0)═NR2— (wherein R2 represents a hydrogen atom, alkyl or aryl). Z1 represents methylene, ethylene, propylene, butylene, pentylene, hexylene, heptylene, octylene, cyclohexane-1,4-diyl, 1,2-phenylene, 1,3-phenylene, 1,4-phenylene, 1,2-naphthalene, 1,5-naphthalene and a linking group composed of two or more of these divalent linking groups linked through —O— or —S—, wherein a hydrogen atoms in these divalent linking groups may be replaced by substituents. R1 represents a hydrogen atom, alkyl, aryl, heterocyclyl, sulfo, alkylsulfonyl and arylsulfonyl. R21, R22 and R23 each independently represent a hydrogen atom, halogen atom or C1-8 alkyl.
    • 提供了平版印刷版和用于制备具有优异的印刷耐久性,耐污染性和耐污染性的平版印刷版的方法。 一种平版印刷版原版,包括:基底; 设置在基板上的感光层; 以及可选地设置在所述基底和所述感光层之间的额外层; 其中所述感光层或与所述基材相邻的所述多余层含有(A)共聚物; 并且其中所述共聚物(A)包含:(a1)在侧链具有由下式(a1-1)表示的结构的重复单元,和(a2)具有至少一个由式 a2-1)〜(a2-6)。 L1表示单键,含有6​​〜14个碳原子的二价芳基,-C(= O)-O-或-C( - )= NR2-(其中R2表示氢原子,烷基或芳基)。 Z1表示亚甲基,亚乙基,亚丙基,亚丁基,亚戊基,亚己基,亚庚基,亚辛基,环己烷-1,4-二基,1,2-亚苯基,1,3-亚苯基,1,4-亚苯基,1,2-萘, 1,5-萘和由这些通过-O-或-S-连接的这些二价连接基团中的两个或更多个的连接基团,其中这些二价连接基团中的氢原子可被取代基取代。 R 1表示氢原子,烷基,芳基,杂环基,磺基,烷基磺酰基和芳基磺酰基。 R 21,R 22和R 23各自独立地表示氢原子,卤素原子或C 1-8烷基。