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    • 3. 发明公开
    • 내충격성 및 외관 특성이 우수한 난연성 스티렌계 수지조성물
    • 具有优异抗冲击性和外观的阻燃苯乙烯树脂组合物
    • KR1020040012014A
    • 2004-02-11
    • KR1020020045362
    • 2002-07-31
    • 제일모직주식회사
    • 김용직이계홍진원재
    • C08L25/10C08L9/06C08L51/04C08K5/02
    • C08L25/10C08K3/2279C08K5/03C08K2003/2282C08L51/04C08L2201/02C08L2201/08C08L2205/025
    • PURPOSE: A flame retardant styrene resin composition which has excellent impact resistance, thermostability, appearance characteristics, and fluidity, thereby being applicable to exterior material for articles used in TV, VCR, copy machine, or FAX is provided by using a mixture of polystyrene with different rubber particle sizes, flame retardants which is selected from melt or non-melt halogen compound or mixture thereof, antimony trioxide, impact modifier, and lubricant of olefin compounds. CONSTITUTION: The flame retardant composition comprises: (A) 100 pts.wt. of polystyrene reinforced with rubber comprised of (a1) 50-90 wt% of polystyrene resin reinforced with rubber having 0.2-0.8 micrometer of average rubber particle size, and (a2) 50-10 wt% of polystyrene resin reinforced with rubber having 2.0-3.0 micrometer of average rubber particle size; (B) 5-25 pts.wt. of halogen compound; (C) 1-10 pts.wt. of antimony trioxide; (D) 0.5-10 pts.wt. of antimony trioxide; (E) 1-10 pts.wt. of impact modifier obtained by carrying out graft polymerization of styrene monomer and acrylonitrile monomer with a rubber selected from a group consisting of butadiene rubber, isoprene rubber, butadiene-styrene copolymer or alkylacrylate rubber; and (F) 0.1-5 pts.wt. of olefin-based lubricant.
    • 目的:具有优异的耐冲击性,耐热性,外观特性和流动性的阻燃性苯乙烯树脂组合物,适用于TV,VCR,复印机或FAX中使用的制品的外用材料,通过使用聚苯乙烯与 不同的橡胶粒径,选自熔融或非熔融卤素化合物或其混合物的阻燃剂,三氧化锑,抗冲改性剂和烯烃化合物的润滑剂。 构成:阻燃剂组合物包含:(A)100重量份 由(a1)50-90重量%的由具有0.2-0.8微米平均橡胶粒度的橡胶增强的聚苯乙烯树脂组成的聚苯乙烯增强的聚苯乙烯和(a2)50-10重量%的用橡胶增强的聚苯乙烯树脂, 3.0微米的平均橡胶粒径; (B)5-25重量份 的卤素化合物; (C)1-10重量份 的三氧化锑; (D)0.5-10重量份 的三氧化锑; (E)1-10重量份 通过使用选自丁二烯橡胶,异戊二烯橡胶,丁二烯 - 苯乙烯共聚物或烷基丙烯酸酯橡胶的橡胶进行苯乙烯单体和丙烯腈单体的接枝聚合而获得的抗冲击改性剂; 和(F)0.1-5重量份 的烯烃基润滑剂。
    • 6. 发明公开
    • 내충격성 및 외관 특성이 우수한 난연성 스티렌계 수지조성물
    • 具有优异抗冲击性和外观的阻燃型苯乙烯树脂组合物
    • KR1020040060029A
    • 2004-07-06
    • KR1020020086541
    • 2002-12-30
    • 제일모직주식회사
    • 김용직이규철최규성전인철
    • C08L25/10C08K5/03C08K3/22
    • C08L25/10C08K3/22C08K5/03C08K2003/2282C08L2201/02C08L2205/025
    • PURPOSE: Provided is a flame retardant styrene-based resin composition, which has excellent appearance, impact strength, thermal stability and flowability. CONSTITUTION: The flame retardant styrene-based resin composition comprises: (A) 100 parts by weight of a rubber-reinforced polystyrene resin consisting of (a1) 50-90 wt% of a rubber-reinforced polystyrene resin having an average rubber particle diameter of 0.2-0.8 micrometers and (a2) 50-10 wt% of a rubber-reinforced polystyrene resin having an average rubber particle diameter of 2.0-3.0 micrometers; (B) 5-30 parts by weight of a halogen-containing flame retardant; (C) 1-10 parts by weight of antimony trioxide; (D) 0.5-10 parts by weight of an impact reinforcing agent based on styrene-butadiene; and (E) 0.1-5 parts by weight of an olefin-based lubricant.
    • 目的:提供具有优异的外观,冲击强度,热稳定性和流动性的阻燃苯乙烯类树脂组合物。 构成:阻燃苯乙烯类树脂组合物包含:(A)100重量份由(a1)50-90重量%的橡胶增强聚苯乙烯树脂组成的橡胶增强聚苯乙烯树脂,其橡胶粒径平均值为 0.2〜0.8微米,(a2)50-10重量%的橡胶增强聚苯乙烯树脂,其平均橡胶粒径为2.0-3.0微米; (B)5-30重量份含卤阻燃剂; (C)1-10重量份三氧化锑; (D)0.5-10重量份基于苯乙烯 - 丁二烯的冲击增强剂; 和(E)0.1-5重量份的烯烃基润滑剂。
    • 7. 发明公开
    • 내후성이 우수한 난연성 열가소성 수지조성물
    • 阻燃热塑性树脂组合物具有优异的耐候性
    • KR1020030056028A
    • 2003-07-04
    • KR1020010086181
    • 2001-12-27
    • 제일모직주식회사
    • 진원재이계홍김용직
    • C08L51/04
    • C08K5/3492C08J2300/22C08K5/03C08L25/14C08L2201/02C08L2201/08
    • PURPOSE: A thermoplastic resin composition is provided, which is improved in the weather resistance and the fluidity by employing 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine and decabromodiphenylethane. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a rubber reinforced polystyrene resin which is prepared by polymerizing rubber, an aromatic monoalkenyl monomer and/or an alkyl ester monomer; 5-20 parts by weight of 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine represented by the formula 1; 5-20 parts by weight of decabromodiphenylethane; and 1-20 parts by weight of an auxiliary flame retardant. Preferably the ratio of 2,4,6-tri(2,4,6-tribromophenoxy)-1,3,5-triazine to decabromodiphenylethane is 1.5:1 to 1:1.5 by weight.
    • 目的:提供一种热塑性树脂组合物,其通过使用2,4,6-三(2,4,6-三溴苯氧基)-1,3,5-三嗪和十溴二苯基乙烷改善耐候性和流动性。 构成:热塑性树脂组合物包含100重量份通过聚合橡胶,芳族单烯基单体和/或烷基酯单体制备的橡胶增强聚苯乙烯树脂; 5-20重量份由式1表示的2,4,6-三(2,4,6-三溴苯氧基)-1,3,5-三嗪; 5-20重量份十溴二苯乙烷; 和1-20重量份的辅助阻燃剂。 优选地,2,4,6-三(2,4,6-三溴苯氧基)-1,3,5-三嗪与十溴二苯基乙烷的重量比为1.5:1至1:1.5。
    • 9. 发明授权
    • 고무변성된 폴리스티렌 수지조성물
    • 橡胶改性聚苯乙烯树脂组合物
    • KR1019960016620B1
    • 1996-12-16
    • KR1019930019963
    • 1993-09-27
    • 제일모직주식회사
    • 고영김용직
    • C08L25/04
    • The polystyrene resin composition comprises using butadiene only as a rubber component. The rubber components consist of 1)cis content of 85 % or more and 95 % styrene having a solution viscosity(25 deg.C) of 50-100 centistoke, 2)cis content of 25-40 % and 35 % styrene having a solution viscosity(25 deg.C) of 30-50 centistoke, 3)bound styrene content of 25-50 wt.% and 95 % styrene having a solution viscosity(25 deg.C) of 30-50 centistoke of styrene-butadiene block copolymer rubber and 5-15 wt.parts(15 wt.%) against the total composition is added with a ratio of 5-20 : 75-30 : 20-50 as to 1):2):3).
    • 聚苯乙烯树脂组合物包括仅使用丁二烯作为橡胶组分。 橡胶组分由以下组分组成:1)85%以上的顺式含量和溶液粘度(25℃)为50-100厘沲的95%苯乙烯,2)25-40%的顺式含量和35%的具有溶液的苯乙烯 30-50厘沲的粘度(25℃),3)25-50重量%的结合苯乙烯含量和溶液粘度(25℃)为30-50厘沲的苯乙烯 - 丁二烯嵌段共聚物的95%苯乙烯 加入5-15重量份(15重量%)相对于总组合物的比例为5-20:75-30:20-50至1):2):3)。