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    • 1. 发明授权
    • Surfactant assisted nanomaterial generation process
    • 表面活性剂辅助纳米材料生成过程
    • US07276184B2
    • 2007-10-02
    • US10193363
    • 2002-07-11
    • Glen C. IrvinRamesh JagannathanSeshadri JagannathanSuresh SunderrajanDavid D. TuschelWilliam C. LenhartDavid J. Nelson
    • Glen C. IrvinRamesh JagannathanSeshadri JagannathanSuresh SunderrajanDavid D. TuschelWilliam C. LenhartDavid J. Nelson
    • B01F3/20B01J20/02
    • C09D11/30B41J2/211C09D11/36
    • A process for the preparation of nanoscale particulate material is described comprising: (i) combining one or more functional material to be precipitated as nanoscale particles and one or more surface active material in a compressed CO2 phase with a density of at least 0.1 g/cc, where the functional material is substantially insoluble in the compressed CO2 in the absence of the surfactant, the surfactant comprises a compressed CO2-philic portion and a functional material-philic portion, and the compressed CO2 phase, functional material and surfactant interact to form an aggregated system having a continuous compressed CO2 phase and a plurality of aggregates comprising surfactant and functional material molecules of average diameter less than 10 nanometers dispersed therein; and (ii) rapidly depressurizing the compressed CO2 phase thereby precipitating the dispersed functional and surfactant materials in the form of composite particles of average diameter from 0.5 to less than 10 nanometers.
    • 描述了制备纳米尺寸颗粒材料的方法,其包括:(i)将一种或多种待沉淀的功能材料作为纳米尺寸颗粒和一种或多种表面活性材料在压缩的CO 2相中组合, 密度为至少0.1g / cc,其中功能材料在不存在表面活性剂的情况下基本上不溶于压缩的CO 2,表面活性剂包括压缩的CO 2 - 亲水部分和功能材料亲水部分,并且压缩的CO 2相,功能材料和表面活性剂相互作用以形成具有连续压缩的CO 2相的聚集体系和 包含分散在其中的表面活性剂和平均直径小于10纳米的功能材料分子的多个聚集体; 和(ii)使压缩的CO 2 2相快速减压,从而将平均直径为0.5至小于10纳米的复合颗粒形式的分散的官能和表面活性剂材料沉淀。