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    • 64. 发明公开
    • 상압직접침출공법을 이용한 니켈 매트에서 니켈 및 유가금속을 회수하는 방법
    • 使用大气直接浸出工艺从镍矿中回收镍和重金属的方法
    • KR1020100108746A
    • 2010-10-08
    • KR1020090026925
    • 2009-03-30
    • 고려아연 주식회사코리아 니켈 주식회사
    • 최창영김병문
    • C22B3/08C22B23/00C22B11/00
    • Y02P10/234C22B23/043C22B3/045C22B3/08C22B3/22C22B23/0453
    • PURPOSE: A method for collecting valuable metal from nickel matte using an atmospheric direct leaching process is provided to collect Ni, Co(Cobalt), and Cu from nickel matte without a pressure vessel by an atmospheric pressure direct leaching method. CONSTITUTION: A method for collecting valuable metal from nickel matte using an atmospheric direct leaching process comprises following steps. A nickel matte is pulverized(S100). First leaching solution is put into a reaction bath under atmospheric pressure, temperature is maintained at 80~85°C, and the pulverized nickel matte and oxygen are put into a reactor(S200). The first leaching solution is divided into the leached residue and leachate(S300). The second leaching solution is put into the reactor and is maintained at 90~95°C, and the leached residue and oxygen are put into the reactor(S400). The second leaching solution is divided into the final leached residue and the final leachate(S500).
    • 目的:提供使用大气直接浸出法从镍锍收集有价值金属的方法,通过大气压直接浸出法从镍锍中收集Ni,Co(钴)和Cu,无需压力容器。 构成:使用大气直接浸出方法从镍锍收集有价金属的方法包括以下步骤。 将镍锍粉碎(S100)。 将第一浸出溶液放入大气压下的反应浴中,温度保持在80〜85℃,将粉碎的镍无光泽和氧气放入反应器中(S200)。 第一浸出液分为浸出渣和渗滤液(S300)。 将第二浸出溶液放入反应器中并保持在90〜95℃,将浸出的残渣和氧气放入反应器中(S400)。 第二浸出液分为最终浸出残渣和最终浸出液(S500)。
    • 65. 发明授权
    • 코발트 스크랩으로부터 코발트의 회수 방법
    • 从钴烧渣中回收钴的方法
    • KR100942518B1
    • 2010-02-12
    • KR1020090041105
    • 2009-05-12
    • 박경도
    • 박경도
    • C22B23/00C22B7/00C22B3/06C22B3/08
    • Y02P10/234C22B23/0407C22B7/007C22B7/008C22B23/0453
    • PURPOSE: A method for recycling cobalt from a cobalt scrap is provided to reuse cobalt by effectively and environmentally-friendly extracting the cobalt from cobalt scrap. CONSTITUTION: A method for recycling cobalt from a cobalt scrap is as follows. Cobalt scrap is divided into scrap sediment and scrap extract. The scrap extract is divided into a first cobalt composite solution and a binary metal deposit. The first cobalt composite solution is divided into a second cobalt composite solution and an oxidized metal deposit. The second cobalt composite solution is divided into NaOH supernatant and Co(OH)2 complex deposit. The Co(OH)2 complex deposit is divided into an acid-cobalt composite solution and a binary metal deposited impurity. The acid-cobalt composite solution is divided into metal organic solution and Co(OH)2 solution. The Co(OH)2 solution is divided into alkali supernatant and cobalt hydroxide. The cobalt hydroxide is recovered and dried.
    • 目的:提供一种从钴废料中回收钴的方法,通过有效和环保地从钴废料中提取钴来再利用钴。 构成:从钴废料回收钴的方法如下。 钴废料分为废渣和废料提取物。 废料提取物分为第一钴复合溶液和二元金属沉积物。 第一钴复合溶液分为第二钴复合溶液和氧化金属沉积物。 第二钴复合溶液分为NaOH上清液和Co(OH)2络合物沉积物。 Co(OH)2复合沉积物分为酸 - 钴复合溶液和二元金属沉积杂质。 酸 - 钴复合溶液分为金属有机溶液和Co(OH)2溶液。 Co(OH)2溶液分为碱性上清液和氢氧化钴。 回收氢氧化钴并干燥。
    • 69. 发明公开
    • 전지 잔사로부터 금속의 회수 방법
    • 从电池残渣中回收金属的方法
    • KR1020080086339A
    • 2008-09-25
    • KR1020070135280
    • 2007-12-21
    • 닛코 킨조쿠 가부시키가이샤
    • 야마구찌,요스께히노,준조
    • C22B3/08C22B7/00
    • Y02P10/234Y02W30/84C22B7/007C22B3/08C22B3/10C22B3/22C22B23/0407C22B47/00
    • A method for recovering precious metals from ternary Li metal salts from battery residues of lithium batteries is provided. A method for recovering precious metals from battery residues containing Co, Ni, and Mn comprises: stirring and leaching lithium battery residues containing lithium metal salts containing almost equivalent Co, Ni and Mn into a hydrochloric acid solution with a concentration of at least 250 g/L, or heating, stirring and leaching the battery residues containing lithium metal salts containing almost equivalent Co, Ni and Mn into a sulfuric acid solution with a concentration of at least 200 g/L; solvent-extracting almost 100% of Mn and Co with respect to the leachate using an acidic extractant to produce solutions containing respective metals; and recovering the metals from the solutions. The method comprises solvent-extracting Mn and Co with the acidic extractant. The method comprises adjusting pH of the extract to precipitate Mn, Co and Ni from the extract and filtering the precipitated Mn, Co and Ni to recover Mn, Co and Ni as solids after solvent-extracting Mn and Co with the acidic extractant. The method comprises dissolving the solids into an electrolytic solution again and electrowinning the solid-dissolved solution.
    • 提供了从锂电池的电池残渣中从三元Li金属盐中回收贵金属的方法。 从含有Co,Ni和Mn的电池残渣中回收贵金属的方法包括:将含有几乎相当于Co,Ni和Mn的锂金属盐的锂电池残渣搅拌并浸出至浓度至少为250g / L,或将含有几乎相当于Co,Ni和Mn的锂金属盐的电池残渣加热,搅拌和浸出到浓度至少为200g / L的硫酸溶液中; 使用酸性萃取剂溶剂提取几乎100%的Mn和Co相对于渗滤液产生含有各种金属的溶液; 并从溶液中回收金属。 该方法包括用酸性萃取剂溶剂萃取Mn和Co。 该方法包括调节提取物的pH值,从提取物中沉淀出Mn,Co和Ni,并对沉淀的Mn,Co和Ni进行过滤,在用酸性萃取剂溶剂萃取Mn和Co后,以Mn,Co和Ni作为固体回收Mn。 该方法包括将固体再次溶解在电解液中并电解提取固体溶解的溶液。
    • 70. 发明公开
    • 전해 침전 구리의 처리 방법
    • 用于处理电沉积铜的方法
    • KR1020080028745A
    • 2008-04-01
    • KR1020070033389
    • 2007-04-04
    • 닛코 킨조쿠 가부시키가이샤
    • 기무라유키오가츠라시게오
    • C22B3/08C22B3/00C22B7/00
    • Y02P10/234Y02P10/236C22B15/0071C22B3/045C22B3/08C22B3/22C22B15/0086C22B30/02C22B30/04C22B30/06
    • A method for separately recovering copper, arsenic, bismuth, antimony and the like from electrolytically precipitated copper in a highly convenient manner is provided. A method for treating electrolytically precipitated copper comprises: a first process of subjecting a leaching residue containing Sb and Bi and a sulfuric acid leachate containing pentavalent As(arsenic) to solid-liquid separation after performing a sulfuric acid leaching process of stirring the solution at a liquid temperature and a time sufficient to oxidize at least 90 wt.% of As contained in the electrolytically precipitated copper into pentavalent As while introducing oxygen-containing gas into the electrolytically precipitated copper contained in an acidic sulfuric acid solution after optionally cleaning electrolytically precipitated copper with water; a second process of adding trivalent iron into the sulfuric acid leachate, thereby producing crystalline Scorodite(FeAsO4-2H2O) to separate a residue containing the crystalline Scorodite and a post-As removal liquid from the sulfuric acid leachate; an optional third process of adding an alkali into the post-As removal liquid to produce an Fe salt if a non-reaction Fe or non-reaction Fe and As is or are remained in the post-As removal liquid, coprecipitating As with the Fe salt if the As is remained in the post-As removal liquid, and separating a post-Fe removal liquid and a precipitate containing an Fe salt and As if the As is remained in the post-As removal liquid; and an optional fourth process of adding an alkali into the post-Fe removal liquid to precipitate a Cu salt, and separating a post-Cu removal liquid and a precipitate containing a Cu salt from the post-Fe removal liquid.
    • 提供了一种以非常方便的方式从电解沉淀铜中分别回收铜,砷,铋,锑等的方法。 一种处理电沉淀铜的方法包括:在进行硫酸浸出过程之后,将溶液浸渍在硫酸浸出过程中,使含有Sb和Bi的浸出残渣和含有五价砷(砷)的硫酸浸出液进行固液分离, 液体温度和足以将电解沉淀的铜中所含的至少90重量%的As氧化成五价砷的时间,同时在含有氧的气体中导入含酸气体进入酸性硫酸溶液中所含的电解沉淀铜中,然后任选地清洗电解沉淀的铜, 水; 向硫酸浸出液中加入三价铁的第二种方法,从而生成结晶的Scorodite(FeAsO 4·2H 2 O),从硫酸浸出液中分离含有结晶Scorodite的残渣和As-As去除液; 如果非反应Fe或非反应Fe和As残留在后As去除液体中,则可将第三种方法添加到后As去除液中以产生Fe盐,与Fe共沉淀 如果As保留在后As去除液体中,并且分离后Fe去除液体和含有Fe盐的沉淀物以及如果As残留在后As去除液体中,则为As; 以及可选地将碱添加到后Fe去除液中以沉淀Cu盐的第四步骤,以及从Fe后除去液体中分离出Cu后除去液体和含有Cu盐的沉淀物。