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1. 发明授权

US4116923A Dyed polyesters, process for their preparation and their use for the dyeing of plastics 失效
标题翻译：染色聚酯，其制备方法及其在塑料染色中的应用
公开(公告)号：US4116923A
公开(公告)日：1978-09-26
申请号：US782163
申请日：1977-03-28
申请人： Hans Gattner , Ernst Spietschka , Helmut Troster
发明人： Hans Gattner , Ernst Spietschka , Helmut Troster
IPC分类号： C08G63/00 , C08G63/12 , C08G63/68 , C08G63/685 , C08G63/78 , C08L67/00
CPC分类号： C08G63/12 , C08G63/68
摘要： When reacting a dyestuff having hydroxy, acyloxy, carboxy or carbalkoxy groups with a polyester derived from terephthalic and/or isophthalic acid and, per mol of dicarboxylic acid, about 0.75 to 1.5 mol of a low-molecular alkanetriol with primary alcohol groups (methylol groups) or, instead of said polyester, with the corresponding starting materials or precondensates, a polyester with chemically linked dyestuff units is obtained which is useful for dyeing plastics, especially polyolefins. The dyed plastic materials are heat resistant, even when containing fluorescent dyestuff units, transparent and uniformly dyed.
摘要翻译：当使具有羟基，酰氧基，羧基或烷氧基的染料与衍生自对苯二甲酸和/或间苯二甲酸的聚酯和每摩尔二羧酸反应约0.75至1.5摩尔具有伯醇基团的低分子量烷三醇（羟甲基）或代替所述聚酯与相应的原料或预缩合物，得到具有化学连接的染料单元的聚酯，其可用于染色塑料，特别是聚烯烃。染色塑料材料耐热，即使含有荧光染料单元，透明均匀染色。

2. 发明授权

US5319083A Black peryene-3,4,9,10-tetracarboxylic diimides, their preparation and use 失效
标题翻译：黑色苝-3,4,9,10-四羧酸二酰亚胺，其制备和用途
公开(公告)号：US5319083A
公开(公告)日：1994-06-07
申请号：US996844
申请日：1992-12-16
申请人： Helmut Troster
发明人： Helmut Troster
IPC分类号： C07D221/18 , C07D471/06 , C07D491/06 , C08K5/3437 , C09B5/62 , C09B67/20 , C09B67/46 , C09D7/00 , C09D11/037
CPC分类号： C07D471/06 , C08K5/3437 , C09B5/62 , C09D11/037 , C09D7/007
摘要： The invention relates to perylene-3,4,9,10-tetracarboxylic diimides of the formula (I) ##STR1## in which R is a 3'- and/or 4'-methoxybenzyl radical, and their preparation and use as black pigments, inter alia in paint preparations, printing inks or for the dyeing of polymers.
摘要翻译：本发明涉及式（I）的苝-3,4,9,10-四羧酸二酰亚胺其中R是3'-和/或4'-甲氧基苄基，其制备和用途作为黑色颜料，特别是在油漆制剂，印刷油墨中或用于聚合物的染色。

3. 发明授权

US4599408A Perylene-3,4,9,10-tetracarboxylic acid monoanhydride monoimides 失效
标题翻译：苝-3,4,9,10-四羧酸单酐单酰亚胺
公开(公告)号：US4599408A
公开(公告)日：1986-07-08
申请号：US599202
申请日：1984-04-11
申请人： Ernst Spietschka , Helmut Troster
发明人： Ernst Spietschka , Helmut Troster
IPC分类号： C07D491/06 , C09B5/62
CPC分类号： C07D491/06 , C09B5/62
摘要： Compounds of the formula ##STR1## in which R denotes hydrogen, hydroxyl, amino or optionally substituted alkyl, X denotes chlorine or bromine and n is a number from zero to 4, are obtained from the corresponding mono-alkali metal salts of perylene-3,4,9,10-tetracarboxylic acid monoanhydrides by reaction with compounds of the formula R--NH.sub.2, in which R has the above meaning, at 0.degree.-130.degree. C. The compounds are colorants or starting materials for colorants.
摘要翻译：其中R表示氢，羟基，氨基或任选取代的烷基，X表示氯或溴，n表示0至4的数，由相应的苝-3的单碱金属盐获得，4,9,10-四羧酸单酸酐，通过与其中R具有上述含义的式R-NH 2化合物在0℃-130℃反应。化合物是着色剂或着色剂的起始材料。

4. 发明授权

US4097450A Perinone compounds as colorants for polyolefins 失效
标题翻译：围烷化合物作为聚烯烃的着色剂
公开(公告)号：US4097450A
公开(公告)日：1978-06-27
申请号：US800895
申请日：1977-05-26
申请人： Theodor Papenfuhs , Helmut Troster
发明人： Theodor Papenfuhs , Helmut Troster
IPC分类号： C08K5/3442 , C09B57/12 , C08K5/34
CPC分类号： C09B57/12 , C08K5/3442
摘要： Perinones of the formula ##STR1## IN WHICH A represents an ortho- or peri-arylene radical or a heterocyclic radical, and n represents the number 1 or 2 and m = 1 if n = 1 and m = 0 if n = 2, are obtained by reacting a 3,6-dihydroxynaphthalic anhydride with an aromatic or heterocyclic ortho- or peri-diamine or tetramine or the salts thereof. The products are valuable pigments.
摘要翻译：其中A表示邻位或亚芳基或杂环基的式子化合物，n表示数1或2，如果n = 1，则n表示m = 1，如果n = 2，则表示m = 0 通过使3,6-二羟基萘二甲酸酐与芳族或杂环的邻 - 或二 - 二胺或四胺或其盐反应而获得。该产品是有价值的颜料。

5. 发明授权

US4769460A Mix-crystal pigments based on perylenetetracarbimides, process for preparing and their use 失效
标题翻译：基于苝四氮嘧啶的混合晶体颜料，其制备方法及其应用
公开(公告)号：US4769460A
公开(公告)日：1988-09-06
申请号：US144779
申请日：1988-01-20
申请人： Ernst Spietschka , Helmut Troster
发明人： Ernst Spietschka , Helmut Troster
IPC分类号： C09B5/62 , C09B67/22 , C09B67/26 , C09B57/00
CPC分类号： C09B67/0034 , C09B5/62
摘要： Process for preparing perylenetetracarbimide mix-crystal pigments in the crystal lattice of the .alpha.-modification of the N,N'-bis-3',5'-dimethylphenylperylenetetracarbimide of the formula (1) comprising essentially symmetrical N,N'-bis-3',5'-dimethylphenylperylenetetracarbimide of the formula (1) and at least one asymmetrically substituted diimide of the formula (2) in which R stands for methyl or ethyl ##STR1## by condensing 1 mole of perylenetetracarboxylic dianhydride with an excess of up to 30 moles of 3,5-dimethylaniline which contains in total 0.5-6 percent by weight of 4-ethoxyaniline, and their use for coloring organic polymers.
摘要翻译：在式（1）的N，N'-二-3'，5'-二甲基苯基四烯基四亚甲基酰亚胺的α-改性的晶格中制备苝四亚甲基亚胺混合晶体颜料的方法，其包含基本上对称的N，N'-二-3 （2）的至少一种不对称取代的二酰亚胺，其中R代表甲基或乙基，其中R代表甲基或乙基。（2）通过将1摩尔苝四羧酸二酐与过量的高达30摩尔的3,5-二甲基苯胺，其含有总共0.5-6重量％的4-乙氧基苯胺，以及它们用于着色有机聚合物的用途。

6. 发明授权

US4709029A Process for the preparation of perylene-3,4,9,10-tetracarboxylic acid monoanhydride monoimides 失效
标题翻译：制备苝-3,4,9,10-四羧酸单酐的方法
公开(公告)号：US4709029A
公开(公告)日：1987-11-24
申请号：US821618
申请日：1986-01-23
申请人： Ernst Spietschka , Helmut Troster
发明人： Ernst Spietschka , Helmut Troster
IPC分类号： C07D491/06 , C09B5/62 , C07D413/06
CPC分类号： C07D491/06 , C09B5/62
摘要： Compounds of the formula ##STR1## in which R denotes hydrogen, hydroxyl, amino or optionally substituted alkyl, X denotes chlorine or bromine and n is a number from zero to 4, are obtained from the corresponding mono-alkali metal salts of perylene-3,4,9,10-tetracarboxylic acid monoanhydrides by reaction with compounds of the formula R-NH.sub.2, in which R has the above meaning, at 0.degree.-130.degree. C. The compounds are colorants or starting materials for colorants.
摘要翻译：其中R表示氢，羟基，氨基或任选取代的烷基，X表示氯或溴，n表示0至4的数，由相应的苝-3的单碱金属盐获得，4,9,10-四羧酸单酸酐，通过与其中R具有上述含义的式R-NH 2化合物在0℃-130℃反应。化合物是着色剂或着色剂的起始材料。

7. 发明授权

US4242139A Water soluble benzoxanthene dyestuffs for fluorescent inks 失效
标题翻译：用于荧光油墨的水溶性苯并呫吨染料
公开(公告)号：US4242139A
公开(公告)日：1980-12-30
申请号：US8484
申请日：1979-02-01
申请人： Helmut Troster
发明人： Helmut Troster
IPC分类号： C09B57/14 , C09D5/22 , C09D11/50 , C09D11/00
CPC分类号： C09D11/50 , C09B57/14 , C09D5/22 , Y10S260/38
摘要： Water-soluble dyestuffs of the formula ##STR1## in which Y is oxygen or an imino group, R.sup.1 and R.sup.2 are hydrogen, halogen or lower alkyl or lower alkoxy, n is 1 to 3 and Z is a cation, are useful for fluorescent inks.
摘要翻译：其中Y是氧或亚氨基的式“IMAGE”的水溶性染料，R 1和R 2是氢，卤素或低级烷基或低级烷氧基，n是1至3，Z是阳离子，可用于荧光油墨。

8. 发明授权

US4002630A Novel aromatic o-hydroxyaldehydes, a process for their preparation and their utilization 失效
标题翻译：新型芳香族羟基醛类，其制备方法及其应用
公开(公告)号：US4002630A
公开(公告)日：1977-01-11
申请号：US598070
申请日：1975-07-22
申请人： Theodor Papenfuhs , Helmut Troster
发明人： Theodor Papenfuhs , Helmut Troster
IPC分类号： C07C51/00 , C07C65/30 , C07C67/00 , C07D221/14 , C07D471/06 , C07D471/14 , C07D217/24
CPC分类号： C07D221/14 , C07C65/30 , C07D471/06 , C07D471/14
摘要： Novel aromatic o-hydro-aldehydes of the formula ##STR1## have been found wherein each X is a carboxy group or both X together are a group of the formula ##STR2## wherein R stands for hydrogen, an optionally substituted amino group, optionally etherified hydroxy group, an optionally substituted aliphatic, cycloaliphatic, aromatic or heterocyclic radical, and A for an optionally substituted phenylene or naphthylene radical. They are valuable intermediate products for the preparation of dyestuffs, optical brighteners, textile auxiliaries and pharmaceutica and are particularly suitable for the preparation of azo-methine dyestuffs which are obtained by condensation of these aldehydes with suitable amines.
摘要翻译：已经发现了新的式（I）的芳族邻羟基醛，其中每个X是一个羧基，或两个X一起是下式的基团：其中R代表氢，任选取代的氨基，任选醚化的羟基，任选取代的脂族，脂环族，芳族或杂环基，A代表任选取代的亚苯基或亚萘基。它们是用于制备染料，荧光增白剂，纺织助剂和药物的有价值的中间产物，并且特别适用于通过将这些醛与合适的胺缩合而获得的偶氮次甲基染料的制备。

9. 发明授权

US3939093A Daylight fluorescent pigments 失效
标题翻译：日光荧光颜料
公开(公告)号：US3939093A
公开(公告)日：1976-02-17
申请号：US530299
申请日：1974-12-06
申请人： Theodor Papenfuhs , Ernst Spietschka , Helmut Troster
发明人： Theodor Papenfuhs , Ernst Spietschka , Helmut Troster
IPC分类号： C09K11/06 , C08K5/00 , C08K5/20 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C09B57/08 , C09B67/00 , C09B67/20 , C09D11/00
CPC分类号： C09B57/08 , C09B67/00 , C09B67/0061
摘要： A daylight fluorescent pigment based on condensation resins which contain a compound of the formula ##SPC1##In which R.sub.1 is hydroxyalkyl of 1-8 carbon atoms or unsubstituted or substituted phenyl, carboxylic acid amide, cyano, nitro, sulfonic acid amide, alkylsulfone of 1-6 carbon atoms, acetylamino or unsubstituted or substituted benzoylamino or the triazolyl or benzimidazolyl radical, R.sub.2 is a straight-drained or branched alkylene radical of 1-8 carbon atoms which may contain as a bridging member between two alkylene moieties the phenylene or cyclohexylene radical or an oxygen or cycloalkylene and zis 1, 2 or 3. Compared with known pigment dyestuffs of the naphthalic acid imide series they have the advantage that they can be prepared with a dyestuff which is technically obtainable in an easy way. The daylight fluorescent pigments of this invention have a very good fastness to bleeding, a very high tinctorial strength, an improved fluorescence intensity and a very good brilliance. They are advantageously suited for the dyeing of lacquers and varnishes, printing pastes, inks, and plastic materials.
摘要翻译：一种基于缩合树脂的日光荧光颜料，其含有下式的化合物：其中R 1为1-8个碳原子的羟基烷基或未取代或取代的苯基，羧酸酰胺，氰基，硝基，磺酰胺，1-6碳烷基砜原子，乙酰氨基或未取代或取代的苯甲酰氨基或三唑基或苯并咪唑基，R2是1-8个碳原子的直链或支链亚烷基，其可以包含作为亚烷基部分之间的桥连构件，亚苯基或亚环己基或氧或亚环烷基和Zis 1,2或3.与已知的萘二甲酰亚胺系染料相比，它们具有可以用技术上可以容易地获得的染料来制备的优点。本发明的日光荧光颜料具有非常好的出血牢度，极高的着色强度，改善的荧光强度和非常好的亮度。它们有利于染色漆和清漆，印刷浆料，油墨和塑料材料。

10. 发明授权

US5154770A Mix-crystal pigments based on perylenetetracarbimides, process for their preparation and their use 失效
标题翻译：基于苝四酰嘧啶的混合晶体颜料，其制备方法及其用途
公开(公告)号：US5154770A
公开(公告)日：1992-10-13
申请号：US587158
申请日：1990-09-19
申请人： Ernst Spietschka , Helmut Troster
发明人： Ernst Spietschka , Helmut Troster
IPC分类号： C09B5/62 , C09B67/22 , C09B67/26
CPC分类号： C09B5/62 , C09B67/0034
摘要： Perylenetetracarbimide mix-crystal pigments in the crystal lattice of the .alpha.-modification of N,N'-bis-3',5'-dimethylphenylperylenetetracarbimide of the formula (1) comprising 99-70 mole percent of the symmetrical diimide of the formula (1) and correspondingly 1-30 mole percent of the asymmetrically substituted diimide of the formula (2) ##STR1## process for their preparation and their use for coloring organic polymers.
摘要翻译：式（1）的N，N'-二-3'，5'-二甲基苯基四环戊四酰亚胺的α-修饰的晶格中的苝四亚甲基亚胺混合晶体颜料包含99-70摩尔的式（1）的对称二酰亚胺）和相应地1-30摩尔％的式（2）的不对称取代的二酰亚胺其制备方法及其用于着色有机聚合物的方法。

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