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21. 发明公开

KR1020020096982A 탄화수소의 선택적인 산화를 위해 열수적으로 합성된ＭＯ-Ｖ-Ｍ-Ｘ 산화물 촉매 失效
标题翻译： HYDROTHERMALLY合成的MO-V-M-X氧化物催化剂用于选择性氧化烃
公开(公告)号：KR1020020096982A
公开(公告)日：2002-12-31
申请号：KR1020020034031
申请日：2002-06-18
申请人： 롬 앤드 하스 캄파니
发明人： 가프니앤메이 , 송루오지
IPC分类号： B01J23/64 , B01J23/887
CPC分类号： C07C51/252 , B01J23/002 , B01J23/18 , B01J23/22 , B01J23/28 , B01J27/0576 , B01J37/10 , B01J2523/00 , C07C51/215 , C07C253/24 , C07C253/26 , Y02P20/52 , C07C57/04 , B01J2523/54 , B01J2523/55 , B01J2523/64 , B01J2523/68 , B01J2523/36 , B01J2523/52 , B01J2523/18 , B01J2523/19 , B01J2523/44 , B01J2523/27 , B01J2523/32 , B01J2523/42 , B01J2523/63 , B01J2523/3706 , B01J2523/53 , C07C255/08
摘要： PURPOSE: Provided are a catalyst for the oxidation of alkanes or a mixture of alkanes and alkenes; their corresponding unsaturated carboxylic acids by vapor phase catalytic oxidation; a method for making the catalyst; and a process for the vapor phase catalytic oxidation of alkanes or a mixture of alkanes and alkenes, to their corresponding unsaturated carboxylic acids using the catalyst. CONSTITUTION: A catalyst comprises a mixed metal oxide having the formula:MoaVbMcXdOe, wherein M is an element selected from the group consisting of Te, Sb and Nb,wherein X is an element selected from the group consisting of Sc, Y, La, Re, Ir, Cu, Ag, Au, Zn, Ga, Si, Ge, As, Pb, S, Se, Sn, Bi, F, Cl, Br and I, and wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0 to 1 and e is dependent on the oxidation state of the other elements, with the proviso that, when d = 0, M is selected from the group consisting of Nb and Te, and with the further proviso that, when d = 0 and M = Te, 0.01
摘要翻译：目的：提供烷烃或烷烃和烯烃的混合物的氧化催化剂; 其相应的不饱和羧酸通过气相催化氧化; 制造催化剂的方法; 以及使用催化剂将烷烃或烷烃和烯烃的混合物气相催化氧化成其相应的不饱和羧酸的方法。构成：催化剂包含具有下式的混合金属氧化物：MoaVbMcXdOe，其中M是选自Te，Sb和Nb的元素，其中X是选自Sc，Y，La，Re ，Ir，Cu，Ag，Au，Zn，Ga，Si，Ge，As，Pb，S，Se，Sn，Bi，F，Cl，Br和I，其中，当a = 1时，b = 0.01〜1.0 ，c = 0.01〜1.0，d = 0〜1，e取决于其他元素的氧化态，条件是当d = 0时，M选自Nb和Te，进一步的条件是，当d = 0且M = Te时，0.01 <= b <0.50或0.17

22. 发明公开

KR1020020090155A 혼합-금속 산화물 촉매 및 그 제조방법 无效
标题翻译：混合金属氧化物催化剂及其制备方法
公开(公告)号：KR1020020090155A
公开(公告)日：2002-11-30
申请号：KR1020020028738
申请日：2002-05-23
申请人： 롬 앤드 하스 캄파니
发明人： 가프니앤메이 , 송루오지
IPC分类号： B01J23/84 , B01J23/887
CPC分类号： C07C51/252 , B01J23/002 , B01J23/20 , B01J23/28 , B01J27/0576 , B01J37/036 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C253/24 , C07C253/26 , Y02P20/52 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C255/08
摘要： PURPOSE: Provided are a mixed-metal oxide catalyst with improved performance quality, which can be useful, for example, in the conversion of alkanes, or mixtures of alkanes and alkenes, to unsaturated carboxylic acids or unsaturated nitriles, and a process for preparing the same. CONSTITUTION: The process for the preparation of an improved catalyst comprising a mixed-metal oxide having the empirical formula MoaVbEcXdOe(wherein E is at least one element selected from the group consisting of Te and Sb, wherein X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pd, Pt, Ag, B, In, Ce and W, and wherein, when a = 1, b = 0.01 to 1.0, c = 0.01 to 1.0, d = 0.01 to 1.0 and e is dependent on the oxidation state of the other elements), comprises the steps of (a) admixing the compounds of Mo, V, E and X and at least one solvent to form a gel; (b) aging the formed gel; and (c) calcining the gel.
摘要翻译：目的：提供具有改进的性能质量的混合金属氧化物催化剂，其可用于例如将烷烃或烷烃和烯烃的混合物转化为不饱和羧酸或不饱和腈的方法，以及制备相同。构成：制备包含具有经验式MoaVbEcXdOe的混合金属氧化物的改进催化剂的方法（其中E是选自Te和Sb中的至少一种元素，其中X是选自以下的至少一种元素：由Nb，Ta，Ti，Al，Zr，Cr，Mn，Fe，Ru，Co，Rh，Ni，Pd，Pt，Ag，B，In，Ce和W组成的组，其中，当a = 1，b = 0.01〜1.0，c = 0.01〜1.0，d = 0.01〜1.0，e取决于其他元素的氧化态），包括以下步骤：（a）将Mo，V，E和X的化合物与至少一种溶剂形成凝胶; （b）老化形成的凝胶; 和（c）煅烧凝胶。

23. 发明公开

KR1020020082764A 개선된 촉매 有权
标题翻译：改进的催化剂
公开(公告)号：KR1020020082764A
公开(公告)日：2002-10-31
申请号：KR1020020021917
申请日：2002-04-22
申请人： 롬 앤드 하스 캄파니
发明人： 보간레오나르드에드워드2세
IPC分类号： B01J27/057 , B01J23/887
CPC分类号： C07C51/215 , B01J23/002 , B01J23/20 , B01J23/28 , B01J27/0576 , B01J37/0236 , B01J37/06 , B01J2523/00 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/18 , B01J2523/3706 , B01J2523/3737 , B01J2523/72
摘要： PURPOSE: Provided is an improved catalyst for the oxidation of alkanes, or a mixture of alkanes and alkenes, to their corresponding unsaturated carboxylic acids by vapor phase catalytic oxidation. CONSTITUTION: The improved catalyst is prepared by process comprising the steps of (a) providing a mixed metal oxide having the empirical formula AaVbNcXdOe(wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te and Se, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Ag, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm, Tb, Br, Cu, Sc, Cl, F and I, wherein A, V, N and X are present in such amounts that the atomic ratio of A : V : N : X is a : b : c : d, and wherein, when a = 1, b = 0.1 to 2, c = 0.1 to 1, d = 0.01 to 1 and e is dependent on the oxidation state of the other elements); (b) contacting the mixed metal oxide with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; and (c) recovering insoluble material from the contact mixture to obtain the improved catalyst.
摘要翻译：目的：提供了通过气相催化氧化将烷烃或烷烃和烯烃的混合物氧化成其相应的不饱和羧酸的改进的催化剂。构成：改进的催化剂是通过以下步骤制备的，该方法包括以下步骤：（a）提供具有经验式AaVbNcXdOe的混合金属氧化物（其中A是选自Mo和W中的至少一种元素，N是至少一种元素选自由Te和Se组成的组中的至少一种元素，X是选自Nb，Ta，Ti，Al，Zr，Cr，Mn，Fe，Ru，Co，Rh，Ni，Pt，Bi ，B，In，Ce，As，Ge，Sn，Li，Na，K，Rb，Cs，Fr，Be，Mg，Ca，Sr，Ba，Ra，Hf，Pb，P，Pm，Eu，Gd，Dy ，Ho，Er，Tm，Yb，Lu，Au，Ag，Re，Pr，Zn，Ga，Pd，Ir，Nd，Y，Sm，Tb，Br，Cu，Sc，Cl，F和I，其中A， V，N和X的存在量使得A:V:N:X的原子比为a:b:c:d，其中当a = 1时，b = 0.1〜2，c = 0.1〜1 ，d = 0.01〜1，e取决于其他元素的氧化态）; （b）使混合的金属氧化物与选自有机酸，醇，无机酸和过氧化氢的液体接触构件接触以形成接触混合物; 和（c）从接触混合物中回收不溶物，得到改进的催化剂。

24. 发明公开

KR1020020030013A 증진된 멀티-금속산화물 촉매 有权
标题翻译：促进的多金属氧化物催化剂
公开(公告)号：KR1020020030013A
公开(公告)日：2002-04-22
申请号：KR1020010058666
申请日：2001-09-21
申请人： 롬 앤드 하스 캄파니
发明人： 챠투르베디산제이 , 가프니앤메이 , 한스코트 , 헤프너미셀도린 , 송루오지 , 레도미니크헝뉴 , 빅케리엘시메이
IPC分类号： B01J23/64 , B01J23/54 , B01J23/76
CPC分类号： B01J23/002 , B01J23/20 , B01J23/28 , B01J23/6525 , B01J23/686 , B01J23/8877 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08 , B01J2523/18 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/19 , B01J2523/824 , B01J2523/847 , B01J2523/17
摘要： PURPOSE: An improved catalyst for the oxidation of alkanes or a mixture of alkanes and alkenes to their corresponding unsaturated carboxylic acids by vapor phase catalytic oxidation in the presence of ammonia is provided, and a preparation method thereof is also provided. CONSTITUTION: A catalyst is characterized in that it comprises a promoted mixed metal oxide having the empirical formula AaMbNcXdZeOf wherein A is at least one element selected from the group consisting of Mo and W, M is at least one element selected from the group consisting of V and Ce, N is at least one element selected from the group consisting of Te, Sb and Se, X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Sb, Bi, B, In, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu, and Z is selected from the group consisting of Ni, Pd, Cu, Ag and Au; and wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.001 to 0.1 and f is dependent on the oxidation state of the other elements.
摘要翻译：目的：提供一种用于在氨存在下通过气相催化氧化将烷烃或烷烃和烯烃与其相应的不饱和羧酸的混合物氧化的改进催化剂，并提供其制备方法。构成：催化剂的特征在于其包含具有经验式AaMbNcXdZeOf的促进的混合金属氧化物，其中A是选自Mo和W中的至少一种元素，M是选自V 和Ce，N是选自Te，Sb和Se中的至少一种元素，X是选自Nb，Ta，Ti，Al，Zr，Cr，Mn，Fe，Ru中的至少一种元素，Co，Rh，Ni，Pt，Sb，Bi，B，In，As，Ge，Sn，Li，Na，K，Rb，Cs，Fr，Be，Mg，Ca，Sr，Ba，Ra，Hf，Pb ，P，Pm，Eu，Gd，Dy，Ho，Er，Tm，Yb和Lu，Z选自Ni，Pd，Cu，Ag和Au; 其中，当a = 1时，b = 0.01〜1.0，c = 0.01〜1.0，d = 0.01〜1.0，e = 0.001〜0.1，f取决于其他元素的氧化态。

25. 发明公开

KR1020020025715A 하소 无效
标题翻译：使用计算制备的多金属氧化物催化剂
公开(公告)号：KR1020020025715A
公开(公告)日：2002-04-04
申请号：KR1020010058681
申请日：2001-09-21
申请人： 롬 앤드 하스 캄파니
发明人： 보간레오나르드에드워드2세 , 헤프너미셀도린 , 자콥스브래들레이앤손 , 링크리차드데이빗3세 , 빅케리엘시메이
IPC分类号： B01J23/64 , B01J23/54 , B01J23/76 , B01J37/08
CPC分类号： C07C45/33 , B01J23/002 , B01J23/20 , B01J23/28 , B01J23/30 , B01J27/0576 , B01J37/0236 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C253/24 , Y02P20/52 , C07C47/22 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C255/08
摘要： PURPOSE: A process for preparing catalysts which are efficient in converting alkanes to unsaturated aldehydes and carboxylic acids, or in the presence of ammonia to unsaturated nitriles is provided. CONSTITUTION: In an improved process for preparing a catalyst including a compound having the formula AaVbNcXdOe wherein, when a = 1, b = 0.1 to 1, c = 0.1 to 1, d = 0.01 to 1 and e is dependent on the oxidation state of the other elements, and wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te, Se and Sb, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pd, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Ag, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm and Tb, the present invention comprises the steps of admixing metal compounds, at least one of which is an oxygen containing compound, and at least one solvent to form a solution; removing the solvent from the solution to obtain a catalyst precursor; and calcining the catalyst precursor to form above catalyst; wherein the improvement comprises: (A) admixing the metal compounds, at least one of which is an oxygen containing compound, and above at least one solvent to form a solution, (B) removing above at least one solvent from above solution to obtain a catalyst precursor, and (C) calcining said catalyst precursor at a temperature of at least 650deg.C in a non-oxidizing atmosphere to form a catalyst including a compound having the formula AaVbNcXdOe wherein, when a = 1, b = 0.1 to 1, c = 0.1 to 1, d = 0.01 to 1 and e is dependent on the oxidation state of the other elements, and wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te, Se and Sb, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pd, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Ag, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm and Tb.
摘要翻译：目的：提供一种制备有效将烷烃转化为不饱和醛和羧酸，或在氨存在于不饱和腈的催化剂的方法。组成：在一种制备包括具有式AaVbNcXdOe的化合物的催化剂的改进方法中，其中当a = 1时，b = 0.1至1，c = 0.1至1，d = 0.01至1，e取决于其他元素，其中A为选自Mo和W中的至少一种元素，N为选自Te，Se和Sb中的至少一种元素，X为选自以下的至少一种元素：由Nb，Ta，Ti，Al，Zr，Cr，Mn，Fe，Ru，Co，Rh，Ni，Pd，Pt，Bi，B，In，Ce，As，Ge，Sn，Li，Na，K组成的组，Rb，Cs，Fr，Be，Mg，Ca，Sr，Ba，Ra，Hf，Ag，Pb，P，Pm，Eu，Gd，Dy，Ho，Er，Tm，Yb，Lu，Au，Re，Pr ，Zn，Ga，Pd，Ir，Nd，Y，Sm和Tb，本发明包括将至少一种是含氧化合物的金属化合物和至少一种溶剂混合以形成溶液的步骤; 从溶液中除去溶剂，得到催化剂前体; 并煅烧催化剂前体以形成上述催化剂; 其中所述改进包括：（A）将金属化合物（其中至少一种为含氧化合物）和至少一种溶剂混合至至少一种溶剂以形成溶液，（B）从上述溶液中除去至少一种溶剂以获得催化剂前体，和（C）在至少650℃的温度下在非氧化气氛中煅烧所述催化剂前体以形成包含具有式AaVbNcXdOe的化合物的催化剂，其中当a = 1时，b = 0.1至1， c = 0.1〜1，d = 0.01〜1，e取决于其他元素的氧化态，其中A为选自Mo和W中的至少一种元素，N为选自由Te，Se和Sb组成的组，X是选自Nb，Ta，Ti，Al，Zr，Cr，Mn，Fe，Ru，Co，Rh，Ni，Pd，Pt中的至少一种元素，Bi，B，In，Ce，As，Ge，Sn，Li，Na，K，Rb，Cs，Fr，Be，Mg，Ca，Sr，Ba，Ra，Hf，Ag，Pb，P，Pm，Eu ，Gd，Dy，Ho，Er，Tm，Yb，Lu，Au，Re，Pr ，Zn，Ga，Pd，Ir，Nd，Y，Sm和Tb。

26. 发明公开

KR1020010067257A 산화반응에 유용한 촉매 有权
标题翻译：催化剂用于气相氧化烷烃，烷烃或醇向不饱和醛或羧酸中的氧化
公开(公告)号：KR1020010067257A
公开(公告)日：2001-07-12
申请号：KR1020000057220
申请日：2000-09-29
申请人： 롬 앤드 하스 캄파니
发明人： 린만후아
IPC分类号： B01J23/00
CPC分类号： C07C51/252 , B01J23/002 , B01J23/20 , B01J23/28 , B01J27/0576 , B01J35/0006 , B01J35/002 , B01J37/0236 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C45/39 , C07C51/215 , C07C51/235 , C07C51/25 , C07C47/21 , C07C47/22 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68
摘要： PURPOSE: A catalyst which is efficient in converting alkanes, alkenes, or alcohols to unsaturated aldehydes and acids, and a process for preparing unsaturated aldehydes and acids using the catalyst. CONSTITUTION: The catalyst is represented by the formula, AaMmNnXxOo, wherein 0.25
摘要翻译：目的：将烷烃，烯烃或醇转化为不饱和醛和酸有效的催化剂，以及使用催化剂制备不饱和醛和酸的方法。构成：催化剂由式AaMmNnXxOO表示，其中0.25

27. 发明公开

KR1020010067150A 알칸의 산화에 유용한 촉매 有权
标题翻译：催化剂用于氧化烷烃
公开(公告)号：KR1020010067150A
公开(公告)日：2001-07-12
申请号：KR1020000051951
申请日：2000-09-04
申请人： 롬 앤드 하스 캄파니
发明人： 한스코트 , 레도미니크헝누 , 맥닐네카나모나
IPC分类号： B01J23/64
CPC分类号： C07C45/33 , B01J21/06 , B01J21/066 , B01J23/002 , B01J23/20 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/31 , B01J27/053 , B01J27/0576 , B01J27/188 , B01J35/0006 , B01J2523/00 , C07C51/215 , C07C47/22 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/48 , B01J2523/69
摘要： PURPOSE: A catalyst which is efficient in converting alkanes to unsaturated aldehydes and carboxylic acids and a process for preparing unsaturated aldehydes and carboxylic acids using the catalyst. CONSTITUTION: A process for preparing a catalyst comprises (i) admixing metal compounds, at least one of which is an oxygen containing compound, and water to form an aqueous solution; (ii) removing the water from the aqueous solution to obtain a mixed metal oxide catalyst precursor; (iii) calcining the catalyst precursor at a temperature from 400 to 800 deg.C under an inert atmosphere; and (iv) admixing an acid selected from at least one of: (a) heteropolyacids, (b) aluminas, (c) zirconias, (d) titanias, (e) zeolites, and (f) acid combinations thereof; to form a catalyst including a mixed metal oxide having the formula: AaMmNnXxOo and the acid, wherein A is selected from Mo, W, and mixtures thereof; M is selected from V, Ce, Cr and mixtures thereof; N is selected from Te, Bi, Sb, and mixtures thereof; X is Nb, Ta, Zr, and mixtures thereof, and the acid is present at from 0.5 to 5 weight percent based on the total weight of the catalyst; 0.25
摘要翻译：目的：一种有效将烷烃转化为不饱和醛和羧酸的催化剂，以及使用该催化剂制备不饱和醛和羧酸的方法。构成：制备催化剂的方法包括（i）将至少一种是含氧化合物的金属化合物和水混合以形成水溶液; （ii）从水溶液中除去水，得到混合金属氧化物催化剂前体; （iii）在惰性气氛下在400-800℃的温度下煅烧催化剂前体; 和（iv）混合选自以下中的至少一种的酸：（a）杂多酸，（b）氧化铝，（c）锆石，（d）钛酸盐，（e）沸石和（f）其酸组合; 以形成包含具有下式的混合金属氧化物的催化剂：AaMmNnXxOo和酸，其中A选自Mo，W及其混合物; M选自V，Ce，Cr及其混合物; N选自Te，Bi，Sb及其混合物; X是Nb，Ta，Zr及其混合物，并且所述酸以所述催化剂总重量的0.5至5重量％存在; 0.25

28. 发明授权

KR1019890003702B1 텔루륨-함유 금속 산화물 촉매의 활성을 증진시키는 방법 失效
标题翻译：提高含碲金属氧化物催化剂活性的方法
公开(公告)号：KR1019890003702B1
公开(公告)日：1989-09-30
申请号：KR1019820002141
申请日：1982-05-15
申请人： 닛또 가가꾸 고오교 가부시끼가이샤
发明人： 유다까사사끼 , 유다까기요미야 , 도시오나까무라
IPC分类号： B01J27/30 , C07C121/32 , B01J27/02
CPC分类号： B01J27/0576 , C01C3/0216 , C01C3/0233 , C01C3/0241 , C07C5/48 , C07C253/26 , Y02P20/52 , Y02P20/584 , C07C11/167 , C07C255/08
摘要： An activity of a Te-contg. metal oxide catalyst is improved by heating the Te-contg. metal oxide catalyst of formula AaTebCcDcEeOx and a Te-contg. solid at 200-900≦̸C. In the formula, A is Sb, Mo or V; C is B, P, As, S or Se; D is Li, Na, K, Rb, Cs or Tl; E is Mg, Ca, Sr, Ba, Y, La, Ce, U, Ti, Zr, etc.; a is 10; b is 0.01-5; c is 0-10; d is 0-5; e is 0-60; x is the number of O corresp. to the oxides formed on combination. The Te-contg. solid is pref. Te, tellurium oxide, tellurium hydroxide or organic tellurium compound.
摘要翻译： Te-contg的活动通过加热Te-contg来改进金属氧化物催化剂。式AaTebCcDcEex的金属氧化物催化剂和Te-contg。固体在200-900＆amp; C; C。在该式中，A是Sb，Mo或V; C是B，P，As，S或Se; D是Li，Na，K，Rb，Cs或Tl; E是Mg，Ca，Sr，Ba，Y，La，Ce，U，Ti，Zr等; a是10 b为0.01-5; c为0-10; d为0-5; e为0-60; x是O对数的数量。与组合形成的氧化物。 Te-contg。固体是最好的。 Te，氧化碲，氢氧化碲或有机碲化合物。

29. 发明授权

KR101832542B1 분자 산소에 의한 올레핀의 올레핀 산화물로의 직접 전환 有权
标题翻译：通过分子氧直接将烯烃转化为烯烃氧化物
公开(公告)号：KR101832542B1
公开(公告)日：2018-02-26
申请号：KR1020137022149
申请日：2012-01-18
申请人： 스미또모 가가꾸 가부시끼가이샤
发明人： 세웁사이아누소른 , 센칸셀림 , 오이시요시히코 , 크납브헤렌카를로스구스타보
IPC分类号： C07D301/03 , B01J23/70
CPC分类号： B01J27/13 , B01J27/0576 , C07D301/03 , C07D301/08
摘要： 본발명은매우다양한가치있는소비자제품, 예컨대폴리우레탄발포체, 중합체, 알킬렌글리콜, 화장품, 식품유화제및 훈증약및 살충제의제조에사용되는중요하고다재다능한중간체인, 올레핀산화물로의올레핀의직접전환에관한것이다. 보다구체적으로, 본발명은할로겐화합물첨가제및 구리, 루테늄또는둘 모두를포함하는촉매의존재하에올레핀과산소를반응시키는것을포함하는올레핀산화물의제조방법을제공한다.
摘要翻译：到本发明的各种值的消费产品，例如聚氨酯泡沫体，聚合的，聚亚烷基二醇，化妆品，烯烃到食品乳化剂和熏蒸剂和重要和多用途的中间体，烯烃氧化物在杀虫剂的制备中使用的直接转换它涉及。更具体地，本发明提供一种制备烯烃氧化物，其包括在含有两个卤素化合物和添加剂铜，钌，或两者的催化剂的存在下使烯烃与氧气反应的方法。

30. 发明公开

KR1020170019128A 고성능 폴리옥소메탈레이트 촉매 및 이의 제조 방법 审中-实审
标题翻译：高性能多金属氧酸盐催化剂及其制备方法
公开(公告)号：KR1020170019128A
公开(公告)日：2017-02-21
申请号：KR1020150113111
申请日：2015-08-11
申请人： 주식회사 엘지화학
发明人： 최병렬 , 신현종 , 최영현 , 김덕기 , 임현섭 , 유효상
IPC分类号： B01J23/88 , B01J23/847 , B01J37/00 , C07C51/42
CPC分类号： B01J27/199 , B01J21/02 , B01J21/06 , B01J21/063 , B01J21/066 , B01J21/10 , B01J23/02 , B01J23/04 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/20 , B01J23/22 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/464 , B01J23/50 , B01J23/6525 , B01J23/6527 , B01J23/6562 , B01J23/686 , B01J23/687 , B01J23/688 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8878 , B01J23/8885 , B01J23/8898 , B01J23/8993 , B01J27/0576 , B01J27/14 , B01J35/08 , B01J37/0219 , B01J37/0221 , B01J37/0228 , B01J37/0232 , B01J2523/00 , C07C51/235 , B01J2523/17 , B01J2523/24 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/69 , B01J2523/72 , B01J2523/842 , C07C57/04
摘要： 본발명은고성능폴리옥소메탈레이트촉매및 이의제조방법에관한것으로, 본발명에따르면바나듐의함량등을조절하여촉매의활성및 선택도가향상되고, 재현성이우수할뿐 아니라, 고수율및 장수명으로불포화알데히드로부터불포화카르복실산을생산할수 있는고성능폴리옥소메탈레이트촉매및 이의제조방법등을제공하는효과가있다.
摘要翻译：本发明涉及一种高性能多金属氧酸盐催化剂及其制备方法。本发明具有以下效果：通过调整钒含量等可以提高活性和选择性的高性能多金属氧酸盐催化剂，其产率高，寿命长，再现性好，可产生不饱和的不饱和醛的羧酸; 及其制造方法。

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