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1. 发明授权

US4406673A Ultrathin solid membrane, process for production thereof, and use thereof for concentrating a specified gas in a gaseous mixture 失效
标题翻译：超薄固体膜，其生产方法及其用于将特定气体浓缩在气体混合物中的用途
公开(公告)号：US4406673A
公开(公告)日：1983-09-27
申请号：US217582
申请日：1980-12-18
申请人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Kiyoshi Sugie , Teizo Yamaji
发明人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Kiyoshi Sugie , Teizo Yamaji
IPC分类号： B01D53/22 , B01D69/12 , B01D71/26 , B29D7/01 , B01D39/16
CPC分类号： B01D53/22 , B01D69/122 , B01D71/26 , B29D7/01 , B01D2313/38
摘要： A process for producing ultrathin solid membranes from a solvent solution of an addition polymer derived from an ethylenically unsaturated hydrocarbon monomer or a conjugated unsaturated hydrocarbon monomer in a solvent composed mainly of a volatile, substantially water-immiscible organic liquid medium capable of dissolving the addition polymer and another organic compound having a distribution coefficient k, which is the ratio of the concentration of the other organic compound in the organic liquid medium to that in water, of from 0.5 to 35. The solvent satisfies the equationc.sub.1 -(a.sub.1 +b.sub.1).gtoreq.25wherein c.sub.1 is the surface tension (dynes/cm) of water, a.sub.1 is the surface tension (dynes/cm) of the solution of the addition polymer in the solvent, and b.sub.1 is the interfacial tension (dynes/cm) between the solvent solution and water.The solvent solution of the addition polymer is allowed to spread spontaneously on the surface of a liquid support consisting substantially of water whereby the solvent in the solvent solution is removed to an amount sufficient to form a solid membrane on the surface of the liquid support. The process may be performed batchwise or continuously. The solid membrane can be used for obtaining a gas having a specified component gas concentrated therein, for example, a gaseous mixture having enriched oxygen gas from a gaseous mixture of two or more gases for example air.
摘要翻译：一种由主要由能够溶解加成聚合物的挥发性基本上与水不混溶的有机液体介质组成的溶剂中的衍生自烯键式不饱和烃单体或共轭不饱和烃单体的加成聚合物的溶剂溶液制备超薄固体膜的方法和作为有机液体介质中的其他有机化合物的浓度与水中的其他有机化合物的比例的分配系数k的另一种有机化合物为0.5〜35。溶剂满足方程式c1-（a1 + b1）其中c1是水的表面张力（达因/厘米），a1是加成聚合物在溶剂中的溶液的表面张力（达因/厘米），b1是界面张力（达因/厘米）在溶剂溶液和水之间。允许加成聚合物的溶剂溶液自发扩散在基本上由水组成的液体载体的表面上，由此除去溶剂溶液中的溶剂至足以在液体载体的表面上形成固体膜的量。该方法可以间歇或连续进行。固体膜可用于获得其中浓缩有特定组分气体的气体，例如具有浓缩氧气的气体混合物，其来自两种或多种气体（例如空气）的气体混合物。

2. 发明授权

US3953539A Aromatic polyester resin composition having inhibited coloration and method for inhibiting coloration 失效
标题翻译：抑制着色的芳香族聚酯树脂组合物和抑制着色的方法
公开(公告)号：US3953539A
公开(公告)日：1976-04-27
申请号：US454605
申请日：1974-03-25
申请人： Shoji Kawase , Takeo Shima , Hiroo Inata , Shizuka Kurisu
发明人： Shoji Kawase , Takeo Shima , Hiroo Inata , Shizuka Kurisu
IPC分类号： C08K5/49 , C08L67/02 , C08L69/00 , C08L67/00
CPC分类号： C08K5/49 , C08L67/02 , C08L69/00
摘要： An aromatic polyester resin composition with inhibited coloration comprising (1) 100 parts by weight of an aromatic polyester resin composed mainly of tetramethylene arylcarboxylate units and polymerized by a titanium compound catalyst, (2) 5 to 100 parts by weight of a polycarbonate resin and (3) a coloration inhibiting amount of at least one phosphorus compound, and a method for inhibiting the coloring phenomenon of a resin composition comprising the polyester resin (1) and polycarbonate resin (2).
摘要翻译：一种具有抑制着色的芳香族聚酯树脂组合物，其包含：（1）100重量份主要由四亚甲基芳基羧酸酯单元组成并由钛化合物催化剂聚合的芳族聚酯树脂，（2）5至100重量份的聚碳酸酯树脂和（ 3）至少一种磷化合物的着色抑制量，以及抑制包含聚酯树脂（1）和聚碳酸酯树脂（2）的树脂组合物着色现象的方法。

3. 发明授权

US4759780A Apparatus for concentrating a gas, especially oxygen, from a gaseous mixture using an ultrathin solid membrane 失效
标题翻译：使用超薄固体膜从气体混合物中浓缩气体，特别是氧气的装置
公开(公告)号：US4759780A
公开(公告)日：1988-07-26
申请号：US498154
申请日：1983-05-25
申请人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Kiyoshi Sugie , Teizo Yamaji
发明人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Kiyoshi Sugie , Teizo Yamaji
IPC分类号： B01D53/22 , B01D69/12 , B01D71/26 , B29D7/01 , B01D13/00
CPC分类号： B01D53/22 , B01D69/122 , B01D71/26 , B29D7/01 , B01D2313/38
摘要： A module comprising a plurality of members for obtaining a gas having a specified gas concentrated therein from a mixture of at least two gases, each of said members comprising (a) a solid support plate and (b) a composite film comprised of a porous sheet-like material and one or a plurality of ultrathin solid membranes supported on the porous sheet-like material with a thickness of about 50 to about 5000 .ANG.. This module is characterized in that(1) each of said members has a first gas drawing port for drawing off the gas having a specified gas concentrated therein, and the pressure drop in a passage for the concentrated gas in the members is not more than about 2 mmHg per cm in a direction away from the first gas drawing port,(2) the module has a common feed port for feeding the mixture of at least two gases to the solid membrane surface of each members, a second drawing port connected to the first gas drawing port of each of said members, and a third common drawing port for drawing off the remaining gases formed as a result of concentration by each of the members, and(3) in each of the members, the flow of the gaseous mixture is countercurrent, or angularly displaced, to the flowing direction of the concentrated gas.An oxygen enricher having the module is useful for obtaining an oxygen-enriched gas from air.

4. 发明授权

US4124566A Process for preparing polyesters 失效
标题翻译：聚酯的制备方法
公开(公告)号：US4124566A
公开(公告)日：1978-11-07
申请号：US806879
申请日：1977-06-15
申请人： Noritsugu Saiki , Shizuka Kurisu , Shoji Kawase
发明人： Noritsugu Saiki , Shizuka Kurisu , Shoji Kawase
IPC分类号： C08G63/20 , C08G63/78 , C08G63/18 , C08G63/22 , C08G63/26 , C08G63/28
CPC分类号： C08G63/78 , C08G63/20
摘要： A process for preparing polyesters having superior thermal stability, transparency and chemical resistance, which comprises (1) a first step of esterifying (A) a difunctional carboxylic acid containing at least 60 mole% of an aromatic dicarboxylic acid, (B) 0 to 80 mole%, based on component (A), of an aliphatic diol and/or a dihydroxybenzene and (C) an aromatic monohydroxy compound in an amount of at least 210 mole% as a total of it and component (B) based on component (A), the esterification being performed until the degree of esterification reaches at least 80%, (2) subsequently, a second step of adding 0 to 80 mole%, based on component (A), of component (B) and a bisphenol (D) in an amount of 100 to 130 mole% as a total of it and component (B) based on component (A) to the reaction product obtained in the first step and reacting the mixture, the total amount of components (B) used in the first and second steps being 0 to 80 mole% based on component (C), and (3) performing at least the first of the above steps in the presence of an aromatic hydrocarbon medium having a boiling point of 105.degree. to 175.degree. C at normal atmospheric pressure and being inert at the reaction temperature.
摘要翻译：一种制备具有优异的热稳定性，透明性和耐化学性的聚酯的方法，其包括（1）第一步（A）含有至少60摩尔％的芳族二羧酸的二官能羧酸，（B）0至80 摩尔％，基于组分（A），脂族二醇和/或二羟基苯和（C）芳族单羟基化合物，其总量为至少210摩尔％，组分（B）为基于组分（ A），进行酯化直到酯化度达到至少80％，（2）随后，添加基于组分（A）0至80摩尔％的组分（B）和双酚（ D），其总量为100〜130摩尔％，（B）成分与第一工序中得到的反应产物的组分（B）反应，使混合物的组分（B）的使用量在第一和第二步骤中，基于组分（C）为0至80摩尔％，和（3）至少执行t 他在上述步骤中首先在正常大气压下在沸点为105〜175℃的芳烃介质存在下，在反应温度下为惰性。

5. 发明授权

US4449992A Heat-and-moisture exchanger 失效
标题翻译：热湿交换器
公开(公告)号：US4449992A
公开(公告)日：1984-05-22
申请号：US222548
申请日：1981-01-05
申请人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Shoji Kawase , Makoto Sano
发明人： Takeyoshi Yamada , Shizuka Kurisu , Shizuo Azuma , Shoji Kawase , Makoto Sano
IPC分类号： F28F21/06 , F24F3/147 , F28D21/00 , F28F21/00 , B01D53/22
CPC分类号： F28D21/0015 , F24F3/147
摘要： A heat-and-moisture exchanger including a thin film-like porous material as a partitioning element for heat and moisture exchanges between two gases, said porous material containing numerous pores having an average diameter of not more than 5 microns and opened to both surfaces thereof, and having a thickness of not more than 500 microns, a specific surface area of at least 0.3 m.sup.2 /g, and a gas permeability having a value of at least 50 seconds/100 cc. This heat-and-moisture exchanger is used in a ventilating device and an air-conditioner.
摘要翻译：一种热湿交换器，其包括作为用于两种气体之间的热和水分交换的分隔元件的薄膜状多孔材料，所述多孔材料包含平均直径不大于5微米且在其两个表面上开口的多个孔，并且具有不大于500微米的厚度，至少0.3m 2 / g的比表面积和至少50秒/ 100cc的气体渗透性。这种热湿交换器用于通风设备和空调。

6. 发明授权

US4081494A Process for preparing soft transparent polyether polyester block copolymers 失效
标题翻译：软透明聚醚聚酯嵌段共聚物的制备方法
公开(公告)号：US4081494A
公开(公告)日：1978-03-28
申请号：US641038
申请日：1975-12-15
申请人： Hiroshi Sakai , Yoshihiko Takeuchi , Shizuka Kurisu
发明人： Hiroshi Sakai , Yoshihiko Takeuchi , Shizuka Kurisu
IPC分类号： C08G63/672 , C08L67/02
CPC分类号： C08G63/672
摘要： In a process for preparing soft polyesters which comprises reacting (A) terephthalic acid and/or its ester-forming derivative, (B) tetramethylene glycol and/or its ester-forming derivative and (C) a poly(oxyalkylene) glycol having a molecular weight of 500 to 5,000 and a ratio of the number of carbon atoms to that of oxygen atoms of 2 to 4.5, the improvement wherein after the reduced viscosity of the reaction product of the components (A), (B) and (C) has reached 0.1 (dl/g), the reaction product is further reacted with (D) a low-molecular-weight ester compound and/or a high-molecular-weight ester compound containing a terephthalic acid residue and an ethylene glycol residue or a low-molecular-weight ester compound and/or a high-molecular-weight ester compound containing a terephthalic acid residue and a 1,4-cyclohexane dimethanol residue to form a polyester-polyether block copolymer.
摘要翻译：在制备软质聚酯的方法中，其包括使（A）对苯二甲酸和/或其形成酯的衍生物与（B）四亚甲基二醇和/或其成酯衍生物和（C）具有分子量的聚（氧化烯）（A），（B）和（C）的反应产物的比浓粘度在具有（A），（B）和（C）的反应产物的比浓粘度达到0.1（dl / g），反应产物进一步与（D）低分子量酯化合物和/或含有对苯二甲酸残基和乙二醇残基的高分子量酯化合物或低 - 分子量酯化合物和/或含有对苯二甲酸残基和1,4-环己烷二甲醇残余物的高分子量酯化合物以形成聚酯 - 聚醚嵌段共聚物。

7. 发明授权

US4244859A Aromatic polyester composition 失效
标题翻译：芳香聚酯组合物
公开(公告)号：US4244859A
公开(公告)日：1981-01-13
申请号：US959636
申请日：1978-11-13
申请人： Kiyoshi Sugie , Shizuka Kurisu , Shingo Emi , Shizuo Azuma , Toshiaki Harada , Shoji Kawase
发明人： Kiyoshi Sugie , Shizuka Kurisu , Shingo Emi , Shizuo Azuma , Toshiaki Harada , Shoji Kawase
IPC分类号： C08G63/18 , C08K3/34 , C08L67/02 , C08K7/00
CPC分类号： C08K3/34 , C08G63/18 , C08L67/02
摘要： A novel composition comprising 100 parts by weight of an aromatic polyester, 5 to 150 parts by weight of powdery feldspar and optionally 5 to 120 parts by weight of a plate-like inorganic filler such as glass flakes and/or 1 to 100 parts by weight of a rubbery elastomer such as acrylic rubber. Up to a half of the powdery feldspar may be replaced by another pulverulent inorganic filler such as talc. The composition is useful as engineering plastics because it gives molded articles having high impact strength and heat distortion temperatures and reduced warping.
摘要翻译：一种新型组合物，其包含100重量份的芳族聚酯，5至150重量份的粉末状长石和任选的5至120重量份的片状无机填料如玻璃片和/或1至100重量份的橡胶弹性体如丙烯酸橡胶。高达一半的粉状长石可以被另一种粉状无机填料如滑石代替。该组合物可用作工程塑料，因为它赋予具有高冲击强度和热变形温度以及减少翘曲的模制品。

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