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    • 6. 发明授权
    • 아세틸렌 가스를 이용한 트리플 본딩 기반의 마이크로포어 폴리머 네트워크의 합성방법
    • 使用乙烯气体作为建筑单元的微孔三键聚合物网络的合成
    • KR100995090B1
    • 2010-11-18
    • KR1020090122650
    • 2009-12-10
    • 한국과학기술원
    • 강정구최정훈최경민전형준최윤정이엽
    • C08F38/02C08J9/00B01J31/00
    • C08F238/00
    • PURPOSE: A synthesis method of a micro-porous triple bond based polymer network is provided to simplify the synthesis method, and to mass produce the polymer network while forming a triple bond at the same time. CONSTITUTION: A synthesis method of a micro-porous triple bond based polymer network(TPN-1) comprises the following steps: inserting tetrakis(4-iodophenyl) methane, CuI, and dichlorobis(triphenylphosphine)peledium(II) to a circular flask, adding piperidine as a solvent before bubbling acetylene gas, and stirring for 12 hours in 60 deg C to initiate the coupling reaction; stirring the outcome for 12 hours without bubbling the acetylene gas, heat-processing before cooling at room temperature, filtering, and washing the outcome with dichloromethane, water, and acetone; and drying the washed product for 23~25 hours, and heat processing for 170~190 minutes in 140~160 deg C.
    • 目的:提供一种微孔三键聚合物网络的合成方法,以简化合成方法,同时大量生产聚合物网络同时形成三键。 构造:微孔三键基聚合物网络(TPN-1)的合成方法包括以下步骤:将四(4-碘苯基)甲烷,CuI和二氯双(三苯基膦)pel(II)插入圆形烧瓶中, 在乙炔气体鼓泡前加入哌啶作为溶剂,并在60℃下搅拌12小时以引发偶联反应; 将结果搅拌12小时而不鼓泡乙炔气体,在室温冷却下进行加热处理,过滤并用二氯甲烷,水和丙酮洗涤; 并将洗涤后的产品干燥23〜25小时,在140〜160℃热处理170〜190分钟。