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1. 发明申请

US20130168292A1 PROCESS FOR THE HYDRODESULPHURIZATION OF A GASOLINE CUT IN THE PRESENCE OF A SUPPORTED SULPHIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE 有权
标题翻译：使用最少一个循环低聚糖制备的支持的硫化物催化剂存在下汽油切割的加氢过程
公开(公告)号：US20130168292A1
公开(公告)日：2013-07-04
申请号：US13812711
申请日：2011-06-24
申请人： Fabrice Diehl , Elodie Devers
发明人： Fabrice Diehl , Elodie Devers
IPC分类号： C10G45/08 , C10G45/10
CPC分类号： C10G45/08 , B01J23/85 , B01J23/882 , B01J27/1853 , B01J27/1856 , B01J27/188 , B01J27/19 , B01J31/0201 , B01J31/2208 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J37/0203 , B01J37/0205 , B01J37/20 , C07C1/321 , C10G45/10 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018
摘要： Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: i) contacting support with precursors of group VIII and group VIB metals; ii) contacting support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) drying to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then iv) sulphurization such that said active phase is in the sulphide form; i) and ii) being carried out separately, in any order, or simultaneously.
摘要翻译：通过使汽油馏分与至少一种具有至少一种来自第VIII族的金属的活性相的催化剂接触，将每个分子含有至少2个碳原子的烃并且终点为250℃或更低的汽油馏分加氢脱硫和至少一种来自组VIB的金属沉积在载体上，所述催化剂使用以下方法制备：i）使载体与第VIII族和第VIB族金属的前体接触; ii）使支持物与至少一种由至少一种由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状寡糖形成的有机化合物接触; iii）干燥以从氧化物形式获得至少来自第VIII族的金属和至少所述VIB族金属; 然后iv）硫化使得所述活性相为硫化物形式; i）和ii）以任何顺序或同时单独进行。

2. 发明授权

US09321041B2 Process for hydrotreating a hydrocarbon cut with a boiling point of more than 250° C. in the presence of a sulphide catalyst prepared using a cyclic oligosaccharide 有权
标题翻译：在使用环状低聚糖制备的硫化物催化剂存在下，加氢处理沸点高于250℃的烃馏分
公开(公告)号：US09321041B2
公开(公告)日：2016-04-26
申请号：US13813016
申请日：2011-06-24
申请人： Fabrice Diehl , Elodie Devers , Karin Marchand , Bertrand Guichard
发明人： Fabrice Diehl , Elodie Devers , Karin Marchand , Bertrand Guichard
IPC分类号： B01J23/76 , C10G45/08 , B01J27/19 , B01J23/652 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J35/00 , B01J37/08 , B01J37/20 , B01J38/14 , C10G45/10 , B01J23/54 , B01J27/186 , B01J21/04 , B01J37/00 , B01J37/02
CPC分类号： B01J27/19 , B01J21/04 , B01J23/652 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/20 , B01J38/14 , C10G45/08 , C10G45/10 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/04
摘要： Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 α-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.
摘要翻译：制备具有至少一种来自第VIII族的金属的催化剂，至少一种来自VIB族的金属和至少一种载体; i）i）使预催化剂与VIII族金属，VIB族的金属接触，并用至少6个α-（1,4）键的吡喃葡萄糖亚基的环状低聚糖进行支持; i2）使支持物与含有VIII族金属的前体的溶液接触，所述VIB族的所述金属的前体和由至少6个α-（1,4）键的吡喃葡萄糖亚基组成的环状低聚糖; 或i3）使支持物与由至少6个α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖接触，然后将从其衍生的固体与来自VIII族的金属前体和来自VIB族的金属前体接触。

3. 发明授权

US08940157B2 Process for the hydrodesulphurization of a gasoline cut in the presence of a supported sulphide catalyst prepared using at least one cyclic oligosaccharide 有权
标题翻译：在使用至少一种环状低聚糖制备的负载型硫化物催化剂的存在下，对汽油加氢脱硫的方法
公开(公告)号：US08940157B2
公开(公告)日：2015-01-27
申请号：US13812711
申请日：2011-06-24
申请人： Fabrice Diehl , Elodie Devers
发明人： Fabrice Diehl , Elodie Devers
IPC分类号： C10G47/02 , C10G45/08 , B01J23/85 , B01J27/185 , B01J27/19 , B01J31/02 , B01J31/22 , B01J37/02 , C07C1/32 , C10G45/10
CPC分类号： C10G45/08 , B01J23/85 , B01J23/882 , B01J27/1853 , B01J27/1856 , B01J27/188 , B01J27/19 , B01J31/0201 , B01J31/2208 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J37/0203 , B01J37/0205 , B01J37/20 , C07C1/321 , C10G45/10 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018
摘要： Hydrodesulphurization of a gasoline cut containing hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting the gasoline cut with at least one catalyst having an active phase of at least one metal from group VIII and at least one metal from group VIB deposited on a support, said catalyst being prepared using a process of: i) contacting support with precursors of group VIII and group VIB metals; ii) contacting support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6α-(1,4)-bonded glucopyranose subunits; iii) drying to obtain at least said metal from group VIII and at least said metal from group VIB in the oxide form; then iv) sulphurization such that said active phase is in the sulphide form; i) and ii) being carried out separately, in any order, or simultaneously.
摘要翻译：通过使汽油馏分与至少一种具有至少一种来自第VIII族的金属的活性相的催化剂接触，将每个分子含有至少2个碳原子的烃并且终点为250℃或更低的汽油馏分加氢脱硫和至少一种来自组VIB的金属沉积在载体上，所述催化剂使用以下方法制备：i）使载体与第VIII族和第VIB族金属的前体接触; ii）使支持物与至少一种由至少一种由至少6α-（1,4） - 键合的吡喃葡萄糖亚基组成的环状寡糖形成的有机化合物接触; iii）干燥以从氧化物形式获得至少来自第VIII族的金属和至少所述VIB族金属; 然后iv）硫化使得所述活性相为硫化物形式; i）和ii）以任何顺序或同时单独进行。

4. 发明申请

US20140005031A1 SPHERICAL MATERIAL BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND USE THEREOF AS CATALYST IN HYDROCARBON REFINING PROCESSES 审中-公开
标题翻译：基于在结构化氧化物基质中捕获的异黄酮的球形材料及其作为烃类精炼工艺中的催化剂的用途
公开(公告)号：US20140005031A1
公开(公告)日：2014-01-02
申请号：US13995508
申请日：2011-12-15
申请人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
发明人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
IPC分类号： B01J27/199 , B01J27/19 , B01J27/188 , B01J23/882
CPC分类号： B01J27/199 , B01J23/882 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/00 , C01B37/005 , C01B37/02 , C01B39/04 , C01B39/06 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G45/06 , C10G47/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10L1/04 , C10L1/06 , C10L1/08 , Y02P30/10 , Y02P30/20
摘要： Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q−, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.
摘要翻译：具有至少两个基本球形颗粒的无机材料，每个所述球形金属颗粒：具有式（XxMmOyHh）q-的多金属氧酸盐，其中H是氢，O是氧，X是磷，硅，硼，镍或钴，M是一种或多种钒，铌，钽，钼，钨，铁，铜，锌，钴和镍，x为0,1,2或4，m为5,6,7,8,9,10,11,12 或18，y为17〜72，h为0〜12，q为1〜20。

5. 发明申请

US20130211163A1 PROCESS FOR SELECTIVELY HYDROGENATING A GASOLINE CUT IN THE PRESENCE OF A SUPPORTED SULPHIDE CATALYST PREPARED USING AT LEAST ONE CYCLIC OLIGOSACCHARIDE 有权
标题翻译：在使用至少一个循环低聚糖制备的支持的硫化物催化剂存在下，选择性地加氢汽油切割的方法
公开(公告)号：US20130211163A1
公开(公告)日：2013-08-15
申请号：US13813021
申请日：2011-06-24
申请人： Fabrice Diehl , Elodie Devers
发明人： Fabrice Diehl , Elodie Devers
IPC分类号： C07C5/05
CPC分类号： C07C5/05 , B01J23/652 , B01J23/85 , B01J23/881 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0201 , B01J37/0203 , B01J37/20 , C10G45/38 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018
摘要： Selective hydrogenation of a gasoline cut containing polyunsaturated hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by bringing said gasoline cut into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII and at least one metal from group VIB deposited on a support.
摘要翻译：通过使所述汽油切割与至少一种催化剂相接触，含有每分子含有至少2个碳原子并具有250℃或更低终点的多不饱和烃的汽油馏分的选择性氢化，所述催化剂的活性相至少包含来自VIII族的一种金属和至少一种沉积在载体上的VIB族金属。

6. 发明授权

US09376636B2 Process for hydrodesulphuration of gasoline cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support 有权
标题翻译：使用基于捕获在介孔二氧化硅载体中的杂多阴离子的催化剂对汽油馏分进行加氢脱硫的方法
公开(公告)号：US09376636B2
公开(公告)日：2016-06-28
申请号：US13995800
申请日：2011-12-15
申请人： Karin Marchand , Elodie Devers , Alexandra Chaumonnot , Audrey Bonduelle , Veronique Dufaud , Frederic Lefebvre , Manuela Bader , Susana Lopes Silva
发明人： Karin Marchand , Elodie Devers , Alexandra Chaumonnot , Audrey Bonduelle , Veronique Dufaud , Frederic Lefebvre , Manuela Bader , Susana Lopes Silva
IPC分类号： C10G45/04 , B01J27/186 , B01J27/188 , B01J27/19 , C10G45/10 , B01J29/03 , B01J35/00 , B01J35/10 , B01J37/03 , B01J37/10 , B01J37/20 , C10G45/06 , B01J27/195 , B01J27/198
CPC分类号： C10G45/10 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/033 , B01J37/10 , B01J37/20 , B01J2229/20 , C10G45/04 , C10G45/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/4018 , C10G2400/02
摘要： A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.
摘要翻译：至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

7. 发明授权

US07981828B2 Process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of a catalyst comprising at least one support, one group VIII and one group VIB element 有权
标题翻译：在含有至少一种载体，一组VIII和一组VIB元素的催化剂存在下加氢脱硫含硫和烯烃的汽油馏分的方法
公开(公告)号：US07981828B2
公开(公告)日：2011-07-19
申请号：US11878929
申请日：2007-07-27
申请人： Elodie Devers , Christophe Bouchy , Nathalie Marchal-George , Florent Picard
发明人： Elodie Devers , Christophe Bouchy , Nathalie Marchal-George , Florent Picard
IPC分类号： B01J27/188 , B01J27/18 , C10G45/08
CPC分类号： B01J27/19 , B01J23/882 , B01J35/1014 , B01J35/1047 , B01J37/0201 , C10G45/08 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： The invention is about a catalyst comprising at least one support, at least one group VIII element, at least one group VIB element and phosphorus, in which the density of group VIB elements per unit surface area of the support is in the range (limits included) 2×10−4 to 18×10−4 of oxides of group VIB elements per m2 of support, in which the molar ratio of phosphorus to the group VIB element is in the range 0.27 to 2.00, and in which the amount of group VIB elements is in the range (limits included) 1% to 20% by weight of oxides of group VIB elements and in which the support has a specific surface area of less than 135 m2/g. The invention is also about a process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of this catalyst.
摘要翻译：本发明涉及包含至少一种载体，至少一种VIII族元素，至少一种VIB族元素和磷的催化剂，其中载体的每单位表面积的VIB族元素的密度在所述范围内）2×10 -4〜18×10 -4的VIB族元素/ m2载体的氧化物，其中磷与VIB族元素的摩尔比在0.27〜2.00的范围内，其中基团的量 VIB元素在范围（包括的范围内）1〜20重量％的VIB族元素的氧化物，其中载体的比表面积小于135m 2 / g。本发明还涉及一种在该催化剂存在下加氢脱硫含硫和烯烃的汽油馏分的方法。

8. 发明申请

US20090139901A1 TWO-STEP PROCESS FOR DESULPHURIZING OLEFINIC GASOLINES COMPRISING ARSENIC 有权
标题翻译：用于将包含ARSENIC的含油气体脱硫的两步法
公开(公告)号：US20090139901A1
公开(公告)日：2009-06-04
申请号：US12270194
申请日：2008-11-13
申请人： Florent Picard , Vincent Coupard , Elodie Devers
发明人： Florent Picard , Vincent Coupard , Elodie Devers
IPC分类号： C10G45/00
CPC分类号： C10G45/08 , B01J23/85 , C10G65/04
摘要： The invention concerns a fixed bed process for capturing arsenic and for desulphurizing a hydrocarbon fraction comprising olefins, sulphur and arsenic, said process comprising a step a) for bringing a capture mass into contact with said hydrocarbon fraction in the presence of hydrogen, the ratio between the flow rate of hydrogen and the flow rate of the hydrocarbon fraction being in the range 50 to 800 Nm3/m3, the operating temperature being in the range 200° C. to 400° C., the operating pressure being in the range 0.2 to 5 MPa. The capture mass comprises molybdenum in a sulphurized form, nickel in a sulphurized form and at least one porous support selected from the group constituted by aluminas, silica, silica-aluminas, titanium oxide and magnesium oxide. The nickel content is in the range 10% to 28% by weight and the molybdenum content is in the range 0.3% to 2.1% by weight.
摘要翻译：本发明涉及用于捕获砷和用于脱硫包含烯烃，硫和砷的烃馏分的固定床方法，所述方法包括步骤a）使捕获物质在氢气存在下与所述烃馏分接触，氢气的流量和烃馏分的流量在50至800Nm 3 / m 3的范围内，操作温度在200℃至400℃的范围内，操作压力在0.2至 5MPa。捕获质量包括硫化形式的钼，硫化形式的镍和至少一种选自氧化铝，二氧化硅，二氧化硅 - 氧化铝，氧化钛和氧化镁的多孔载体。镍含量为10〜28重量％，钼含量为0.3〜2.1重量％。

9. 发明申请

US20080053872A1 Process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of a catalyst comprising at least one support, one group VIII and one group VIB element 有权
标题翻译：在含有至少一种载体，一组VIII和一组VIB元素的催化剂存在下加氢脱硫含硫和烯烃的汽油馏分的方法
公开(公告)号：US20080053872A1
公开(公告)日：2008-03-06
申请号：US11878929
申请日：2007-07-27
申请人： Elodie Devers , Christophe Bouchy , Nathalie Marchal-George , Florent Picard
发明人： Elodie Devers , Christophe Bouchy , Nathalie Marchal-George , Florent Picard
IPC分类号： C10G45/00 , B01J27/18
CPC分类号： B01J27/19 , B01J23/882 , B01J35/1014 , B01J35/1047 , B01J37/0201 , C10G45/08 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： The invention is about a catalyst comprising at least one support, at least one group VIII element, at least one group VIB element and phosphorus, in which the density of group VIB elements per unit surface area of the support is in the range (limits included) 2×10−4 to 18×10−4 of oxides of group VIB elements per m2 of support, in which the molar ratio of phosphorus to the group VIB element is in the range 0.27 to 2.00, and in which the amount of group VIB elements is in the range (limits included) 1% to 20% by weight of oxides of group VIB elements and in which the support has a specific surface area of less than 135 m2/g. The invention is also about a process for hydrodesulphurizing gasoline cuts containing sulphur and olefins in the presence of this catalyst.
摘要翻译：本发明涉及包含至少一种载体，至少一种VIII族元素，至少一种VIB族元素和磷的催化剂，其中载体的每单位表面积的VIB族元素的密度在所述范围内）2×10 -4至18×10 -4 VIB元素/ m 2载体的氧化物，其中磷与基团VIB元素在0.27〜2.00的范围内，其中VIB族元素的量在范围（包括的范围）中，1〜20重量％的VIB族元素的氧化物，其中载体具有比表面积面积小于135m 2 / g。本发明还涉及一种在该催化剂存在下加氢脱硫含硫和烯烃的汽油馏分的方法。

10. 发明授权

US09206094B2 Process for selectively hydrogenating a gasoline cut in the presence of a supported sulphide catalyst prepared using at least one cyclic oligosaccharide 有权
标题翻译：在使用至少一种环状低聚糖制备的负载型硫化物催化剂存在下选择性氢化汽油馏分的方法
公开(公告)号：US09206094B2
公开(公告)日：2015-12-08
申请号：US13813021
申请日：2011-06-24
申请人： Fabrice Diehl , Elodie Devers
发明人： Fabrice Diehl , Elodie Devers
IPC分类号： C07C5/05 , B01J23/652 , B01J23/85 , B01J23/881 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/10 , B01J37/02 , B01J37/20 , C10G45/38 , C10G45/32 , C10G45/34 , B01J23/70 , B01J23/75 , B01J23/755 , C07C5/02
CPC分类号： C07C5/05 , B01J23/652 , B01J23/85 , B01J23/881 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0201 , B01J37/0203 , B01J37/20 , C10G45/38 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4018
摘要： Selective hydrogenation of a gasoline cut containing polyunsaturated hydrocarbons containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by bringing said gasoline cut into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII and at least one metal from group VIB deposited on a support.
摘要翻译：通过使所述汽油切割与至少一种催化剂相接触，含有每分子含有至少2个碳原子并具有250℃或更低终点的多不饱和烃的汽油馏分的选择性氢化，所述催化剂的活性相至少包含来自VIII族的一种金属和至少一种沉积在载体上的VIB族金属。

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