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    • 1. 发明公开
    • 트리플루오로메틸-티오펜 카르복실산 아닐리드 및 그의항진균제로서의 용도
    • 三氟甲基硫代羧酸类抗坏血酸及其作为杀真菌剂的用途
    • KR1020050115925A
    • 2005-12-08
    • KR1020057017804
    • 2004-03-20
    • 바스프 에스이
    • 게베르,마르쿠스뮬러,벤드그로테,토마스그라메노스,바실리오스기프제르,안드레아스토르모이블라스코,조르디쉬베글러,안자레인하이머,조아킴블레트너,칼스텐쉬베크,프랑크라크,미카엘쇼플,울리치스트라트만,시그프리드스티를라인하드레테,잔
    • C07D333/38C07D333/20C07D333/12
    • C07D333/38
    • The invention relates to trifluoromethyl- thiophene carboxylic acid anilides of general formulas I, II, and III, wherein the substituents have the following meaning: R1, R 4 independently represent C1-C4alkyl, C3- C6 cycloalkyl, C2-C4 alkenyl, C2-C4 alkinyl, C1-C4 alkoxy, said groups being optionally substituted by halogen, H, halogen, nitro, CN; R2 represents H, OH, C1-C4 alkyl, C 3-C6 cycloalkyl, C1-C4 alkoxy, said groups being optionally substituted by halogen; R3represents C1-C12 alkyl, C3-C12 cycloalkyl, C2-C12 alkenyl, C5-C12 cycloalkenyl, C2-C12 alkinyl, C3-C12 cycloalkyl-C1-C4 alkyl, said groups being optionally substituted by R7; phenyl, phenyl-C1-C6 alkyl, phenyl-C2-C6 alkenyl, phenyl-C2-C 6 alkinyl, phenyloxy-C1-C6 alkyl, phenyloxy-C2- C6 alkenyl, phenyloxy-C2-C6 alkinyl, the alkyl portion, alkenyl portion, and alkinyl portion being optionally substituted by R 7 and the phenyl ring being optionally substituted by R5; -C(R8)=NOR6; X represents O, S, or a direct bond; R5 represents H, C1-C4alkyl, C3-C6 cycloalkyl, C1-C4 alkoxy, C2-C4 alkenyl, C2-C4 alkinyl, said groups being optionally substituted by halogen, halogen, nitro, CN, phenyl which can be substituted by R1, phenoxy that can be substituted by R1, C1-C6 alkyl-phenyl, the alkyl portion being optionally substituted by halogen and the phenyl ring being optionally substituted by R1; R6 represents C 1-C4 alkyl, C3-C6 cycloalkyl, C2-C4 alkenyl, C2-C4 alkinyl, said groups being optionally substituted by halogen, phenyl which can be substituted by R1; R7 represents C 1-C4 alkyl, C1-C8 alkoxy, C2-C8 alkenyloxy, C2-C8 alkinyloxy, C1-C4 alkoxy-C 1-C8 alkoxy, said groups being optionally substituted by halogen, halogen; R8 represents H, R7, or C1-C12 alkyl, C3- C12 cycloalkyl, C2-C12 alkenyl, C5-C12 cycloalkenyl, C3-C12 cycloalkyl-C1-C4 alkyl, said groups being optionally substituted by halogen; phenyl which can be substituted by R5; n represents 0 to 4; and m represents 0, 1. Also disclosed is the use of the inventive trifluoromethyl- thiophene carboxylic acid anilides as fungicides and agents containing said trifluoromethyl-thiophene carboxylic acid anilides.
    • 本发明涉及通式I,II和III的三氟甲基噻吩羧酸酰胺,其中取代基具有以下含义:R 1,R 4独立地表示C 1 -C 4烷基,C 3 -C 6环烷基,C 2 -C 4烯基, C4烷氧基,C1-C4烷氧基,所述基团任选被卤素,H,卤素,硝基,CN取代; R 2表示H,OH,C 1 -C 4烷基,C 3 -C 6环烷基,C 1 -C 4烷氧基,所述基团任选被卤素取代; R3代表C 1 -C 12烷基,C 3 -C 12环烷基,C 2 -C 12烯基,C 5 -C 12环烯基,C 2 -C 12炔基,C 3 -C 12环烷基-C 1 -C 4烷基,所述基团任选被R 7取代; 苯基-C 1 -C 6烷基,苯基-C 2 -C 6烯基,苯基-C 2 -C 6炔基,苯氧基-C 1 -C 6烷基,苯氧基-C 2 -C 6烯基,苯氧基-C 2 -C 6炔基,烷基部分,链烯基 部分和炔基部分任选被R 7取代,并且苯环任选被R 5取代; -C(R8)= NOR6; X表示O,S或直接键; R5表示H,C1-C4烷基,C3-C6环烷基,C1-C4烷氧基,C2-C4烯基,C2-C4炔基,所述基团任选被卤素,卤素,硝基,CN取代,可被R 1取代的苯基, 可被R 1,C 1 -C 6烷基 - 苯基取代的苯氧基,烷基部分任选被卤素取代,苯环任选被R 1取代; R 6表示C 1 -C 4烷基,C 3 -C 6环烷基,C 2 -C 4烯基,C 2 -C 4炔基,所述基团任选被卤素取代,可被R 1取代的苯基; R 7表示C 1 -C 4烷基,C 1 -C 8烷氧基,C 2 -C 8烯氧基,C 2 -C 8烷氧基,C 1 -C 4烷氧基-C 1 -C 8烷氧基,所述基团任选被卤素,卤素取代; R8表示H,R7或C1-C12烷基,C3-C12环烷基,C2-C12链烯基,C5-C12环烯基,C3-C12环烷基-C1-C4烷基,所述基团任选被卤素取代; 可被R5取代的苯基; n表示0〜4; 并且m表示0。还公开了本发明的三氟甲基 - 噻吩羧酸二酰胺作为杀真菌剂和含有所述三氟甲基 - 噻吩羧酸苯胺的试剂的用途。