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1. 发明公开

KR1020130091302A 다반응 이기능성 폴리머 촉매 无效
标题翻译：多功能双功能聚合催化剂
公开(公告)号：KR1020130091302A
公开(公告)日：2013-08-16
申请号：KR1020130088576
申请日：2013-07-26
申请人： 롬 앤드 하아스 컴패니
发明人： 마테낙다니엘 , 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： B01J31/06 , B01J31/28 , C07C5/00 , C07C45/00
CPC分类号： B01J31/10 , B01J2231/46 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C45/73 , C07C49/04
摘要： PURPOSE: A polymer catalyst adapted to reduce the formation of undesirable products at low temperatures to increase the yield is provided, along with a manufacturing method of a saturated ketone adduct employing the same. CONSTITUTION: A polymer catalyst contains at least one mono-sulfonation gel resin and a metal impregnated in the mono-sulfonation gel resin. The particle size of the resin is 560 μm or less and the surface area is 0.1 m^2/g or less. The metal is at least one selected from palladium, platinum, iridium, rhodium, ruthenium, copper, gold, and silver.
摘要翻译：目的：提供一种适用于在低温下减少不需要的产物形成以提高产率的聚合物催化剂，以及采用该催化剂的饱和酮加合物的制备方法。构成：聚合物催化剂含有至少一种单磺化凝胶树脂和浸渍在单磺化凝胶树脂中的金属。树脂的粒径为560μm以下，表面积为0.1m 2 / g以下。金属是选自钯，铂，铱，铑，钌，铜，金和银中的至少一种。

2. 发明公开

KR1020120002463A 케톤의 제조방법 无效
标题翻译：制备酮的方法
公开(公告)号：KR1020120002463A
公开(公告)日：2012-01-05
申请号：KR1020110063353
申请日：2011-06-29
申请人： 롬 앤드 하아스 컴패니
发明人： 마테낙다니엘 , 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： C07C45/68 , C07C49/04 , B01J31/06 , B01J31/28
CPC分类号： C07C45/73 , C07C49/04
摘要： PURPOSE: A manufacturing method of ketone is provided to obtain ketone without additional step for activating catalyst to a reducing agent, and improve producing efficiency after charging catalyst to columns. CONSTITUTION: A manufacturing method of ketone comprises: a step for charging the catalyst of an ion exchange resin in which metal chelate is impregnated, into a column; a step of adding solvent into column; and a step manufacturing ketone by flowing the solvent and hydrogen through the column. The solvent comprises acetone. The metal chelate comprises one metal ion selected from palladium, platinum, iridium, rhodium, ruthenium, copper, gold and silver. The catalyst comprises 0.1-15wt% metal chelate basis on the weight of the dried catalyst.
摘要翻译：目的：提供酮的制造方法以获得酮，而不需要另外的步骤来将催化剂活化到还原剂上，并且在将催化剂装入柱后提高生产效率。构成：酮的制造方法包括：将其中浸渍有金属螯合物的离子交换树脂的催化剂装入柱中的步骤; 将溶剂加入柱中的步骤; 以及通过使溶剂和氢气流过色谱柱来制造酮的步骤。溶剂包括丙酮。金属螯合物包含一种选自钯，铂，铱，铑，钌，铜，金和银的金属离子。该催化剂以干燥催化剂的重量为基准计算为0.1-15wt％的金属螯合物。

3. 发明授权

KR101444695B1 분지된 불포화 알데히드를 생산하기 위한 촉매 및 방법 有权
标题翻译：催化剂和生产分散不饱和醛的方法
公开(公告)号：KR101444695B1
公开(公告)日：2014-09-26
申请号：KR1020120153100
申请日：2012-12-26
申请人： 다우 글로벌 테크놀로지스 엘엘씨 , 롬 앤드 하아스 컴패니
发明人： 베커미카엘씨. , 테이트제임스에프. , 올슨로버트제이. , 트레조-오라일리호세안토니오
IPC分类号： C07C45/78 , C07C47/20 , C07C47/02
CPC分类号： C07C45/002 , C07C45/74 , C07C47/21
摘要： 알데히드를 VIII족으로부터의 금속이 없는 산 폴리머성 촉매와 반응시켜 분지된 불포화 알데히드를 약 10 내지 99.99 중량% 가지며 분지된 알데히드에 대한 반응 선택도가 적어도 92%인 생성물을 생산하고 생성물의 일부를 재순환시키는, 분지된 알데히드의 연속 제조 방법 및 시스템.

4. 发明授权

KR101323632B1 불균일계 촉매의 제조 방법 有权
标题翻译：制备非均相催化剂的方法
公开(公告)号：KR101323632B1
公开(公告)日：2013-11-14
申请号：KR1020110063349
申请日：2011-06-29
申请人： 롬 앤드 하아스 컴패니
发明人： 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： B01J31/06 , B01J31/28 , B01J37/04 , C07B41/06
CPC分类号： B01J23/44 , B01J23/38 , B01J23/72 , B01J31/08 , B01J31/10 , B01J35/002 , B01J37/0203 , B01J37/0209 , B01J37/16 , B01J2231/342 , B01J2231/645 , C07C45/73 , C07C49/04
摘要： 건조된 이온 교환 수지를 케톤과 금속의 용액과 혼합하고, 이온 교환 수지를 팽창시키며, 수지 중에 금속을 분포시킨 다음, 120℃ 이하의 온도에서 금속을 환원제 없이 0가로 전환하는 것을 포함하는 불균일계 촉매의 제조 방법, 이로부터 제조된 촉매, 및 촉매의 용도가 제공된다.

5. 发明授权

KR101416603B1 다반응 이기능성 폴리머 촉매 有权
标题翻译：多功能双功能聚合催化剂
公开(公告)号：KR101416603B1
公开(公告)日：2014-07-08
申请号：KR1020110063351
申请日：2011-06-29
申请人： 롬 앤드 하아스 컴패니
发明人： 마테낙다니엘 , 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： B01J31/06 , B01J31/28 , C07C5/00 , C07C45/00
CPC分类号： B01J31/10 , B01J2231/46 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C45/73 , C07C49/04
摘要： 입자 크기가 560 μm 미만인 모노설폰화 이온 교환 수지, 모노설폰화 겔 및 거대망상(macroreticular) 수지중 적어도 하나와 수지내에 함침되고(impregnated) 팔라듐, 백금, 이리듐, 로듐, 루테늄, 구리, 금 및/또는 은인 금속을 포함하는 폴리머 촉매 및 그의 사용방법이 제공된다.

6. 发明公开

KR1020130076740A 분지된 불포화 알데히드를 생산하기 위한 촉매 및 방법 有权
标题翻译：催化剂和生产分散不饱和醛的方法
公开(公告)号：KR1020130076740A
公开(公告)日：2013-07-08
申请号：KR1020120153100
申请日：2012-12-26
申请人： 다우 글로벌 테크놀로지스 엘엘씨 , 롬 앤드 하아스 컴패니
发明人： 베커미카엘씨. , 테이트제임스에프. , 올슨로버트제이. , 트레조-오라일리호세안토니오
IPC分类号： C07C45/78 , C07C47/20 , C07C47/02
CPC分类号： C07C45/002 , C07C45/74 , C07C47/21
摘要： PURPOSE: A manufacturing method of a branched unsaturated aldehyde is provided to manufacture a branched unsaturated aldehyde capable of manufacturing a branched acid by an oxidation, with an improved selectivity. CONSTITUTION: A manufacturing method of a branched unsaturated aldehyde comprises a step of providing a feedstock which has 99.99 wt% of a C_n unsaturated aldehyde; a step of attaching the feedstock to a resin which contains an acid functional group and does not contain a metal from the group VIII; a step of generating an exit stream of which the reaction selectivity to the branched unsaturated C_2n aldehyde is at least 92%, by the reaction between the mixture and the resin; and a step of removing at least parts of the C_n branched unsaturated C_2n aldehyde; and additionally includes a step of recycling parts of the exit stream.
摘要翻译：目的：提供支链不饱和醛的制造方法，以制备能够通过氧化制备支链酸的支链不饱和醛，并提高选择性。构成：支链不饱和醛的制造方法包括提供具有99.99重量％C_n不饱和醛的原料的步骤; 将原料连接到含有酸官能团并且不含VIII族金属的树脂的步骤; 通过混合物和树脂之间的反应产生其对支链不饱和C_2n醛的反应选择性至少为92％的出口流的步骤; 以及除去C_n支链不饱和C_2n醛的至少一部分的步骤; 并且还包括回收出口流的部分的步骤。

7. 发明公开

KR1020120002462A 다반응 이기능성 폴리머 촉매 有权
标题翻译：多功能双功能聚合催化剂
公开(公告)号：KR1020120002462A
公开(公告)日：2012-01-05
申请号：KR1020110063351
申请日：2011-06-29
申请人： 롬 앤드 하아스 컴패니
发明人： 마테낙다니엘 , 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： B01J31/06 , B01J31/28 , C07C5/00 , C07C45/00
CPC分类号： B01J31/10 , B01J2231/46 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C45/73 , C07C49/04
摘要： PURPOSE: A multireaction-bifunctional polymeric catalyst is provided to reduce the formation of undesirable products at low temperatures by including a monosulfonated ion exchanging resin, monosulfonated gel, or a macro-reticular resin. CONSTITUTION: A multireaction-bifunctional polymeric catalyst includes at least one of a monosulfonated ion exchanging resin, monosulfonated gel, or a macro-reticular resin, and a metal impregnated in the resin. The metal is at least one selected from palladium, platinum, iridium, rhodium, ruthenium, copper, gold, and silver. The catalyst includes 0.1-15% of metals. The monosulfonated gel and the macro-reticular resin include cross linking agents.
摘要翻译：目的：提供多功能双官能聚合催化剂，通过包括单磺化离子交换树脂，单磺化凝胶或大网状树脂，在低温下减少不需要的产物的形成。构成：多功能双功能聚合催化剂包括单磺化离子交换树脂，单磺化凝胶或大网状树脂中的至少一种以及浸渍在树脂中的金属。金属是选自钯，铂，铱，铑，钌，铜，金和银中的至少一种。催化剂含0.1-15％的金属。单磺化凝胶和大网状树脂包括交联剂。

8. 发明公开

KR1020120002461A 불균일계 촉매의 제조 방법 有权
标题翻译：制备异构催化剂的方法
公开(公告)号：KR1020120002461A
公开(公告)日：2012-01-05
申请号：KR1020110063349
申请日：2011-06-29
申请人： 롬 앤드 하아스 컴패니
发明人： 테이트제임스에프. , 트레조-오라일리호세안토니오
IPC分类号： B01J31/06 , B01J31/28 , B01J37/04 , C07B41/06
CPC分类号： B01J23/44 , B01J23/38 , B01J23/72 , B01J31/08 , B01J31/10 , B01J35/002 , B01J37/0203 , B01J37/0209 , B01J37/16 , B01J2231/342 , B01J2231/645 , C07C45/73 , C07C49/04
摘要： PURPOSE: A method for manufacturing a heterogeneous catalyst is provided to minimize the generation of excess liquid and to omit a reducing agent-based activating process. CONSTITUTION: A method for manufacturing a heterogeneous catalyst includes the following: A dried ion exchanging resin is mixed with ketone and a metal solution. The ion exchanging resin is expanded, and the metal of the metal solution is distributed in the resin. The metal is converted into zero valent without a reducing agent at a temperature lower than or equal to 120 degrees Celsius. The keton is eliminated from the ion exchanging resin. The catalyst includes metal ions. The metal ions are one or more selected from palladium, platinum, iridium, rhodium, ruthenium, copper, gold, and silver.
摘要翻译：目的：提供一种用于制造非均相催化剂的方法，以使过量液体的产生最小化并省略基于还原剂的活化方法。构成：用于制造非均相催化剂的方法包括以下步骤：将干燥的离子交换树脂与酮和金属溶液混合。离子交换树脂膨胀，金属溶液的金属分散在树脂中。在低于或等于120摄氏度的温度下，金属转化为零价而不含还原剂。从离子交换树脂中除去酮。催化剂包括金属离子。金属离子是选自钯，铂，铱，铑，钌，铜，金和银中的一种或多种。

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