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    • 1. 发明申请
    • IN SITU FLUID CONDITION MONITORING
    • 在现场流体状况监测
    • US20050184734A1
    • 2005-08-25
    • US10786818
    • 2004-02-24
    • David SosnowskiGordon Fincannon
    • David SosnowskiGordon Fincannon
    • G01N27/02G01N33/28
    • G01N33/2888G01N27/026
    • A database is compiled of values of the frequency fNM corresponding to the minimum reactance Z″MIN (Nyquist minimum) versus temperature TL over a selected range of temperatures for a probe immersed in a sample of the fluid to be monitored and excited by an a.c. voltage and the frequency swept over a range to cover both bulk fluid and electrode interface impedance characteristics. The probe is then excited in situ and the temperature measured. The Nyquist minimum is then determined from the database and the current measured on the low frequency (interfacial) side of the Nyquist minimum. The angle Θ of the rate of change of resistance Z″ with respect to resistance Z′ and magnitude of the impedance ZS is then determined from the current measurement; and, the fluid condition Ψ determined from a previously compiled database of values of Ψ, ZS and Θ.
    • 数据库被编译为对应于最小电抗Z“SUB”最小“(奈奎斯特最小值)对温度T L L以上的频率f N N N的值 浸没在要被监测和被ac激发的流体样品中的探针的选定温度范围 电压和频率扫过范围以覆盖主流体和电极界面的阻抗特性。 然后将探针原位激发并测量温度。 然后从数据库中确定奈奎斯特最小值,并在Nyquist最小值的低频(界面)侧测量电流。 然后从电流测量确定电阻Z“相对于电阻Z'和阻抗Z S S的大小的变化率的角度θta; 并且,从先前编制的Psi,Z S S和Theta值的数据库确定的流体条件Psi。
    • 2. 发明申请
    • Fluid condition monitoring using broad spectrum impedance spectroscopy
    • 使用广谱阻抗光谱法进行流体状态监测
    • US20060155485A1
    • 2006-07-13
    • US11370416
    • 2006-03-08
    • Charles KoehlerDavid WootonDavid SosnowskiRichard Hirthe
    • Charles KoehlerDavid WootonDavid SosnowskiRichard Hirthe
    • G06F19/00
    • G01N27/026G01N33/28
    • Impedance spectroscopy is used to determine values associated with properties of a substance such as a fluid. In some embodiments, the present invention is applied to engine lubricants. A spectral matrix is constructed that comprises data taken from spectral plots. Also constructed is a result matrix comprising known quantities of a plurality of fluid constituents. A known analytic technique is performed on the spectral matrix to identify at least one principal component having significant influence on the spectral matrix. A reduced spectral matrix, wherein each column in the reduced spectral matrix is associated with a principal component having significant influence on the spectral matrix, is next created. A statistical technique uses the reduced spectral matrix and the result matrix to create at least one prediction equation. The prediction equation is used to predict at least one property in a second substance in situ.
    • 阻抗谱用于确定与物质如流体的性质相关的值。 在一些实施方案中,本发明应用于发动机润滑剂。 构建了包括从谱图中获取的数据的谱矩阵。 还构造了包括已知量的多种流体成分的结果矩阵。 在光谱矩阵上执行已知的分析技术以识别对光谱矩阵具有显着影响的至少一个主成分。 减小的频谱矩阵,其中减小的频谱矩阵中的每个列与对频谱矩阵具有显着影响的主分量相关联。 统计学技术使用缩减谱矩阵和结果矩阵来创建至少一个预测方程。 预测方程用于预测原位第二物质中的至少一种性质。
    • 4. 发明申请
    • Detection of coolant contamination in lubricating fluids
    • 检测润滑液中的冷却剂污染
    • US20050184733A1
    • 2005-08-25
    • US10786815
    • 2004-02-24
    • David SosnowskiRichard Hirthe
    • David SosnowskiRichard Hirthe
    • G01N27/06G01N33/28G01N27/02
    • G01N33/2888G01N27/06
    • An impedance spectroscopy technique and system for detecting in real time engine coolant contamination in lubricant. A probe is disposed in the lubricant and the probe excited with an a.c. voltage frequency sweep over a selected frequency range. The current and current phase angle are measured at selected frequency intervals and the reactance and resistance computed and plotted at each frequency internal as Nyquist plots. The Nyquist minimum is determined at various lubricant temperatures and a database compiled. The probe is then excited in-situ and current measurements taken for a selected frequency lower than the Nyquist minimum to insure measurement of electrode surfaces characteristics. The reactance and resistance are then computed and the angle Θ of change (slope) of reactance with respect to resistance computed. The value of Θ is then compared with values of contamination concentration Ψ versus Θ in a database, and the value of Ψ determined by interpolation.
    • 用于实时检测发动机冷却剂润滑剂污染的阻抗谱技术和系统。 探针设置在润滑剂中,探针用一个等离子体激发。 在所选频率范围内进行电压频率扫描。 以选定的频率间隔测量电流和电流相位角,并在每个频率内计算和绘制的电抗和电阻为奈奎斯特图。 奈奎斯特最小值是在各种润滑剂温度和数据库中进行确定的。 然后探针被原位激发,并且对于低于奈奎斯特最小值的选定频率进行电流测量,以确保电极表面特性的测量。 然后计算电抗和电阻,并计算电抗相对于电阻的变化角(斜率)。 然后将Theta的值与数据库中污染浓度Psi与Theta的值进行比较,并通过插值确定Psi的值。
    • 5. 发明申请
    • Fluid condition monitoring using broad spectrum impedance spectroscopy
    • 使用广谱阻抗光谱法进行流体状态监测
    • US20050110503A1
    • 2005-05-26
    • US10723624
    • 2003-11-26
    • Charles KoehlerDavid WootonDavid SosnowskiRichard Hirthe
    • Charles KoehlerDavid WootonDavid SosnowskiRichard Hirthe
    • G01N27/02G01N33/28G01R27/08
    • G01N27/026G01N33/28
    • Impedance spectroscopy is used to determine values associated with properties of a substance such as a fluid. In some embodiments, the present invention is applied to engine lubricants. A spectral matrix is constructed that comprises data taken from spectral plots. Also constructed is a result matrix comprising known quantities of a plurality of fluid constituents. A known analytic technique is performed on the spectral matrix to identify at least one principal component having significant influence on the spectral matrix. A reduced spectral matrix, wherein each column in the reduced spectral matrix is associated with a principal component having significant influence on the spectral matrix, is next created. A statistical technique uses the reduced spectral matrix and the result matrix to create at least one prediction equation. The prediction equation is used to predict at least one property in a second substance in situ.
    • 阻抗谱用于确定与物质如流体的性质相关的值。 在一些实施方案中,本发明应用于发动机润滑剂。 构建了包括从谱图中获取的数据的谱矩阵。 还构造了包括已知量的多种流体成分的结果矩阵。 在光谱矩阵上执行已知的分析技术以识别对光谱矩阵具有显着影响的至少一个主成分。 减小的频谱矩阵,其中减小的频谱矩阵中的每个列与对频谱矩阵具有显着影响的主分量相关联。 统计学技术使用缩减谱矩阵和结果矩阵来创建至少一个预测方程。 预测方程用于预测原位第二物质中的至少一种性质。