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1. 发明授权

US09005828B2 Redox fuel cells with a catholyte solution containing a polyoxometallate 有权
标题翻译：具有含多金属氧酸盐的阴极电解液的氧化还原型燃料电池
公开(公告)号：US09005828B2
公开(公告)日：2015-04-14
申请号：US12294320
申请日：2007-03-23
申请人： Andrew Martin Creeth , Andrew Robert Potter
发明人： Andrew Martin Creeth , Andrew Robert Potter
IPC分类号： H01M8/04 , H01M8/06 , H01M8/10 , H01M8/18 , H01M8/20 , H01M8/22 , H01M4/86 , H01M4/90
CPC分类号： H01M8/188 , H01M4/8605 , H01M4/9016 , H01M8/1009 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/20 , H01M2300/0082 , Y02E60/521 , Y02E60/528
摘要： This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing fluid communication with the cathode, the catholyte solution comprising a polyoxometallate redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the catholyte solution comprising at least about 0.075M of the said polyoxometallate.
摘要翻译：本发明提供了一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜分离的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，包含多金属氧酸盐氧化还原对的阴极电解液在电解槽操作时在阴极处至少部分还原，并且在这种还原之后至少部分地与氧化剂反应产生重新产生在阴极处，阴极电解液包含至少约0.075M的所述多金属氧酸盐。

2. 发明申请

US20090317668A1 FUEL CELLS 有权
标题翻译：燃料电池
公开(公告)号：US20090317668A1
公开(公告)日：2009-12-24
申请号：US12294320
申请日：2007-03-23
申请人： Andrew Martin Creeth , Andrew Robert Potter
发明人： Andrew Martin Creeth , Andrew Robert Potter
IPC分类号： H01M8/10 , H01M8/04
CPC分类号： H01M8/188 , H01M4/8605 , H01M4/9016 , H01M8/1009 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/20 , H01M2300/0082 , Y02E60/521 , Y02E60/528
摘要： This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing fluid communication with the cathode, the catholyte solution comprising a polyoxometallate redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the catholyte solution comprising at least about 0.075M of the said polyoxometallate.
摘要翻译：本发明提供了一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜分离的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，包含多金属氧酸盐氧化还原对的阴极电解液在电解槽操作时在阴极处至少部分还原，并且在这种还原之后至少部分地与氧化剂反应产生重新产生在阴极处，阴极电解液包含至少约0.075M的所述多金属氧酸盐。

3. 发明授权

US08647781B2 Redox fuel cells 有权
标题翻译：氧化还原燃料电池
公开(公告)号：US08647781B2
公开(公告)日：2014-02-11
申请号：US12864496
申请日：2009-01-23
申请人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
发明人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
IPC分类号： H01M8/10
CPC分类号： H01M8/188 , H01M4/9008 , H01M2008/1095 , H01M2300/0082 , Y02E60/528
摘要： This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing in fluid communication with the cathode, the catholyte solution comprising a redox mediator which is at least partially reduced at the cathode in operation of the cell, and at least partially regenerated by, optionally indirect, reaction with the oxidant after such reduction at the cathode, and a transition metal complex of a multidentate macrocyclic N-donor ligand as a redox catalyst catalysing the regeneration of the mediator.
摘要翻译：本发明提供了一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜分离的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，所述阴极电解液包含氧化还原介体，所述氧化还原介体在所述电池的操作中在所述阴极处至少部分还原，并且至少部分地通过与所述氧化剂的间接反应部分地再生在阴极这样的还原之后，以及多齿大环N-供体配体的过渡金属络合物作为催化介体再生的氧化还原催化剂。

4. 发明授权

US06573229B2 Laundry wash compositions 失效
标题翻译：洗衣组合物
公开(公告)号：US06573229B2
公开(公告)日：2003-06-03
申请号：US10210581
申请日：2002-08-01
申请人： Andrew Martin Creeth , Philippus Cornelis Van Der Hoeven , Edwin John Staples
发明人： Andrew Martin Creeth , Philippus Cornelis Van Der Hoeven , Edwin John Staples
IPC分类号： C11D300
CPC分类号： C11D3/3719 , C11D1/02 , C11D3/06 , C11D3/3723 , C11D17/065
摘要： The present invention relates to compositions for the washing of laundry fabrics, the compositions containing anionic surfactants and a cationic detergency enhancing polymer which may be homopolymer or copolymer.
摘要翻译：本发明涉及用于洗涤衣物的组合物，该组合物含有阴离子表面活性剂和可以是均聚物或共聚物的阳离子去污力增强聚合物。

5. 发明授权

US5789365A Detergent compositions containing soil release polymers 失效
标题翻译：含有污垢释放聚合物的洗涤剂组合物
公开(公告)号：US5789365A
公开(公告)日：1998-08-04
申请号：US755509
申请日：1996-11-22
申请人： Wilfried Blokzijl , Andrew Martin Creeth , Mohamad Sami Falou , Andrew David Green , Michael Hull , Reginald Vear Scowen
发明人： Wilfried Blokzijl , Andrew Martin Creeth , Mohamad Sami Falou , Andrew David Green , Michael Hull , Reginald Vear Scowen
IPC分类号： C11D3/00 , C11D3/37
CPC分类号： C11D3/0036 , C11D3/3715
摘要： A laundry detergent composition contains a surfactant system consisting wholly of anionic surfactant, or of anionic and nonionic surfactants in a ratio at least 0.9:1, a detergency builder, and a soil release polymer which is a defined water-soluble or water-dispersible sulphonated non-end-capped polyester, for example, of terephthalic acid, isophthalic acid, sulphoisophthalic acid and ethylene glycol.
摘要翻译：衣物洗涤剂组合物含有完全由阴离子表面活性剂组成的表面活性剂体系，或比例至少为0.9:1的阴离子和非离子表面活性剂，洗涤助洗剂和污垢释放聚合物，其是限定的水溶性或水分散性磺化非封端聚酯，例如对苯二甲酸，间苯二甲酸，磺基间苯二甲酸和乙二醇。

6. 发明申请

US20130256152A1 CELL 审中-公开
标题翻译：细胞
公开(公告)号：US20130256152A1
公开(公告)日：2013-10-03
申请号：US13879376
申请日：2011-10-11
申请人： Andrew Martin Creeth
发明人： Andrew Martin Creeth
IPC分类号： C25B1/10 , C25B9/10
CPC分类号： C25B1/10 , C25B1/003 , C25B9/08 , C25B9/10 , C25B9/16 , Y02E60/366
摘要： An electrolytic cell comprising an anode in an anode region and a cathode in a cathode region, the anode region and the cathode regions separated by an ion selective polymer electrolyte membrane; an anolyte in flowing fluid communication with the anode, the anolyte comprising water and a redox mediator couple which is at least partially oxidised at the anode in operation of the cell and at least partially reduced by reaction with water after such oxidation at the anode.
摘要翻译：一种电解槽，包括在阳极区域中的阳极和阴极区域中的阴极，所述阳极区域和所述阴极区域被离子选择性聚合物电解质膜隔开; 与阳极流动连通的阳极电解液，所述阳极电解液包含水和氧化还原介体对，所述氧化还原介体对在所述电池的操作中在所述阳极处至少部分氧化，并且在所述阳极处经过氧化后至少部分地通过与水反应而被还原。

7. 发明申请

US20120231363A1 FUEL CELLS 有权
标题翻译：燃料电池
公开(公告)号：US20120231363A1
公开(公告)日：2012-09-13
申请号：US13388981
申请日：2010-08-05
申请人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
发明人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
IPC分类号： H01M8/02 , H01M8/10 , H01M8/24 , H01M8/08
CPC分类号： H01M8/188 , Y02E60/528
摘要： The invention concerns the use as a redox a catalyst and/or mediator in a fuel cell catholyte solution of the compound of Formula (I) wherein: X is selected from hydrogen and from various functional groups; R1-8 are independently selected from hydrogen and various functional groups; wherein R1 and X and/or R5 and X may together form an optionally substituted ring structure; wherein R1 and R2 and/or R2 and R3 and/or R3 and R4 and/or R4 and R8 and/or R8 and R7 and/or R7 and R6 and/or R6 and R5 may together form an optionally substituted ring structure; wherein (L) indicates the optional presence of a linking bond or group between the two neighbouring aromatic rings of the structure, and when present may form an optionally substituted ring structure with one or both of R4 and R8; and wherein at least one substituent group of the structure is a charge-modifying substituent.
摘要翻译：本发明涉及在式（I）化合物的燃料电池阴极液溶液中作为氧化还原催化剂和/或介体的用途，其中：X选自氢和各种官能团; R1-8独立地选自氢和各种官能团; 其中R1和X和/或R5和X可以一起形成任选取代的环结构; 其中R1和R2和/或R2和R3和/或R3和R4和/或R4和R8和/或R8和R7和/或R7和R6和/或R6和R5可以一起形成任选取代的环结构; 其中（L）表示在结构的两个相邻芳环之间任选存在连接键或基团，并且当存在时可以形成具有一个或两个R 4和R 8的任选取代的环结构; 并且其中所述结构的至少一个取代基是电荷改性取代基。

8. 发明申请

US20120107702A1 FUEL CELLS 审中-公开
标题翻译：燃料电池
公开(公告)号：US20120107702A1
公开(公告)日：2012-05-03
申请号：US13319073
申请日：2010-05-07
申请人： Andrew Martin Creeth , David Ward
发明人： Andrew Martin Creeth , David Ward
IPC分类号： H01M8/06 , H01M8/04
CPC分类号： H01M8/182 , H01M8/04276 , H01M2250/00 , H01M2250/405 , Y02B90/16 , Y02E60/528
摘要： A redox fuel cell comprising a catholyte solution comprising at least one non-volatile catholyte component, the catholyte solution comprising a redox mediator couple; and a regeneration zone separate from the membrane electrode assemblies of the fuel cell, the means for supplying an oxidant to the fuel cell being adapted to supply the oxidant to the regeneration zone, the volume of catholyte solution in the regeneration zone being from about 25% to about 90% of the total combined volume of catholyte solution in the regeneration zone and the cathode chambers of the fuel cell.
摘要翻译：一种氧化还原燃料电池，包括含有至少一种非挥发性阴极电解液组分的阴极电解液，所述阴极电解液包含氧化还原介体对; 以及与燃料电池的膜电极组件分开的再生区，用于向燃料电池供应氧化剂的装置适于将氧化剂供应到再生区，再生区中的阴极电解液的体积为约25％至燃料电池再生区和阴极室中阴极电解液总组合体积的约90％。

9. 发明申请

US20110014532A1 REDOX FUEL CELLS 有权
标题翻译： REDOX燃料电池
公开(公告)号：US20110014532A1
公开(公告)日：2011-01-20
申请号：US12864496
申请日：2009-01-23
申请人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
发明人： Kathryn Knuckey , David Rochester , Andrew Martin Creeth
IPC分类号： H01M8/10 , H01M8/06
CPC分类号： H01M8/188 , H01M4/9008 , H01M2008/1095 , H01M2300/0082 , Y02E60/528
摘要： This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing in fluid communication with the cathode, the catholyte solution comprising a redox mediator which is at least partially reduced at the cathode in operation of the cell, and at least partially regenerated by, optionally indirect, reaction with the oxidant after such reduction at the cathode, and a transition metal complex of a multidentate macrocyclic N-donor ligand as a redox catalyst catalysing the regeneration of the mediator.
摘要翻译：本发明提供了一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜分离的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，所述阴极电解液包含氧化还原介体，所述氧化还原介体在所述电池的操作中在所述阴极处至少部分地还原，并且至少部分地通过与所述氧化剂的间接反应部分再生在阴极这样的还原之后，以及多齿大环N-供体配体的过渡金属络合物作为催化介体再生的氧化还原催化剂。

10. 发明授权

US09029042B2 Redox fuel cell 有权
标题翻译：氧化还原燃料电池
公开(公告)号：US09029042B2
公开(公告)日：2015-05-12
申请号：US12678687
申请日：2008-09-24
申请人： Andrew Martin Creeth , Andrew Robert Potter , Kathryn Knuckey
发明人： Andrew Martin Creeth , Andrew Robert Potter , Kathryn Knuckey
IPC分类号： H01M8/10 , H01M8/18 , H01M8/20
CPC分类号： H01M8/188 , Y02E60/528
摘要： This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing fluid communication with the cathode, the catholyte solution comprising a polyoxometallate redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the catholyte solution comprising at least one counterion for the polyoxometallate redox couple wherein the at least one counterion comprises one or more divalent ions.
摘要翻译：本发明提供了一种氧化还原燃料电池，其包括由离子选择性聚合物电解质膜分离的阳极和阴极; 用于向所述电池的阳极区域供应燃料的装置; 用于向所述电池的阴极区域供应氧化剂的装置; 用于在阳极和阴极之间提供电路的装置; 与阴极流体连通的非挥发性阴极电解液，包含多金属氧酸盐氧化还原对的阴极电解液在电解槽操作时在阴极处至少部分还原，并且在这种还原之后至少部分地与氧化剂反应产生重新产生在阴极处，阴极电解液包含至少一种用于多金属氧酸盐氧化还原对的抗衡离子，其中所述至少一种抗衡离子包含一个或多个二价离子。

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