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1. 发明申请

US20050009688A1 Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom 失效
标题翻译：包括羟基或静止反应性官能团的膨胀的阴离子化合物及其催化剂活化剂
公开(公告)号：US20050009688A1
公开(公告)日：2005-01-13
申请号：US10875475
申请日：2004-06-24
申请人： David Babb , David Neithamer , Richard Campbell , Grant Jacobsen , Edmund Carnahan
发明人： David Babb , David Neithamer , Richard Campbell , Grant Jacobsen , Edmund Carnahan
IPC分类号： C07F5/02 , C07F5/06 , C07F7/08 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C07F5/027 , C07F5/062 , C07F5/066 , C07F7/0803 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F4/61908 , C08F4/65908 , C08F210/14 , C08F2500/12
摘要： A cocatalyst or cocatalyst component, including a compound corresponding to the formula: (A*+a)b(Z*J*j)−cd, wherein: A* is a cation of from 1 to 80 atoms, not counting hydrogen atoms, Z* is an anion group of from 1 to 50 atoms, not counting hydrogen atoms, containing two or more Lewis base sites; J* is a Lewis acid of from 1 to 80, not counting hydrogen atoms, coordinated to at least one Lewis base site, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality, j is from 2 to 12 and a, b, c, and d are integers from 1 to 3, with the proviso that a×b is equal to c×d, and provided further that one or more of A*, Z* or J* comprises a hydroxyl group or a polar group containing quiescent reactive functionality.
摘要翻译：一种助催化剂或助催化剂组分，包括对应于下列化学式的化合物：（A * a + b）（Z * J * j）c> d，其中：A *是1至80个原子的阳离子，不计数氢原子，Z *是1至50个原子的阴离子基团，不计算含有两个或更多个路易斯碱基位点的氢原子; J *是1至80的路易斯酸，不计数氢原子，与至少一个路易斯碱基位点配位，并且任选地两个或更多个这样的J *基团可以在具有多个路易斯酸官能团的部分中连接在一起，j是 2至12，a，b，c和d为1至3的整数，条件是axb等于cxd，并进一步提供A *，Z *或J *中的一种或多种包含羟基或含有静止反应性官能团的极性基团。

2. 发明申请

US20070105709A1 Chemically-modified supports and supported catalyst systems prepared therefrom 失效
标题翻译：由其制备的化学改性的载体和负载的催化剂体系
公开(公告)号：US20070105709A1
公开(公告)日：2007-05-10
申请号：US11526242
申请日：2006-09-25
申请人： Edmund Carnahan , David Neithamer
发明人： Edmund Carnahan , David Neithamer
IPC分类号： B01J37/00 , C08F4/44
CPC分类号： B01J31/14 , B01J31/0239 , B01J31/0254 , B01J31/0268 , B01J31/0274 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/65916 , C08F210/14
摘要： The present invention provides a chemically-modified support comprising an inorganic oxide containing optionally functionalized hydroxyl groups, having chemically linked thereto the cation of a cation/anion pair. The present invention further provides a supported catalyst system comprising the chemically-modified support as described above, and a transition metal compound of Groups 3-10 (preferably a Group 4 metal compound) containing at least one π-bonded anionic ligand group, said transition metal compound being capable of reacting with the chemically-modified support through the cation of the cation/anion pair to thereby render the transition metal compound catalytically active. The present invention further provides a process for preparing the chemically-modified support of the invention. The present invention further provides an addition polymerization process comprising contacting one or more addition polymerizable monomers with the supported catalyst system of the invention under addition polymerization conditions.
摘要翻译：本发明提供一种化学修饰的载体，其包含含有任选官能化羟基的无机氧化物，其与阳离子/阴离子对的阳离子化学连接。本发明进一步提供了一种载体催化剂体系，其包括如上所述的化学改性的载体和含有至少一个π键合的阴离子配体基团的3-10族（优选第4族金属化合物）的过渡金属化合物，所述转变金属化合物能够通过阳离子/阴离子对的阳离子与化学改性的载体反应，从而使过渡金属化合物具有催化活性。本发明还提供了制备本发明的化学改性载体的方法。本发明进一步提供加成聚合方法，其包括在加成聚合条件下使一种或多种可加聚的单体与本发明的负载型催化剂体系接触。

3. 发明申请

US20080021172A1 Functionalized Poly(4-Methyl-1-Pentene) 有权
标题翻译：官能化聚（4-甲基-1-戊烯）
公开(公告)号：US20080021172A1
公开(公告)日：2008-01-24
申请号：US11632372
申请日：2005-01-21
申请人： John Briggs , Edmund Carnahan , Phillip Hustad , Tia Jackson
发明人： John Briggs , Edmund Carnahan , Phillip Hustad , Tia Jackson
IPC分类号： C08F10/14 , C08F8/00 , C08F8/06
CPC分类号： C08F10/00 , C08F4/65912 , C08F8/00 , C08F110/14 , C08F4/659 , C08F4/64193 , C08F2500/02 , C08F2500/03 , C08F2500/15 , C08F4/6411
摘要： An olefin polymer having greater than 95 percent chain end unsaturation, where greater than 80 percent of said unsaturation comprises a 1,2-disubstituted olefinic unsaturation, especially polymers comprising in polymerized form 4-methyl-1-pentene and more especially highly isotactic polymers, a process of manufacture, methods to functionalize and articles formed therefrom.
摘要翻译：具有大于95％的链末端不饱和度的烯烃聚合物，其中大于80％的所述不饱和度包括1,2-二取代的烯属不饱和度，特别是包含聚合形式的4-甲基-1-戊烯和更特别高度全同立构聚合物的聚合物，制造方法，官能化方法和由其形成的制品。

4. 再颁专利

USRE42276E1 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：USRE42276E1
公开(公告)日：2011-04-05
申请号：US12604905
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08L23/00 , C08F4/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: MS ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.
摘要翻译：聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。一些聚合物组合物的特征在于基本上不存在戊基或甲基支链和满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约12.5，y大于或等于一些聚合物的特征在于满足以下关系的熔体强度（MS）：MS≥xI 2 + y其中x大于或等于约3，y大于或等于约4.5，以及分子量分布大于3.还公开了制备聚合物的方法。

5. 发明申请

US20080051537A1 Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers 审中-公开
标题翻译：负载的双（羟基芳基芳氧基）催化剂用于制造聚合物
公开(公告)号：US20080051537A1
公开(公告)日：2008-02-28
申请号：US11632371
申请日：2005-08-09
申请人： Edmund Carnahan , David Devore , Gregory Godziela , Paul Vosejpka , Burkhard Wagner , Joseph Coalter
发明人： Edmund Carnahan , David Devore , Gregory Godziela , Paul Vosejpka , Burkhard Wagner , Joseph Coalter
IPC分类号： C08F4/06 , B01J31/12 , C08F10/02 , C08F10/06
CPC分类号： B01J31/223 , B01J31/143 , B01J31/146 , B01J2231/122 , B01J2531/49 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F2410/01 , C08F2410/02 , C08F4/65916 , C08F2500/03 , C08F2500/01 , C08F210/16 , C08F4/64193
摘要： A supported, heterogeneous catalyst composition for use in polymerization of addition polymerizable monomers to form high molecular weight polymers, comprising: 1) a substrate comprising a solid, particulated, high surface area, surface modified, inorganic oxide compound, 2) a Group 4 metal complex of a bis(hydroxyarylaryloxy) ligand; and optionally 3) an activating cocatalyst for the metal complex.
摘要翻译：一种用于聚合加成聚合单体以形成高分子量聚合物的载体，非均相催化剂组合物，包括：1）包含固体，微粒，高表面积，表面改性的无机氧化物化合物的基材，2）第4族金属双（羟基芳基芳氧基）配体的络合物; 和任选的3）金属络合物的活化助催化剂。

6. 再颁专利

USRE43004E1 High melt strength polymers and method of making same 有权
标题翻译：高熔体强度聚合物及其制备方法
公开(公告)号：USRE43004E1
公开(公告)日：2011-12-06
申请号：US12604940
申请日：2009-10-23
申请人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
发明人： Alexander W. DeGroot , James C. Stevens , Sylvie Y. Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel D. VanderLende
IPC分类号： C08L23/08 , C08L23/10
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition that has a backbone chain; and a plurality of long chain branches connected to the backbone is described. The polymer composition also has a value of 2g′LCB-1g′LCB g′2LCB-g′1LCB that is less than about 0.22, where 1g′LCB g′2LCB is the long chain branching index for a fraction of the composition having a Mw of 100,000 and 2g′LCB g′1LCB is the long chain branching index for a fraction of the composition having a Mw of 500,000.
摘要翻译：具有主链的聚合物组合物; 并且描述了连接到主干的多个长链分支。聚合物组合物还具有小于约0.22的2g'LCB-1g'LCB g'2LCB-g'1LCB的值，其中1g'LCB g'2LCB是组分的一部分的长链支化指数，其具有 Mw为100,000和2g'LCB g'1LCB是Mw为500,000的组合物的一部分的长链支化指数。

7. 发明申请

US20070167578A1 Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation 有权
标题翻译：催化剂组合物包含用于乙烯多嵌段共聚物形成的穿梭剂
公开(公告)号：US20070167578A1
公开(公告)日：2007-07-19
申请号：US10589377
申请日：2005-03-17
申请人： Daniel Arriola , Edmund Carnahan , Yunwa Cheung , David Devore , David Graf , Phillip Hustad , Roger Kuhlman , Colin Shan , Benjamin Poon , Gordon Roof , James Stevans , Pamela Stirn , Timothy Wenzel
发明人： Daniel Arriola , Edmund Carnahan , Yunwa Cheung , David Devore , David Graf , Phillip Hustad , Roger Kuhlman , Colin Shan , Benjamin Poon , Gordon Roof , James Stevans , Pamela Stirn , Timothy Wenzel
IPC分类号： C08F297/02
CPC分类号： B32B27/327 , B32B27/06 , B32B27/32 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/14 , C08F110/02 , C08F210/14 , C08F210/16 , C08F295/00 , C08F297/00 , C08F297/08 , C08F297/083 , C08F297/086 , C08F2410/01 , C08F2410/04 , C08F2420/02 , C08L23/02 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08L23/10 , C08L53/00 , C08L53/005 , Y10T428/24942 , Y10T428/24992 , Y10T428/2826 , Y10T428/31573 , Y10T428/31587 , C08F2/38 , C08F4/65904 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F4/64148 , C08F4/64193 , C08F4/64048 , C08F4/6411 , C08F4/64144 , C08F2500/08 , C08F4/64113 , C08L2666/02 , C08L2666/04 , C08F2500/12 , C08F2500/20 , C08F210/08 , C08F2500/11 , C08F2500/21 , C08F210/02 , C08F212/08 , C08F232/02 , C08F232/08
摘要： A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
摘要翻译：一种用于形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个化学或物理性质不同的链段或嵌段，使用该多嵌段共聚物的聚合方法和所得聚合物，其中组合物包含混合物或反应产物由（A）第一金属络合物烯烃聚合催化剂，（B）能够在等效聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二金属络合物烯烃聚合催化剂，以及（C）链式穿梭剂。

8. 发明申请

US20050065286A1 High melt strength polymers and method of making same 有权
公开(公告)号：US20050065286A1
公开(公告)日：2005-03-24
申请号：US10920485
申请日：2004-08-17
申请人： Alexander DeGroot , James Stevens , Sylvie Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel Vanderlende
发明人： Alexander DeGroot , James Stevens , Sylvie Desjardins , Jeffrey Weinhold , Edmund Carnahan , David Gillespie , Daniel Vanderlende
IPC分类号： C08F2/00 , C08F4/02 , C08F4/64 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F290/04 , C08L23/04 , C08L23/06 , C08L23/08 , C08F4/44
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2314/02 , C08L2314/06 , Y02P20/52 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08F2/06 , C08L2666/04 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/02 , C08F2/00 , C08F2500/08 , C08F2500/05 , C08F2500/17 , C08F2500/26
摘要： A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship: M ⁢ ⁢ S ≥ x I 2 + y where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship: M ⁢ ⁢ S ≥ x I 2 + y where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.

9. 发明申请

US20070167315A1 Catalyst composition comprising shuttling agent for ethylene copolymer formation 有权
标题翻译：催化剂组合物包含用于乙烯共聚物形成的穿梭剂
公开(公告)号：US20070167315A1
公开(公告)日：2007-07-19
申请号：US10589378
申请日：2005-03-17
申请人： Daniel Arriola , David Devore , Edmund Carnahan , Phillip Hustad , Roger Kuhlman , Timothy Wenzel
发明人： Daniel Arriola , David Devore , Edmund Carnahan , Phillip Hustad , Roger Kuhlman , Timothy Wenzel
IPC分类号： C08F4/02 , C08F4/44
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , C08F297/08 , C08L23/06 , C08L23/0815 , C08L23/0853 , C08F4/65904 , C08F2/38 , C08L2666/06 , C08F2500/09 , C08F2500/03 , C08F210/14 , C08F2500/08 , C08F4/64048 , C08F4/6411 , C08F4/64193 , C08F4/7006
摘要： A composition for use in forming a multi-block copolymer from a single polymerizable monomer, said copolymer containing therein two or more segments or blocks differing in branching index, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, at least one of catalyst (A) or catalyst (B) being capable of forming a branched polymer by means of chain walking or reincorporation of in situ formed olefinic polymer chains, and (C) a chain shuttling agent.
摘要翻译：一种用于从单一可聚合单体形成多嵌段共聚物的组合物，所述共聚物中含有两个或更多个支链指数不同的链段或嵌段，使用其的聚合方法和所得聚合物，其中组合物包含混合物或（A）第一烯烃聚合催化剂，（B）能够在相同的聚合条件下制备由催化剂（A）制备的聚合物在化学或物理性质上不同的聚合物的第二种烯烃聚合催化剂，至少催化剂（A）或催化剂（B）中的一种能够通过原位形成的烯烃聚合物链的链式步行或再结合形成支链聚合物，和（C）链式穿梭剂。

10. 发明申请

US20060199930A1 Ethylene/alpha-olefins block interpolymers 有权
标题翻译：乙烯/α-烯烃嵌段互聚物
公开(公告)号：US20060199930A1
公开(公告)日：2006-09-07
申请号：US11376835
申请日：2006-03-15
申请人： Colin Li Pi Shan , Lonnie Hazlitt , Yunwa Cheung , Benjamin Poon , Phillip Hustad , Roger Kuhlman , Edmund Carnahan , Xiaohua Qui , Angela Taha
发明人： Colin Li Pi Shan , Lonnie Hazlitt , Yunwa Cheung , Benjamin Poon , Phillip Hustad , Roger Kuhlman , Edmund Carnahan , Xiaohua Qui , Angela Taha
IPC分类号： C08F112/02
CPC分类号： C08F212/08
摘要： Embodiments of the invention provide a class of ethylene/α-olefin block interpolymers. The ethylene/α-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/α-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (“TREF”), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/α-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.3.
摘要翻译：本发明的实施方案提供一类乙烯/α-烯烃嵌段互聚物。乙烯/α-烯烃互聚物的特征在于平均嵌段指数ABI，其大于零并且高达约1.0，分子量分布为M / SUB>，大于约1.3。优选地，嵌段指数为约0.2至约1.另外或替代地，嵌段乙烯/α-烯烃互聚物的特征在于具有通过升温洗脱分级（“TREF”）获得的至少一个馏分，其中部分具有大于约0.3且高达约1.0的嵌段指数，并且所述乙烯/α-烯烃互聚物具有大于约1.3的分子量分布，M分子量。

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