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1. 发明授权

US4417035A Emulsifiable hard waxes consisting of copolymers of ethylene with unsaturated carboxylic acids 失效
标题翻译：由乙烯与不饱和羧酸的共聚物组成的可乳化硬蜡
公开(公告)号：US4417035A
公开(公告)日：1983-11-22
申请号：US320976
申请日：1981-11-13
申请人： Dieter Oeder , Wolfram Dietsche , Stefan Weiss , Walter Ziegler , Peter Kueppers , Albert Hettche
发明人： Dieter Oeder , Wolfram Dietsche , Stefan Weiss , Walter Ziegler , Peter Kueppers , Albert Hettche
IPC分类号： C08F2/00 , C08F2/38 , C08F210/00 , C08F210/02 , C09G1/10 , C08F212/02 , C08F220/06
CPC分类号： C08F210/02 , C09G1/10
摘要： Water-emulsifiable hard waxes consisting of homogeneous copolymers of ethylene with from 1 to 8% by weight, based on copolymer, of one or more .alpha.-olefinically unsaturated C.sub.3 -C.sub.8 -carboxylic acids, and having the following characteristic data:Melt index=1,500 to 20 MFI units, measured at 160.degree. C. under 325 g loadAcid number=10-60Hoppler hardness=400-800 bar, measured at 23.degree. C. by DGF standard method M-III 9a (57).
摘要翻译：由具有1至8重量％乙烯与1至8重量％的基于共聚物的一种或多种α-烯属不饱和C 3 -C 8 - 羧酸组成的具有以下特征数据的水可乳化硬蜡：熔体指数= 1500 在160℃下，在325g负荷下测量的20MFI单位酸值=10-60Höppler硬度= 400-800巴，在23℃下通过DGF标准方法M-III 9a（57）测量。

2. 发明授权

US4438008A Lubricant, containing esterified ethylene/acrylic acid or ethylene/maleic acid copolymers as the active ingredient, for moulding chlorine-containing thermoplastics 失效
标题翻译：含有酯化乙烯/丙烯酸或乙烯/马来酸共聚物作为活性成分的润滑剂，用于成型含氯热塑性塑料
公开(公告)号：US4438008A
公开(公告)日：1984-03-20
申请号：US348276
申请日：1982-02-12
申请人： Dieter Oeder , Walter Ziegler , Manfred Daeuble , Wolfram Dietsche , Albert Hettche , Stefan Weiss
发明人： Dieter Oeder , Walter Ziegler , Manfred Daeuble , Wolfram Dietsche , Albert Hettche , Stefan Weiss
IPC分类号： C08L27/00 , C08L1/00 , C08L23/00 , C08L23/08 , C08L27/06 , C08L33/00 , C08L33/02 , C08L35/00 , C08L101/00 , C10M3/12
CPC分类号： C08L27/06 , C08L23/08
摘要： A lubricant for molding chlorine-containing thermoplastics, which contains ethylene/acrylic acid or ethylene/maleic acid copolymers esterified, in a molar ratio of carboxyl groups to alcoholic hydroxyl groups of from 1:0.2 to 1:1, with C.sub.1 -C.sub.20 -aliphatic alcohols which may or may not contain ether groups, the copolymers, prior to esterification, having a mean molecular weight of from 500 to 10,000 and containing from 2 to 15% by weight of acrylic acid or from 1 to 8% by weight of maleic acid as copolymerized units, the percentages being based on copolymer.
摘要翻译：用于模塑含氯热塑性塑料的润滑剂，其含有羧酸与醇羟基的摩尔比为1:0.2至1:1的乙烯/丙烯酸或乙烯/马来酸共聚物与C 1 -C 20脂族可以或可以不含有醚基团的醇，该共聚物，在酯化之前，其平均分子量为500至10,000，并含有2至15重量％的丙烯酸或1至8重量％的马来酸作为共聚单元，百分比基于共聚物。

3. 发明授权

US4406705A Hard waxes comprising terpolymers of ethylene with unsaturated carboxylic acids and unsaturated carboxylic acid esters 失效
标题翻译：硬蜡包括乙烯与不饱和羧酸和不饱和羧酸酯的三元共聚物
公开(公告)号：US4406705A
公开(公告)日：1983-09-27
申请号：US349159
申请日：1982-02-16
申请人： Dieter Oeder , Wolfram Dietsche , Stefan Weiss , Walter Ziegler , Albert Hettche
发明人： Dieter Oeder , Wolfram Dietsche , Stefan Weiss , Walter Ziegler , Albert Hettche
IPC分类号： C08F210/00 , C08F210/02 , C09G1/00 , D06M15/263 , C08L91/06
CPC分类号： C08F210/02
摘要： Water-emulsifiable hard waxes consisting of homogeneous terpolymers of ethylene with--based on weight of terpolymer--from 1 to 8% by weight of C.sub.3 -C.sub.8 -olefinically unsaturated carboxylic acids and from 0.5 to 10% by weight of C.sub.1 -C.sub.12 -alkyl esters of such unsaturated carboxylic acids and having a Staudinger index, determined according to DIN 53,728, of from 5 to 55, an acid number of from 8 to 62 and a Hoppler hardness, measured by DFG standard method M-III-9a(57), at 23.degree. C., of from 250 to 800 bar, are obtained by copolymerizing ethylene with olefinically unsaturated C.sub.3 -C.sub.8 -carboxylic acids and esters of such acids with C.sub.1 -C.sub.12 -alkanols in a continuous process in the presence of a free radical initiator at from 150.degree. to 300.degree. C. under a pressure of from 1,000 to 3,000 bar, using a weight ratio of ethylene:acid:acrylate of from 500:1:1 to 20:1:1, in a one-phase polymerization medium in which the monomers are soluble, in the presence of from 0.01 to 8% by weight, based on the sum of the monomers, of a regulator, from 3 to 25% by weight of the ethylene being converted and the copolymer formed being removed continuously from the reaction zone.
摘要翻译：由均相的三元共聚物组成的水可乳化的硬蜡，其基于三元共聚物的重量 - 1至8重量％的C 3 -C 8 - 烯属不饱和羧酸和0.5至10重量％的C 1 -C 12烷基酯的这种不饱和羧酸，并且根据DIN 53,728测定的Staudinger指数为5至55，酸值为8至62，Höppler硬度通过DFG标准方法M-III-9a（57）测量，通过在自由基引发剂存在下，在连续方法中将乙烯与烯属不饱和C 3 -C 8 - 羧酸和这些酸的酯与C 1 -C 12 - 链烷醇共聚获得，其熔点为23℃，在1000-3000巴的压力下，使用乙烯：酸：丙烯酸酯的重量比为500:1:1至20:1:1的单相聚合介质其中单体可溶，在0.01至8重量％的存在下，基于单体，调节剂，3至25重量％的乙烯被转化，形成的共聚物从反应区连续除去。

4. 发明授权

US5756627A High molecular weight homopolymers and copolymers of ethene 失效
标题翻译：乙烯的高分子量均聚物和共聚物
公开(公告)号：US5756627A
公开(公告)日：1998-05-26
申请号：US954429
申请日：1992-09-30
申请人： Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
发明人： Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
IPC分类号： C08F4/02 , C08F4/18 , C08F4/22 , C08F4/24 , C08F10/00 , C08F110/02 , C08F10/02
CPC分类号： C08F10/00 , C08F110/02
摘要： The present invention relates to high molecular weight homopolymers and copolymers of ethene, which homopolymer or copolymer is obtained by polymerizing the monomer(s) at a temperature of from 70.degree. to 150.degree. C. and under a pressure of from 2 to 150 bar in contact witha chromium trioxide catalyst, (1) loading a support based on silicon dioxide with (2) either chromium trioxide or a chromium compound capable of being converted to chromium trioxide under the conditions of stage (3) below and then (3) heating the resulting intermediate in a gas stream containing oxygen, the support (1) being a special silica xerogel obtained by extracting not more than 30% of the water from a silica hydrogel by means of an alkanol, an alkanone or a mixture thereof followed by drying, comminution and fractional screening.
摘要翻译：本发明涉及乙烯的高分子量均聚物和共聚物，其均聚物或共聚物是通过在70℃至150℃的温度和2至150巴的压力下将单体聚合而获得的与三氧化铬催化剂接触，（1）在下述阶段（3）的条件下，将（2）三氧化铬或能够转化成三氧化铬的铬化合物（2）加载基于二氧化硅的载体，然后（3）加热在含有氧的气流中产生中间体，所述载体（1）是通过使用烷醇，烷酮或其混合物从二氧化硅水凝胶中提取不超过30％的水而获得的特殊二氧化硅干凝胶，然后干燥，粉碎和分数筛选。

5. 发明授权

US4074040A Manufacture of ethylene polymers in an autoclave reactor 失效
标题翻译：在高压釜反应器中制造乙烯聚合物
公开(公告)号：US4074040A
公开(公告)日：1978-02-14
申请号：US758208
申请日：1977-01-10
申请人： Dieter Oeder , Hans Gropper , Friedrich Urban
发明人： Dieter Oeder , Hans Gropper , Friedrich Urban
IPC分类号： C08F10/00 , C08F2/02 , C08F2/34 , C08F10/02
CPC分类号： C08F10/02
摘要： Ethylene polymers are manufactured by polymerizing ethylene under high pressure at high temperatures in an autoclave reactor. The heat of reaction generated by the polymerization is removed, within the reactor, by a cooling system in which the cooling medium is ethylene; the pressure of the monomer in the cooling system should differ by from 0 to 200 bars from the pressure prevailing in the polymerization system, and the temperature of the monomer on entering the cooling system is at least 40.degree. C. lower than the temperature prevailing in the autoclave. The process permits an increase in the conversion achieved in the polymerization reaction.
摘要翻译：乙烯聚合物通过在高压釜反应器中在高压下高压聚乙烯来制造。在反应器内通过冷却介质为乙烯的冷却系统除去聚合产生的反应热; 冷却系统中单体的压力应与聚合体系中的压力相差0至200巴，进入冷却系统的单体温度低于低于常温下的温度至少40℃ 高压灭菌器该方法允许在聚合反应中实现的转化率增加。

6. 发明授权

US3987020A Manufacture of ethylene polymers 失效
标题翻译：乙烯聚合物的制造
公开(公告)号：US3987020A
公开(公告)日：1976-10-19
申请号：US569271
申请日：1975-04-18
申请人： Hans Gropper , Dieter Oeder , Friedrich Urban
发明人： Hans Gropper , Dieter Oeder , Friedrich Urban
IPC分类号： C08F10/00 , C08F2/34 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2/02 , C08F2/38
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16
摘要： Ethylene polymers are produced at pressures between 1000 and 4000 atmospheres and temperatures of from 120.degree. to 300.degree. C in a reaction zone having an 1/d ratio of from 10:1 to 20:1 while shear forces act on the reaction mixture. The ethylene is fed continuously and radially to the reaction zone at a velocity of from 2 to 20 m/sec. The average residence time of the reaction mixture in the reaction zone is from 20 to 90 seconds. The products show a broad molecular weight distribution and are particularly advantageous for use as extruded coatings.

7. 发明授权

US5189123A Catalyst for the preparation of high molecular weight homopolymers and copolymers of ethene, and the manufacture thereof 失效
标题翻译：用于制备高分子量重量共聚物和乙烯共聚物的催化剂及其制备方法
公开(公告)号：US5189123A
公开(公告)日：1993-02-23
申请号：US599873
申请日：1990-10-19
申请人： Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
发明人： Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
IPC分类号： C08F4/02 , C08F4/18 , C08F4/22 , C08F4/24 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F110/02
摘要： The present invention relates to a novel catalyst for the preparation of high molecular weight homopolymers and copolymers of ethene, which catalyst is obtainable by(1) loading a support based on silicon dioxide with(2) either chromium trioxide or a chromium compound capable of being converted to chromium trioxide under the conditions of stage (3) below and then(3) heating the resulting intermediate in a gas stream containing oxygen.the support (1) being a special silica xerogel obtained by extracting not more than 30% of the water from a silica hydrogel by means of an alkanol, an alkanone or a mixture thereof followed by drying, comminution and fractional screening.
摘要翻译：本发明涉及一种用于制备乙烯的高分子量均聚物和共聚物的新催化剂，该催化剂可通过以下步骤获得：（1）将基于二氧化硅的载体与（2）三氧化铬或能够形成在下面的阶段（3）的条件下转化成三氧化铬，然后（3）在含氧的气流中加热得到的中间体。载体（1）是通过链烷醇，烷酮或其混合物从二氧化硅水凝胶中提取不超过30％的水而获得的特殊二氧化硅干凝胶，然后干燥，粉碎和分级筛选。

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