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1. 发明授权

US07230051B2 Use of polyacrylate-modified polysiloxanes as levelling agents in coating compositions 有权
标题翻译：在涂料组合物中使用聚丙烯酸酯改性的聚硅氧烷作为流平剂
公开(公告)号：US07230051B2
公开(公告)日：2007-06-12
申请号：US10465536
申请日：2003-06-19
申请人： Bernd Gobelt , Alfred Bubat , Albert Frank , Karlheinz Haubennestel
发明人： Bernd Gobelt , Alfred Bubat , Albert Frank , Karlheinz Haubennestel
IPC分类号： C08L83/02
CPC分类号： C08G77/442 , C08F293/005 , C09D7/47 , Y10S525/934
摘要： The invention relates to the use of block copolymers as leveling agents for surface coatings, having a weight-average molecular weight of from 1000 to 100000. The leveling agent is a linear or branched block copolymer composed of a polysiloxane block and one or more blocks prepared from ethylenically unsaturated monomers by controlled free-radical addition polymerization.The invention also relates to coating compositions which comprise the leveling agent.
摘要翻译：本发明涉及嵌段共聚物作为表面涂料的流平剂的用途，其重均分子量为1000-100000。流平剂是由聚硅氧烷嵌段和一个或多个嵌段制备的直链或支链嵌段共聚物通过控制的自由基加成聚合从烯属不饱和单体中获得。本发明还涉及包含流平剂的涂料组合物。

2. 发明授权

US06710127B2 Levelling agents for surface coatings 失效
标题翻译：流平剂表面涂层
公开(公告)号：US06710127B2
公开(公告)日：2004-03-23
申请号：US09967499
申请日：2001-09-28
申请人： Karlheinz Haubennestel , Alfred Bubat , Albert Frank
发明人： Karlheinz Haubennestel , Alfred Bubat , Albert Frank
IPC分类号： C08L7900
CPC分类号： C08F290/04 , C08F283/12 , C08F290/06 , C08F290/061 , C08F290/068 , C09D7/47
摘要： The invention relates to levelling agents for surface coatings having a weight-average molecular weight of from 5000 to 100,000. The levelling agent is a branched polymer comprising a free-radically or ionically polymerized base molecule into which macromonomeric units containing at one end a monomeric unit which has an ethylenically unsaturated bond and possessing a weight-average molecular weight of from 1000 to 30,000 have been incorporated by free-radical or ionic copolymerization, the weight fraction of the macromonomeric units, based on the total weight of the branched polymer, being from 1 to 60% by weight. The invention further relates to the use of appropriate polymers as levelling agents for coating formulations and to coating formulations comprising the levelling agents of the invention.
摘要翻译：本发明涉及重均分子量为5000至100,000的表面涂层流平剂。流平剂是包含自由基或离子聚合的碱分子的支链聚合物，其中含有一端具有烯键式不饱和键并具有1000至30,000重均分子量的单体单元的大分子单体已经被引入通过自由基或离子共聚，基于支化聚合物的总重量，大分子单元的重量分数为1至60重量％。本发明还涉及合适的聚合物作为流平剂用于涂布制剂和包含本发明的流平剂的包衣制剂的用途。

3. 发明授权

US07122599B2 Coating compositions and polymeric moulding compounds having anti-adhesion and dirt repellency properties 有权
标题翻译：涂料组合物和具有防粘附性和防污性的聚合物模塑料
公开(公告)号：US07122599B2
公开(公告)日：2006-10-17
申请号：US09967504
申请日：2001-09-28
申请人： Karlheinz Haubennestel , Alfred Bubat , Albert Frank , Axel Woocker , Udo Krappe
发明人： Karlheinz Haubennestel , Alfred Bubat , Albert Frank , Axel Woocker , Udo Krappe
IPC分类号： C08L43/04
CPC分类号： C08G77/42 , C08G77/442 , C08G77/445 , C08G77/458
摘要： The invention relates to coating compositions having anti-adhesion and dirt repellency properties, these compositions being admixed as additive with from 0.1 to 10% by weight, based on the solids content of the coating composition, of a branched polymer which possesses a weight-average molecular weight of from 2000 to 200,000 and comprises a polymeric base molecule and also polydiorganosiloxane side chains which are bonded covalently to the base molecule via Si—C bonds, have a weight-average molecular weight of between 1000 and 30,000, and whose fraction of the total weight of the branched polymer is from 5 to 25% by weight. The present invention further relates to polymeric moulding compounds having anti-adhesion and dirt repellency properties, to which this branched polymer is added as additive in an amount of from 0.1 to 10% by weight, based on the total weight of the polymeric moulding compounds. The invention additionally relates to the use of the branched polymers as additives for coating compositions and polymeric moulding compounds.
摘要翻译：本发明涉及具有防粘附性和防污性的涂料组合物，这些组合物以占涂料组合物的固体含量为基准的0.1至10重量％的混合添加剂，其具有重均分子量分子量为2000至200,000，并且包含通过Si-C键与基础分子共价键合的聚合物基础分子和聚二有机硅氧烷侧链，其重均分子量为1000至30,000，并且其分子量为支链聚合物的总重量为5〜25重量％。本发明还涉及具有抗粘附性和防污性的聚合物模塑料，该支化聚合物以其占聚合物模塑料总重量的0.1至10重量％的量加入其中。本发明还涉及使用支化聚合物作为涂料组合物和聚合物模塑料的添加剂。

4. 发明授权

US08512465B2 Use of copolymers as adhesion promoters in lacquers 失效
标题翻译：在漆中使用共聚物作为粘合促进剂
公开(公告)号：US08512465B2
公开(公告)日：2013-08-20
申请号：US12227070
申请日：2007-05-04
申请人： Karlheinz Haubennestel , Stefan Mossmer , Thomas Launag , Albert Frank
发明人： Karlheinz Haubennestel , Stefan Mossmer , Thomas Launag , Albert Frank
IPC分类号： C08F26/06 , C08F126/06 , C08F226/06 , C04B14/00 , C09B67/00
CPC分类号： C09D139/00 , C09D7/65 , C09D131/02 , C09D133/06 , C09D135/02 , C09D135/08
摘要： The invention relates to the use of copolymers which as well as other monomers contain in copolymerized form 10% to 90% by weight of monomers containing heterocyclic basic groups, and which do not contain vinylpyrrolidone as a monomer component, as additives in paints for improving the adhesion of the solid paint film to a substrate.The invention also relates to cured and uncured polymer compositions comprising copolymers which as well as other monomers contain in copolymerized form 10% to 90% by weight of monomers containing heterocyclic basic groups, and which do not contain vinylpyrrolidone as a monomer component, as adhesion improver additions.
摘要翻译：本发明涉及共聚物的用途以及其它单体含有10重量％至90重量％的含有杂环碱基的单体，并且不含乙烯基吡咯烷酮作为单体组分的共聚形式的单体作为改进涂料的添加剂固体漆膜粘附到基材上。本发明还涉及包含共聚物的固化和未固化的聚合物组合物，以及其它单体含有10重量％至90重量％的含有杂环碱基的单体并且不含乙烯基吡咯烷酮作为单体组分的共聚物作为粘合改进剂添加。

5. 发明申请

US20100029838A1 Use of Copolymers as Adhesion Promoters in Lacquers 失效
标题翻译：在树脂中使用共聚物作为粘合促进剂
公开(公告)号：US20100029838A1
公开(公告)日：2010-02-04
申请号：US12227070
申请日：2007-05-04
申请人： Karlheinz Haubennestel , Stefan Mossmer , Thomas Launag , Albert Frank
发明人： Karlheinz Haubennestel , Stefan Mossmer , Thomas Launag , Albert Frank
IPC分类号： C08L39/00
CPC分类号： C09D139/00 , C09D7/65 , C09D131/02 , C09D133/06 , C09D135/02 , C09D135/08
摘要： Use of copolymers as adhesion promoters in paints The invention relates to the use of copolymers which as well as other monomers contain in copolymerized form 10% to 90% by weight of monomers containing heterocyclic basic groups, and which do not contain vinylpyrrolidone as a monomer component, as additives in paints for improving the adhesion of the solid paint film to a substrate.The invention also relates to cured and uncured polymer compositions comprising copolymers which as well as other monomers contain in copolymerized form 10% to 90% by weight of monomers containing heterocyclic basic groups, and which do not contain vinylpyrrolidone as a monomer component, as adhesion improver additions.
摘要翻译：共聚物在涂料中的粘合促进剂的用途本发明涉及共聚物的用途以及其它单体含有共聚形式的10重量％至90重量％的含有杂环碱基的单体，并且不含乙烯基吡咯烷酮作为单体成分作为涂料中的添加剂，用于改善固体漆膜与基材的粘附性。本发明还涉及包含共聚物的固化和未固化的聚合物组合物，以及其它单体含有10重量％至90重量％的含有杂环碱基的单体并且不含乙烯基吡咯烷酮作为单体组分的共聚物作为粘合改进剂添加。

6. 发明授权

US08987410B2 Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use 有权
标题翻译：末端不饱和，缩水甘油基大分子单体，可从其获得的聚合物，制备和用途
公开(公告)号：US08987410B2
公开(公告)日：2015-03-24
申请号：US13379303
申请日：2010-06-04
申请人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis
发明人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis
IPC分类号： C07C231/12 , C07C41/03 , C07C233/20 , C07C43/178 , C08G65/26 , C08G65/00 , C08G65/22
CPC分类号： C08G65/2609 , C08G65/00 , C08G65/22 , C08G65/2612
摘要： Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.
摘要翻译：制备大分子单体的方法，其中起始化合物H2C = CR1-C6H4-s（R4）s-R3-OH或H2C = CR2-CO-NH-R3-OH，其中R1和R2各自为H或直链或具有1至4个碳原子的支链烷基，R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基，亚芳基，并且基团R 4各自彼此独立地为具有1至20个碳原子且s = 0-4的直链或支链烷基，芳烷基，烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n（起始化合物）:n（环氧乙烷化合物）的摩尔量的摩尔比为1：100〜1：1的环氧乙烷环的开环自由基聚合。可以通过该方法获得的大分子单体，可从其获得的聚合物及其作为涂料组合物，塑料和化妆品中的添加剂的用途。

7. 发明申请

US20120165414A1 TERMINAL UNSATURATED, GLYCIDOL-BASED MACROMONOMERS, POLYMERS OBTAINABLE THEREFROM, PREPARATION AND USE 有权
标题翻译：端基不饱和，基于甘氨酸的麦芽糖，可获得的聚合物，制备和使用
公开(公告)号：US20120165414A1
公开(公告)日：2012-06-28
申请号：US13379303
申请日：2010-06-04
申请人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis
发明人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis
IPC分类号： A61K8/81 , C07C231/12 , C07C43/178 , C09D125/08 , C08F220/58 , C08F216/14 , C09D133/26 , C07C41/03 , C07C233/20
CPC分类号： C08G65/2609 , C08G65/00 , C08G65/22 , C08G65/2612
摘要： Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.
摘要翻译：制备大分子单体的方法，其中起始化合物H2C = CR1-C6H4-s（R4）s-R3-OH或H2C = CR2-CO-NH-R3-OH，其中R1和R2各自为H或直链或具有1至4个碳原子的支链烷基，R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基，亚芳基，并且基团R 4各自彼此独立地为具有1至20个碳原子且s = 0-4的直链或支链烷基，芳烷基，烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n（起始化合物）:n（环氧乙烷化合物）的摩尔量的摩尔比为1：100〜1：1的环氧乙烷环的开环自由基聚合。可以通过该方法获得的大分子单体，可从其获得的聚合物及其作为涂料组合物，塑料和化妆品中的添加剂的用途。

8. 发明申请

US20110294933A1 POLYHYDROXYFUNCTIONAL POLYSILOXANES FOR INCREASING THE SURFACE ENERGY OF THERMOPLASTICS, METHOD FOR PRODUCTION AND USE THEREOF 审中-公开
标题翻译：用于增加热塑性表面能的聚羟基多官能团，其生产方法及其用途
公开(公告)号：US20110294933A1
公开(公告)日：2011-12-01
申请号：US13002720
申请日：2009-07-06
申请人： Wojciech Jaunky , Barbel Gertzen , Albert Frank , Hans-Willi Bogershausen , Alfred Bubat , Jurgen Omeis
发明人： Wojciech Jaunky , Barbel Gertzen , Albert Frank , Hans-Willi Bogershausen , Alfred Bubat , Jurgen Omeis
IPC分类号： C08K5/5419 , C07F7/08 , C08L27/06 , C08L55/02 , C08L23/06 , C08L23/10
CPC分类号： C08G77/38 , C08G77/46
摘要： The invention relates to polyhydroxyfunctional polysiloxanes, which may be produced by the addition of at least one branched polyhydroxyfunctional allyl polyether to a Si—H functional alkyl polysiloxane, to methods for production thereof and the use thereof as additives in thermoplastics and polymeric moulded masses and the thermoplastics and polymeric moulded masses containing the same.
摘要翻译：本发明涉及多羟基官能聚硅氧烷，其可以通过向Si-H官能的烷基聚硅氧烷中加入至少一种支链多羟基官能的烯丙基聚醚制备，其制备方法及其作为热塑性塑料和聚合物成型体中的添加剂的用途，热塑性塑料和含有它们的聚合物成型体。

9. 发明申请

US20120130007A1 POLYMERS OBTAINABLE FROM OXETANE BASED MACROMONOMERS, METHOD FOR THE PRODUCTION THEREOF, AND THE USE THEREOF AS ADDITIVES IN COATING AGENTS AND PLASTICS 有权
标题翻译：可从基于OXETANE的MACROMONOMERS获得的聚合物，其生产方法及其作为涂料和塑料中添加剂的用途
公开(公告)号：US20120130007A1
公开(公告)日：2012-05-24
申请号：US13321357
申请日：2010-05-03
申请人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis , Petra Della Valentina , Bernd Göbelt
发明人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis , Petra Della Valentina , Bernd Göbelt
IPC分类号： C09D133/08 , C08F214/18 , C09D167/00 , C08G63/66 , C09D127/12 , C09D183/04 , C08F230/08 , C08F220/10
CPC分类号： C08G65/18 , C08F220/18 , C08F220/28 , C08F230/08 , C08F2220/285
摘要： A polymer obtainable by free-radical polymerization of one or more oxetane-based macromonomers and optionally one or more further, free-radically polymerizable comonomers, the oxetane-based macromonomer(s) being obtainable by cationic ring-opening polymerization of at least one hydroxyoxetane with a terminally ethylenically unsaturated starter molecule free of allyl groups in a molar ratio (hydroxyoxetane(s):starter molecule) of (100:1) to (1:1) in the presence of at least one suitable catalyst. Processes for preparing the polymer and the use thereof as an additive in coating compositions and plastics.
摘要翻译：可通过一种或多种氧杂环丁烷基大分子单体和任选的一种或多种另外的可自由基聚合的共聚单体的自由基聚合获得的聚合物，所述基于氧杂环丁烷的大分子单体可通过至少一种羟基氧杂环丁烷的阳离子开环聚合在至少一种合适的催化剂的存在下，具有（100:1）至（1:1）摩尔比的（羟基氧杂环丁烷：起始分子）的烯丙基的末端烯属不饱和起始分子。制备聚合物的方法及其在涂料组合物和塑料中作为添加剂的用途。

10. 发明授权

US08501880B2 Polymers obtainable from oxetane based macromonomers, method for the production thereof, and the use thereof as additives in coating agents and plastics 有权
标题翻译：由氧杂环丁烷基大分子单体获得的聚合物，其制备方法及其作为涂料和塑料中的添加剂的用途
公开(公告)号：US08501880B2
公开(公告)日：2013-08-06
申请号：US13321357
申请日：2010-05-03
申请人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis , Petra Della Valentina , Bernd Göbelt
发明人： Wojciech Jaunky , Albert Frank , Alfred Bubat , Jürgen Omeis , Petra Della Valentina , Bernd Göbelt
IPC分类号： C08L29/10 , C09D133/08
CPC分类号： C08G65/18 , C08F220/18 , C08F220/28 , C08F230/08 , C08F2220/285
摘要： A polymer obtainable by free-radical polymerization of one or more oxetane-based macromonomers and optionally one or more further, free-radically polymerizable comonomers, the oxetane-based macromonomer(s) being obtainable by cationic ring-opening polymerization of at least one hydroxyoxetane with a terminally ethylenically unsaturated starter molecule free of allyl groups in a molar ratio (hydroxyoxetane(s):starter molecule) of (100:1) to (1:1) in the presence of at least one suitable catalyst. Processes for preparing the polymer and the use thereof as an additive in coating compositions and plastics.
摘要翻译：可通过一种或多种氧杂环丁烷基大分子单体和任选的一种或多种另外的可自由基聚合的共聚单体的自由基聚合获得的聚合物，所述基于氧杂环丁烷的大分子单体可通过至少一种羟基氧杂环丁烷的阳离子开环聚合在至少一种合适的催化剂的存在下，具有（100:1）至（1:1）摩尔比的（羟基氧杂环丁烷：起始分子）的烯丙基的末端烯属不饱和起始分子。制备聚合物的方法及其在涂料组合物和塑料中作为添加剂的用途。

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