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    • 4. 发明公开
    • 탄소 나노튜브의 수성 현탁액의 제조 방법 및 이로부터 수득된 현탁액
    • 制备碳纳米管的悬浮悬浮液和获得的悬浮液的方法
    • KR1020100015742A
    • 2010-02-12
    • KR1020097021917
    • 2008-04-18
    • 아르끄마 프랑스
    • 쁠레도미니끄
    • B82B3/00C08J3/02B82Y40/00
    • B82Y40/00B82Y30/00C01B32/162C01B32/17C01B32/174C01B2202/28C01B2202/34C01B2202/36H01L2924/0002H01L2924/00
    • The invention relates to a method for preparing an aqueous suspension of carbon nanotubes, that comprises: contacting in an aqueous medium said nanotubes with at least one dispersant comprising a copolymer including at least one anionic hydrophile monomer and at least one monomer containing at least one aromatic group substituted by at least one chain containing one or more oxygen atoms, said chain linking the aromatic group to the unsaturated or cyclic chain of the monomer capable of opening during the formation of the copolymer, the weight ratio between the dispersant and the carbon nanotubes ranging from 0.6:1 to 1.9:1; and mechanically processing the mixture thus obtained using ultrasounds or a rotor-stator system or by passing it in a bead or ball grinder, the invention also relates to the suspension thus obtained and to the uses thereof.
    • 本发明涉及一种制备碳纳米管水性悬浮液的方法,其包括:在含水介质中使所述纳米管与至少一种包含至少一种阴离子亲水单体的共聚物和至少一种含有至少一个芳族的单体的分散剂接触 由至少一个含有一个或多个氧原子的链取代的基团,所述链将芳族基团连接到在共聚物形成期间能够开启的单体的不饱和或环状链,分散剂和碳纳米管之间的重量比范围 从0.6:1至1.9:1; 并使用超声波或转子 - 定子系统机械处理由此获得的混合物,或通过将其通过珠粒或球磨机,本发明还涉及由此获得的悬浮液及其用途。
    • 6. 发明公开
    • 양성자빔 조사를 통한 탄소구조체 정제 방법
    • 使用非化学处理来净化碳纳米管的方法及其使用的装置
    • KR1020080012062A
    • 2008-02-11
    • KR1020060073050
    • 2006-08-02
    • 한국원자력연구원
    • 김재용신관우이종오이석기김계령
    • C01B31/02B82Y40/00
    • C01B32/17B01J19/08B82Y40/00
    • A method for refining a carbon structure is provided to prevent polluting products from being generated due to use of chemical solvent and improve the refining efficiency of the carbon structure, by applying a proton beam to the carbon structure to refine the carbon structure. A carbon structure to be refined is fixed on a stage, which is disposed within a radiation chamber(S10). A proton beam, which is accelerated through a proton accelerator, is applied to the carbon structure to remove impurities contained in the carbon structure, thereby refining the carbon structure(S40). The appliance of the proton beam is performed under an oxidizing ambience, by making an inside of the radiation chamber to have the oxidizing ambience. Further, the carbon structure is one selected from carbon nano tube, carbon fiber, fullerene or carbon black.
    • 提供一种精炼碳结构的方法,通过向碳结构施加质子束以改善碳结构,防止由于使用化学溶剂而产生污染物并提高碳结构的精制效率。 待精制的碳结构固定在放置在辐射室内的台上(S10)。 将通过质子促进剂加速的质子束施加到碳结构以除去碳结构中所含的杂质,从而精炼碳结构(S40)。 通过使辐射室的内部具有氧化气氛,在氧化气氛下进行质子束的制造。 此外,碳结构选自碳纳米管,碳纤维,富勒烯或炭黑。
    • 7. 发明公开
    • 수직 정렬되는 탄소나노튜브 필름 제조 방법
    • 制备碳纳米管膜的方法
    • KR1020080011871A
    • 2008-02-11
    • KR1020060072540
    • 2006-08-01
    • 세종대학교산학협력단
    • 이내성곽정춘이승환
    • B82B3/00B82Y40/00C01B31/02
    • C01B32/16B01J6/00B82B3/0009B82B3/0066B82Y40/00C01B32/17C01B32/174C01B2202/08C01B2202/28C01B2202/30H01J2201/30469
    • A manufacturing method of carbon nanotube film is provided to prepare easily bucky paper through simple filtering and to obtain an emitter of field emission having even electron emitting property. A manufacturing method of carbon nanotube film having vertical arrangement comprises steps of: purifying a carbon nanotube composition containing impurities by a wet purifying method for obtaining high purity carbon nanotube; preparing carbon nanotube film by subjecting the purified carbon nanotube to a filtering process to make the carbon nanotube have vertical arrangement; and carrying out heat treatment for removing organic matters contained in the carbon nanotube film. For aqueous acid solution treatment, the carbon nanotube composition containing impurities is refluxed with aqueous acid solution of 100-110deg.C for 3-12 hours. The wet purifying method comprises steps of: treating the carbon nanotube containing impurities by means of aqueous acid solution; reacting the treated carbon nanotube composition with cationic dispersant; and filtering for extracting impurities by using organic solvent. For the reaction between the treated carbon nanotube composition and cationic dispersant, the reactants are mixed in solid state and the reaction is carried out at 90-150deg.C for 12-96 hours. In the filtering step, the reacted carbon nanotube composition is placed in a filtering vessel having filter inside which is equipped in a soxhlet extraction equipment, and the impurities are extracted by washing the carbon nanotube composition with organic solvent. For heat treatment, the temperature is maintained in the range of 300-400deg.C for 10 minutes to 1 hour in the furnace while flowing 80-120sccm of air. The carbon nanotube film preparing step comprises steps of: dispersing the purified carbon nanotube in organic solvent by ultrasonic vibration; and filtering the dispersion having dispersed carbon nanotube.
    • 提供碳纳米管膜的制造方法,通过简单的过滤制备容易的纸,并获得具有均匀电子发射性能的场致发射体。 具有垂直布置的碳纳米管膜的制造方法包括以下步骤:通过用于获得高纯度碳纳米管的湿法纯化方法来纯化含有杂质的碳纳米管组合物; 通过对纯化的碳纳米管进行过滤处理以使碳纳米管具有垂直布置来制备碳纳米管膜; 并进行用于除去碳纳米管膜中所含有机物质的热处理。 对于酸性水溶液处理,含有杂质的碳纳米管组合物与100-110℃的酸水溶液回流3-12小时。 湿式净化方法包括以下步骤:通过酸水溶液处理含有杂质的碳纳米管; 使经处理的碳纳米管组合物与阳离子分散剂反应; 并通过使用有机溶剂提取杂质进行过滤。 对于经处理的碳纳米管组合物和阳离子分散剂之间的反应,反应物以固态混合,反应在90-150℃下进行12-96小时。 在过滤步骤中,将反应后的碳纳米管组合物置于过滤器内,过滤器内装有索格利特提取设备,通过用有机溶剂洗涤碳纳米管组合物提取杂质。 为了进行热处理,在80-120sccm的空气中,在炉中将温度保持在300-400℃范围内10分钟至1小时。 碳纳米管膜制备步骤包括以下步骤:通过超声振动将纯化的碳纳米管分散在有机溶剂中; 并对具有分散的碳纳米管的分散体进行过滤。