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    • 41. 发明公开
    • 열경화성 도료 조성물
    • 耐热硬化漆组合物
    • KR1020000068271A
    • 2000-11-25
    • KR1019997001406
    • 1997-07-29
    • 바스프 코팅스 게엠베하니치유 가부시키가이샤
    • 누끼따,아끼또시바또,기시오뤼어,잉고
    • C09D157/00
    • C09D175/04C08G18/6229C08G18/7893C08L61/32C09D133/066C08L2666/14
    • The invention relates to a heat-hardenable paint composition which contains (A) vinyl based copolymer of hydroxyl group value from 20 to 200 mg KOH/g, being a copolymer of from 5 to 70 wt.% hydroxyl group containing vinyl based monomer which can be represented by general formula (1) and from 95 to 30 wt.% other vinyl based monomer (a-2), and (B) 1,3,5-triazine-2,4,6-triscarbamic acid ester which can be represented by general formula (2): C 3 N 3 (NHCOOR) 3 or an oligomer thereof, in which the mol ratio of hydroxyl groups originating from the aforementioned (A) component: NHCOOR groups originating from the aforementioned (B) component in the composition is from 1:3 to 3:1. In general formula (1), X 1, X 2 and X 3 each independently represent a hydrogen atom or a methyl group. Moreover j is an integer of value from 0 to 2, m is an integer of value from 3 to 5, and n is an integer of value from 0 to 5. However, j and n cannot both be 0. In general formula (2), R represents an alkyl group which has from 1 to 20 carbon atoms, an aryl group which has from 6 to 20 carbon atoms or an aralkyl group which has from 7 to 20 carbon atoms, and these groups may be the same or different.
    • 本发明涉及一种热硬化性涂料组合物,其含有羟基值为20〜200mg KOH / g的(A)乙烯基类共聚物,为含有5-70%(重量)羟基的乙烯基系单体的共聚物, 由通式(1)表示,95〜30重量%的其他乙烯基类单体(a-2)和(B)1,3,5-三嗪-2,4,6-三氨基甲酸酯 由通式(2)表示:C 3 N 3(NHCOOR)3或其低聚物,其中源于上述(A)成分的羟基的摩尔比:源自上述(B)成分的NHCOOR基团 组成为1:3至3:1。 在通式(1)中,X 1,X 2和X 3各自独立地表示氢原子或甲基。 此外,j为0〜2的整数,m为3〜5的整数,n为0〜5的整数。然而,j,n均不能为0。通式(2) ),R表示碳原子数1〜20的烷基,碳原子数6〜20的芳基或碳原子数7〜20的芳烷基,这些基可以相同也可以不同。
    • 42. 发明公开
    • 자동차 도료용 수지조성물
    • 汽车涂料用树脂组合物
    • KR1020000045053A
    • 2000-07-15
    • KR1019980061565
    • 1998-12-30
    • 주식회사 케이씨씨
    • 김창수김동진김종문
    • C09D133/06
    • C09D133/066C08L67/00C09D5/00C09D183/04
    • PURPOSE: A thermosetting resin excellent in scratch resistance is provided which uses a siloxane monomer with a silyl group that does not cause trouble in the reactivity with moisture as well as resolving a problem of a silyl group. CONSTITUTION: A composition for clear paint of an automobile overcoat contains a binder comprising 10 to 80 parts by weight of a siloxane modified acrylic resin having a hydroxyl group of 50 to 170 mg KOH/g, a number average molecular weight of 1,000 to 10,000 and a glass transition temperature of -10 to -50°C, 10 to 50 parts by weight of an acrylic modified polyester polyol, 5 to 20 parts by weight of a melamine curing agent, and 0.5 to 5 parts by weight of an acid catalyst. The composition can restrain the occurrence of a scratch by an automatic washing machine.
    • 目的:提供耐刮擦性优异的热固性树脂,其使用具有甲硅烷基的硅氧烷单体,其不会引起与水分的反应性的问题,并解决甲硅烷基的问题。 构成:用于汽车外涂层的透明涂料的组合物含有粘合剂,其包含10至80重量份的羟基为50至170mg KOH / g,数均分子量为1,000至10,000的硅氧烷改性丙烯酸树脂和 玻璃化转变温度为-10〜-50℃,丙烯酸改性聚酯多元醇为10〜50重量份,蜜胺固化剂为5〜20重量份,酸催化剂为0.5〜5重量份。 组合物可以通过自动洗衣机抑制划痕的发生。
    • 47. 发明授权
    • 이액형 노면표지용 도료 조성물
    • 这种用于道路标志的液体型涂料组合物
    • KR101814346B1
    • 2018-01-04
    • KR1020170106382
    • 2017-08-23
    • 주식회사 에코리치나항도
    • 나항도
    • C09D133/00C09D7/12C09D5/33C09D133/12C09D133/06
    • C09D133/00C09D5/004C09D7/61C09D7/63C09D133/066C09D133/12
    • 본발명은상기한문제점을해결하기위한것으로본 발명의목적은이액형노면표지용도료의경화건조가 3-10분사이에신속하게이루어지며, 내마모성, 내구성및 내충격성이우수한이액형노면표지용도료조성물과그 제조방법을제공하는데있다본 발명에따른이액형노면표지용도료조성물은복합아크릴수지와 2관능아크릴수지, 분산제, 안정제, 반응촉진제, 유동성조정제, 증점제, 착색안료, 체질안료를포함하는주제와, 주성분이벤조산분지형알킬에스테르(Benzoic acid branched alkyl ester)와과산화벤조일(Benzoyl peroxide), 실리카에의한디클로로디메틸의반응생성물(Dichlorodimethylsiline: reaction products with silica), 옥타데칸산아연염(Octadecanoic acid zinc salt)로구성되는경화제를포함하는것을특징으로한다.
    • 意在解决上述问题,本发明的发明对象是液体型路面变得迅速作出3-10的注射,优良的耐磨性,耐用和耐冲击组分涂料组合物用于标记路面的覆盖涂层材料的干燥固化 的液体类型路面覆盖涂层组合物是本发明提供一种组合物及其制造方法,其包括复合材料的丙烯酸类树脂和双官能丙烯酸类树脂,分散剂,稳定剂,反应促进剂,流动性调节剂,增稠剂,着色颜料,体质颜料 本研究的目的是研究苯甲酸支链烷基酯和过氧化苯甲酰对二氧化硅与十八烷酸锌反应产物的影响 固化剂的盐。