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    • 1. 发明申请
    • Ultraviolet-Curable Resin Composition For Optical Disc And Cured Product Thereof
    • 用于光盘及其固化产品的紫外线固化树脂组合物
    • US20120282427A1
    • 2012-11-08
    • US13511814
    • 2010-11-29
    • Hiroki TsutsumiDaisuke KobayashiMasahiro NaitouYuichiro MatsuoJun KidobaHayato Motohashi
    • Hiroki TsutsumiDaisuke KobayashiMasahiro NaitouYuichiro MatsuoJun KidobaHayato Motohashi
    • B32B3/02C08G18/75B29C35/08
    • G11B7/2533C08F290/067C08G18/672C08G18/755G11B7/24038G11B7/256G11B7/263
    • The present invention relates to a multilayer optical disc having, as an intermediate layer, a cured product layer of an ultraviolet-curable resin composition containing an urethane (meth)acrylate (A) having one or two (meth)acrylate groups in one molecule obtained by reacting a monofunctional or bifunctional organic isocyanate (a) having a molecular weight of 350 or less with a mono(meth)acrylate (b) having a hydroxy group, a (meth)acrylate monomer (B) and a photopolymerization initiator (C), where the content of the (A) component is 5 to less than 40% by weight based on the total amount of the (A) component and the (B) component and the rest is (B), and to a resin composition for said cured product layer. Said resin composition has characteristics that it has a smaller variation in warp before and after curing the above-described resin composition when it is formed into the above-described intermediate layer, it is suitable for shaping a substrate by a 2P method because it allows good detachability of a stamper after curing, it is excellent in mass production of multilayer optical discs, and that the obtained optical disc therefrom has a smaller variation in warp before and after durability test under high temperature and high humidity.
    • 本发明涉及一种具有一分子中含有一个或两个(甲基)丙烯酸酯基团的氨基甲酸酯(甲基)丙烯酸酯(A))的紫外线固化树脂组合物的固化产物层作为中间层的多层光盘, 通过使分子量为350以下的单官能或双官能的有机异氰酸酯(a)与具有羟基的单(甲基)丙烯酸酯(b),(甲基)丙烯酸酯单体(B)和光聚合引发剂(C) ,其中(A)成分的含量相对于(A)成分和(B)成分的总量为5〜小于40重量%,其余为(B)),以及(A)成分的树脂组合物 所述固化产物层。 所述树脂组合物具有如下特征:当上述树脂组合物形成上述中间层时,其固化之前和之后的翘曲变化较小,因此适用于通过2P法成型基板,因为它允许良好 固化后的压模的可拆卸性,多层光盘的批量生产是优异的,并且所获得的光盘在高温高湿下耐久性试验前后的翘曲变化较小。