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    • 2. 发明公开
    • 가호 조성물
    • 尺寸组成
    • KR1020040002559A
    • 2004-01-07
    • KR1020030038617
    • 2003-06-16
    • 바이엘 악티엔게젤샤프트
    • 리쉐,토스톤노족스,카린펠러,토마스규틀러,크리스토프마자넥,잔
    • C08G18/80
    • C09D175/04C03C25/326C08G18/808
    • PURPOSE: A sizing composition, a method for sizing a glass fiber by using the composition and a glass fiber sized by the method are provided, to improve mechanical properties and hydrolysis resistance by using a water-dispersive and/or water-soluble blocked isocyanate having a remarkable low deblocking temperature. CONSTITUTION: The sizing composition comprises a water-dispersive and/or water-soluble aralkylamine-blocked polyisocyanate; a film-forming resin; a coupling agent; and a lubricant. Preferably the water-dispersive and/or water-soluble aralkylamine-blocked polyisocyanate is prepared from at least one polyisocyanate comprising an aliphatic, alicyclic, araliphatic and/or aromatic bonded isocyanate group; at least one ionic, potentially ionic and/or nonionic compound; at least one blocking agent containing 20 wt% or more of an aralkylamine; at least one aliphatic (alicyclic) monoamine and/or polyamine containing 1-4 amine groups and having a molecular weight of 200 or less; at least one polyvalent alcohol containing 1-4 hydroxyl groups and having a molecular weight of 250 or less; at least one stabilizer and other auxiliaries; and at least one solvent.
    • 目的:提供一种施胶组合物,通过使用该组合物来定尺寸玻璃纤维的方法和通过该方法尺寸的玻璃纤维,通过使用水分散性和/或水溶性封闭异氰酸酯改善机械性能和耐水解性, 显着的低解块温度。 构成:施胶组合物包含水分散和/或水溶性芳烷基胺封闭的多异氰酸酯; 成膜树脂; 偶联剂; 和润滑剂。 优选地,水分散和/或水溶性芳烷基胺封闭的多异氰酸酯由至少一种包含脂族,脂环族,芳脂族和/或芳族键合的异氰酸酯基团的多异氰酸酯制备; 至少一种离子,潜在的离子和/或非离子的化合物; 含有20重量%以上的芳烷基胺的至少一种封端剂; 至少一种含有1-4个胺基并且分子量为200以下的脂族(脂环族)单胺和/或多胺; 至少一种含有1-4个羟基并且分子量为250以下的多价醇; 至少一种稳定剂和其他助剂; 和至少一种溶剂。