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    • 20. 发明公开
    • 다공성 플라스틱 비드 물질
    • 大面积塑料珠材料
    • KR1020070114120A
    • 2007-11-29
    • KR1020077018152
    • 2005-11-08
    • 에보니크 룀 게엠베하
    • 멘츨러,스테판마이어,크리스티안렉크텐발트,로저슈바르츠-바락,사비네
    • C08F220/04C08F220/54C08F220/32C12N11/08
    • C08F2/18C08F222/385
    • The invention relates to a macroporous plastic bead material with a mean particle diameter of 10 to 1000 pm, radically polymerised from the following monomer types a) 5 - 40 wt. % vinylic polymerisable monomers with a water-solubility of at least 1% at 20°C, which are not vinylic polymerisable monomers with a quaternary amino group, b) 5 - 50 wt. % of vinylic polymerisable monomers with an additional functional group which can form covalent bonds on reaction with nucleophilic groups of ligands, c) 20 - 60 wt. % hydrophilic, cross-linking radically polymerisable monomers with two or more ethylenically-unsaturated polymerisable groups, characterised in that in addition d) 1 to 20 wt. % of a vinylic polymerisable monomer with a quaternary amino group are used for the polymer. The invention further relates to a method for production of the macroporous plastic bead material by inverse suspension polymerisation of monomer phase and uses thereof.
    • 本发明涉及一种平均粒径为10-1000μm的大孔塑料珠粒材料,其从以下单体类型自由基聚合a)5-40wt。 在20℃下水溶性至少为1%的乙烯基可聚合单体不是具有季氨基的乙烯基可聚合单体,b)5-50wt。 %的具有附加官能团的乙烯基可聚合单体,其可以与配体的亲核基团反应形成共价键,c)20-60wt。 具有两个或更多个烯键式不饱和可聚合基团的亲水性交联可自由基聚合单体,其特征在于另外d)1至20wt。 用于聚合物的具有季氨基的乙烯基可聚合单体的%。 本发明还涉及通过单体相的反相悬浮聚合及其用途来生产大孔塑料珠粒材料的方法。