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11. 发明公开

KR1020090113363A 압력 변동 정류에 의해 트리옥산／포름알데히드／물 혼합물로부터 트리옥산을 분리하는 방법 无效
标题翻译：通过压力变化方法从三氧化硅/甲醛/水混合物中分离三氧化二锑的方法
公开(公告)号：KR1020090113363A
公开(公告)日：2009-10-30
申请号：KR1020097015612
申请日：2008-01-23
申请人： 바스프 에스이
发明人： 랑,네펜 , 틸,요아힘 , 슈트뢰퍼,에크하르트 , 키르쉬바움,율리아 , 지게르트,마르쿠스
IPC分类号： B01D3/14 , C07D323/06
CPC分类号： C07D323/06 , B01D3/146 , B01D3/148
摘要： The invention relates to a method for separating trioxane from an inlet flow (I) consisting of formaldehyde, trioxane and water. Said method consists in a) preparing an inlet flow (I), which contains formaldehyde as the main component and trioxane and water as auxiliary components, b) feeding the inlet flow (I), a return flow (V) and a return flow (VII), containing formaldehyde as the main component and trioxane and water auxiliary components, into a first distillation step and distilling it at a pressure of between 0.1 to 2.5 bars, thus enabling a flow (II), which contains formaldehyde as the main component and water as the auxiliary component, and a flow (III), which contains trioxane as the main component and water and formaldehyde as the auxiliary components, and a flow (X), which contains water, trioxane and formaldehyde to be obtained, c) distilling the flow (III), optionally after separating materials at a low-boiling point from the flow (III) in a low-boiling separation step and in a second distillation step at a pressure of between 0.2 to 17. 5 bars, whereby the pressure in the second distillation step is 0.1 to 15 bars higher that the pressure in the first distillation step. A flow (IV) is obtained which is essentially made of trioxane, and also a return flow (V), which contains trioxane as the main component and water and formaldehyde as the auxiliary components, d) feeding the flow (X) and optionally a flow (IX), which contains water as the main component, into a third distillation step and distilling it at a pressure of between 1 to 10 bars, whereby a flow (VI), which is essentially made of water, and a return flow (VII), which contains formaldehyde as the main component and water and trioxane as the auxiliary components, are obtained.
摘要翻译：本发明涉及从甲醛，三恶烷和水组成的入口流（I）分离三恶烷的方法。所述方法包括：a）制备以甲醛为主要成分的入口流（I），以及三恶烷和水为辅助成分，b）进料入口流（I），回流（V）和回流 VII），其以甲醛为主要成分和三恶烷和水辅助成分，分成第一蒸馏步骤，并在0.1至2.5巴之间的压力下蒸馏，从而使得能够含有甲醛作为主要成分的流动（II）和水作为辅助成分，含有三恶烷作为主要成分的水（III）和作为辅助成分的水和甲醛，以及含有水，三恶烷和甲醛的流动（X），c）蒸馏流动（III），任选地在低沸点分离步骤和第二蒸馏步骤中在低于沸点（III）的沸点下在0.2至17.5巴之间的压力下分离材料，由此压力在第二蒸馏步骤中比第一蒸馏步骤中的压力高0.1至15巴。获得基本上由三恶烷制成的流动（IV），以及含有三恶烷作为主要成分的回流（V），以及作为辅助成分的水和甲醛，d）进料流（X）和任选的以水为主要成分的流（Ⅸ）进入第三蒸馏步骤，并在1至10巴之间的压力下蒸馏，由此基本上由水制成的流动（VI）和回流（ VII），其中含有甲醛作为主要成分，并以水和三恶烷为辅助成分。

12. 发明公开

KR1020080033364A 포름알데히드로부터 트리옥산의 통합 제조 방법 无效
标题翻译：用于从甲醛生产三氧化二铁的综合方法
公开(公告)号：KR1020080033364A
公开(公告)日：2008-04-16
申请号：KR1020087003041
申请日：2006-08-01
申请人： 바스프 에스이
发明人： 랑,네펜 , 스트뢰퍼,에크하르트 , 스타머,아힘 , 프리제,토르스텐 , 시게르트,마르쿠스 , 하세,한스 , 그뤼츠너,토마스 , 블라고프,세르게이
IPC分类号： C07D323/06
CPC分类号： C07D323/06 , Y02P20/125
摘要： The invention relates to an integrated method for producing trioxane from formaldehyde. According to said method, a flow A1 containing water and formaldehyde as well as a recirculation flow B2 substantially composed of water and formaldehyde are delivered to a trioxane synthesis reactor in which the formaldehyde is reacted to trioxane such that a product flow A2 containing trioxane, water, and formaldehyde is obtained. Flow A2 and a recirculation flow D1 containing trioxane, water, and formaldehyde are fed to a first distillation column and are distilled at a pressure ranging from 0.1 to 2.5 bar such that a trioxane-enriched flow B1 and flow B2, which is essentially composed of water and formaldehyde, are obtained. Flow B1 is delivered to a second distillation column and is distilled at a pressure ranging from 0.2 to 17.5 bar such that a product flow substantially comprising trioxane and a flow C1 containing trioxane, water, and formaldehyde are obtained. Flow C1 is fed to a third distillation column and is distilled at a pressure ranging from 1 to 10 bar such that the recirculation flow D1 containing trioxane, water, and formaldehyde as well as a flow D2 that is substantially composed of water are obtained.
摘要翻译：本发明涉及从甲醛生产三恶烷的综合方法。根据所述方法，将含有水和甲醛的流动A1以及基本上由水和甲醛组成的再循环流B2输送到三恶烷合成反应器，其中甲醛与三恶烷反应，使得含有三恶烷的产物流A2，水，得到甲醛。将流动A2和含有三恶烷，水和甲醛的再循环流D1加入到第一蒸馏塔中，并在0.1至2.5巴的压力下蒸馏，使得富含三恶烷的流B1和流B2基本上由水和甲醛。将流量B1输送到第二蒸馏塔，并在0.2至17.5巴的压力下蒸馏，使得获得基本上包含三恶烷的产物流和含有三恶烷，水和甲醛的流动C1。将流C1加入到第三蒸馏塔中并在1至10巴的压力下蒸馏，从而获得含有三恶烷，水和甲醛的再循环流D1以及基本上由水组成的流动D2。

13. 发明公开

KR1020080033363A 포름알데히드로부터 트리옥산의 통합 제조 방법 无效
标题翻译：用于从甲醛生产三氧化二铁的综合方法
公开(公告)号：KR1020080033363A
公开(公告)日：2008-04-16
申请号：KR1020087003039
申请日：2006-08-04
申请人： 바스프 에스이
发明人： 랑,네펜 , 스트뢰퍼,에크하르트 , 스타머,아힘 , 프리제,토르스텐 , 시게르트,마르쿠스 , 하세,한스 , 그뤼츠너,토마스 , 블라고프,세르게이
IPC分类号： C07D323/06
CPC分类号： C07D323/06 , Y02P20/125
摘要： The invention relates to an integrated method for producing trioxane from formaldehyde. According to said method, a flow A1 containing water and formaldehyde and a return flow B2 consisting essentially of water and formaldehyde are introduced into a trioxane synthesis reactor in which the formaldehyde is converted into trioxane, forming a product flow A2 containing trioxane, water and formaldehyde; the flow A2 is introduced into a first distillation column and distilled at a pressure of between 0. 1 and 2.5 bar, forming a trioxane-enriched flow B1 and the flow B2 consisting essentially of water and formaldehyde; the flow B1 and a return flow D1 containing trioxane, water and formaldehyde are introduced into a second distillation column and distilled at a pressure of between 0.2 and 17.5 bar, forming a product flow C2 consisting essentially of trioxane and a flow C1 containing trioxane, water and formaldehyde; and the flow C1 is introduced into a third distillation column and distilled at a pressure of between 0.1 and 2.5 bar, forming the return flow D1 containing trioxane, water and formaldehyde and a flow D2 consisting essentially of water and formaldehyde.
摘要翻译：本发明涉及从甲醛生产三恶烷的综合方法。根据所述方法，将含有水和甲醛的流动A1和基本上由水和甲醛组成的回流B2引入三氧化硅合成反应器中，其中甲醛被转化成三恶烷，形成含有三恶烷，水和甲醛的产物流A2 ; 将流动A2引入第一蒸馏塔并在0.1至2.5巴之间的压力下蒸馏，形成富含三恶烷的流量B1和基本上由水和甲醛组成的流量B2; 将流动B1和含有三恶烷，水和甲醛的回流D1引入第二蒸馏塔中并在0.2至17.5巴之间的压力下蒸馏，形成基本上由三恶烷组成的产物流C2和含有三恶烷的流C1，水和甲醛; 并且将流C1引入第三蒸馏塔并在0.1至2.5巴之间的压力下蒸馏，形成含有三恶烷，水和甲醛的回流流D1和基本上由水和甲醛组成的流动D 2。

14. 发明公开

KR1019990007906A 트리옥산의제조방법 失效
标题翻译：三恶烷的制备方法
公开(公告)号：KR1019990007906A
公开(公告)日：1999-01-25
申请号：KR1019970707429
申请日：1996-04-22
申请人： 폴리플라스틱스 가부시키가이샤
发明人： 가시하라오사무 , 아키야마미노루
IPC分类号： C07D323/06
摘要： 장기간 동안 안정한 운행을 허용하는, 고체 산의 존재하에 포름알데히드 수용액으로부터 트리옥산을 제조하기 위한 실용적이고 경제적인 방법을 제공하는 것이다.
포름 알데히드 수용액으로부터 트리옥산을 제조하는 방법은 이온교환능을 갖는 물질을 사용하여 포름알데히드 수용액으로부터 주로 금속 불순물을 제거하는 제 1 기능 공정, 및 고체 산 촉매를 사용하여 금속 불순물이 제거되어진 포름알데히드 수용액으로부터 주로 트리옥산을 합성하는 제 2 기능 공정인, 2가지 기능 공정을 포함하는 장치를 사용하여 실시된다.

15. 发明公开

KR1019940018377A 트리옥산의 제조방법 无效
标题翻译：三恶烷的制备方法
公开(公告)号：KR1019940018377A
公开(公告)日：1994-08-16
申请号：KR1019940000137
申请日：1994-01-06
申请人： 훽스트 게엠베하
发明人： 게르하르트에미크 , 벤노크뤼거 , 프랑크케른 , 미카엘호프모켈 , 칼-프리드리히뮈크 , 귄터젝스트로
IPC分类号： C07D323/06
摘要： 기체 상의 포름알데히드로부터 촉매의 존재하에 트리옥산을 제조하는 방법이 기술되어 있으며, 여기에서 사용되는 촉매는 11-몰리브도-1-바나도인산, H
4 PVM
110 ·nH
2 O(n=0 내지 32)이다.
이 방법의 잇점은 특히 높은 공간- 시간 수율 및 부산물 생성의 억제이다.

16. 发明公开

KR1019940014379A 트리옥산의 제조 방법 无效
标题翻译：三恶烷的制备方法
公开(公告)号：KR1019940014379A
公开(公告)日：1994-07-18
申请号：KR1019930031220
申请日：1993-12-30
申请人： 훽스트 게엠베하
发明人： 게르하르트에미크 , 벤노크뤼거 , 프랑크케른 , 미카엘호프목켈 , 칼-프리드리히윅크 , 귄터젝스트로
IPC分类号： C07D323/06
摘要： 기상으로 포름알데히드로부터 트리옥산을 촉매적으로 제조하는 본 발명의 방법은 스팀에 의해 활성화되거나 활성화될 수 없는 바나딜 인산수소·1/2수화물을 포함하는 촉매를 사용한다.
본 방법은 부산물이 없으며 공간-시간 수율이 높다. 반응기내 침착물도 존재하지 않는다.

17. 发明公开

KR1020140106599A 이종 반응 시스템에서 환상 아세탈의 제조 방법 审中-实审
标题翻译：在异构反应体系中生产循环乙醇的方法
公开(公告)号：KR1020140106599A
公开(公告)日：2014-09-03
申请号：KR1020147017191
申请日：2012-11-23
申请人： 셀라니즈 세일즈 저머니 게엠베하
发明人： 하웁스미카엘 , 페오르드다미안 , 조니 , 쿠르츠클라우스 , 링나우위르겐
IPC分类号： C07D323/06
CPC分类号： C07D323/06 , C07C47/04 , C07D323/04 , C08G2/10 , C08G2/36 , C08G65/06 , C08G65/16 , C08G65/30 , C08G2650/62 , C08J11/16 , C08J11/28 , C08J2359/02 , Y02P20/125
摘要： 본 발명은 환상 아세탈의 제조 방법에 관한 것이다. 상기 방법에 따라, 폼알데하이드 공급원을 비양성자성 화합물과 배합하고 이종 촉매와 접촉시키며, 이는 상기 폼알데하이드 공급원을 트라이옥산과 같은 환상 아세탈로 전환되게 한다. 상기 촉매는 예를 들어 고체 촉매, 예를 들어 이온 교환 수지를 포함할 수 있다. 하나의 실시태양에서, 상기 방법을 무수 폼알데하이드 기체의 트라이옥산으로의 전환에 사용한다. 상기 무수 폼알데하이드 기체는 추출 증류에 의해 수성 폼알데하이드 용액으로부터 생성될 수 있다.
摘要翻译：本发明涉及一种制备环状缩醛的方法，其包括：i）制备液体反应混合物，其包含a）甲醛源，b）非质子化合物和c）催化剂; 其中基于反应混合物的总重量，质子化合物的总量小于40重量％; 和ii）将甲醛源转化为环状缩醛。

18. 发明授权

KR101092199B1 1.3,5―트리옥산의 제조방법 有权
标题翻译：制备1,3,5-三氯乙烯的方法
公开(公告)号：KR101092199B1
公开(公告)日：2011-12-09
申请号：KR1020100107121
申请日：2010-10-29
申请人： 코오롱플라스틱 주식회사
发明人： 조인기 , 최진상 , 강경민
IPC分类号： C07D323/06 , B01D3/40
CPC分类号： C07D323/06 , A61K9/0014 , B01D3/009 , Y02P20/127
摘要： PURPOSE: A method for preparing 1,3,5-trioxane using a reactive distillation column is provided to reflux 1,3,5-trioxane extraction and to prevent eduction of paraformaldehyde. CONSTITUTION: A method for preparing 1,3,5-trioxane using a reactive distillation column comprises a step of recirculating a phase-separated aqueous phase(a) to a distillation unit and an extraction unit. The aqueous phase is isolated a first aqueous phase(a1) recirculated to the distillation unit and a second aqueous phase(a2) recirculated to the extraction unit.
摘要翻译：目的：提供使用反应蒸馏塔制备1,3,5-三恶烷的方法，用于回流1,3,5-三恶烷萃取并防止多聚甲醛的引发。构成：使用反应蒸馏塔制备1,3,5-三恶烷的方法包括将相分离的水相（a）再循环到蒸馏单元和萃取单元的步骤。水相分离出再循环到蒸馏单元的第一水相（a1）和再循环到萃取单元的第二水相（a2）。

19. 发明公开

KR1020090029258A 포름알데히드로부터 트리옥산의 통합 제조 방법 有权
标题翻译：用于从甲醛制备三氧化二铁的综合方法
公开(公告)号：KR1020090029258A
公开(公告)日：2009-03-20
申请号：KR1020097000464
申请日：2007-06-11
申请人： 바스프 에스이
发明人： 지게르트,마르쿠스 , 랑,네펜 , 스트뢰퍼,에크하르트 , 지크바르트,크리스토프
IPC分类号： C08G2/10 , C08G8/08 , C07D323/06
CPC分类号： C07D323/06 , Y02P20/125
摘要： Integrated method for the preparation of trioxane from formaldehyde, comprising the steps: a) introduction of a feeding flow A1 containing formaldehyde and water and a return flow B3 consisting essentially of formaldehyde and trioxane into a formaldehyde concentration unit, wherein said flows are separated into a formaldehyde-rich flow A2 and a flow A3 consisting essentially of water; b) introduction of a product flow C1, containing trioxane, water, and formaldehyde, a return flow E1 containing trioxane, water, and formaldehyde, and possibly flow A2 into a first low-pressure distillation column, wherein said flows are distilled at a pressure of from 0.1 to 1.5 atmospheres, with a trioxane-enriched flow B1 containing predominantly trioxane, and also water and formaldehyde, a slough removal flow B2 consisting essentially of formaldehyde and water, and the return flow B3 containing predominantly water, and also formaldehyde and trioxane removed as a side removal flow; c) introduction of a slough removal flow B2 and possibly the flow A2 into a trioxane synthesis reactor, wherein said flows are allowed to react, and wherein the flow C1 containing trioxane, water, and formaldehyde is obtained; d) introduction of a flow B1 into a mid-pressure distillation column, wherein said flow is distilled at a pressure of from 1.0 to 3.0 atmospheres, wherein a low boiler stream D1 containing methanol, methylal, and methylformate,and a stream D2 containing predominantly trioxane and also formaldehyde and water are obtained; e) introduction of a stream D2 into a high-pressure distillation column, wherein said stream is distilled at a pressure of from 2.5 to 10.0 atmospheres, wherein the return flow E1 contains trioxane, water, and formaldehyde, and a product flow E2 consisting essentially of trioxane is obtained; wherein flow A2 can be introduced into either the low-pressure distillation column or into the trioxane-35 synthesis reactor, or into both.
摘要翻译：一种由甲醛制备三恶烷的综合方法，包括以下步骤：a）将含有甲醛和水的进料流A1和基本上由甲醛和三恶烷组成的回流B3引入甲醛浓缩装置，其中所述流分离成富甲醛流A2和基本上由水组成的流量A3; b）引入含有三恶烷，水和甲醛的产物流C1，含有三恶烷，水和甲醛的回流E1和可能的流A2到第一低压蒸馏塔，其中所述流在压力下蒸馏具有主要为三恶烷的三恶烷富集流B1以及水和甲醛，基本上由甲醛和水组成的脱水除去流B2以及主要含水的回流B3以及甲醛和三恶烷作为侧面去除流除去; c）将脱脂流B2和可能的流A2引入三恶烷合成反应器中，其中使所述流动反应，并且其中得到含有三恶烷，水和甲醛的流C1; d）将流B1引入中压蒸馏塔，其中所述流在1.0至3.0大气压的压力下蒸馏，其中含有甲醇，甲缩醛和甲酸甲酯的低沸点物流D1和主要含有得到三恶烷，还得到甲醛和水; e）将料流D2引入高压蒸馏塔中，其中所述料流在2.5至10.0大气压的压力下蒸馏，其中回流E1包含三恶烷，水和甲醛，产物流E2基本上组成得到三恶烷; 其中流动A2可以被引入低压蒸馏塔或三恶烷-35合成反应器中，或两者进入。

20. 发明公开

KR1020080075126A 트리옥산 및 1종 이상의 공단량체의 제조 방법 无效
标题翻译：生产三氧化物和至少一个人的过程
公开(公告)号：KR1020080075126A
公开(公告)日：2008-08-14
申请号：KR1020087013040
申请日：2006-10-27
申请人： 바스프 에스이
发明人： 랑,네벤 , 뵈링,랄프 , 스타머,아힘 , 올덴부르크,얀 , 지게르트,마르쿠스 , 스트뢰퍼,에크하르트
IPC分类号： C08G2/10 , C07D317/12 , C07D319/00 , C07D323/06
CPC分类号： C08G2/10 , C07D317/12 , C07D323/06 , C08G2/20 , Y02P20/127 , Y02P20/582
摘要： The invention relates to a process for producing trioxane and at least one comonomer for producing (co)polymers on a trioxane basis, in which, in a first step, formaldehyde and at least one comonomer starting material are reacted in aqueous solution to form trioxane and comonomer, wherein a reaction mixture A1 containing trioxane, comonomer, formaldehyde, water and if appropriate comonomer starting material is obtained. In a second step, the reaction mixture A1 is distilled in a first distillation stage at a first pressure, wherein a trioxane-and comonomer-enriched stream B1 and an essentially water-, formaldehyde-and if appropriate comonomer starting material-containing stream B2 are obtained. In a third step, the stream B1 is distilled in a second distillation stage at a pressure which is above the pressure of the first distillation stage, wherein a trioxane-, comonomer-and water-containing stream C1 and a product stream C2 essentially consisting of comonomer and trioxane are obtained.
摘要翻译：本发明涉及三恶烷和至少一种用于在三恶烷基上制备（共）聚合物的共聚单体的方法，其中在第一步中，甲醛和至少一种共聚单体原料在水溶液中反应形成三恶烷，共聚单体，其中获得含有三恶烷，共聚单体，甲醛，水和如果合适的共聚单体原料的反应混合物A1。在第二步骤中，反应混合物A1在第一压力下在第一蒸馏阶段进行蒸馏，其中富含三恶烷和共聚单体的料流B1和基本上水，甲醛和如果合适的共聚单体起始原料流B2是获得。在第三步骤中，在高于第一蒸馏阶段的压力的压力下，在第二蒸馏阶段蒸馏料流B1，其中三恶烷，共聚单体和含水流C1和基本上由共聚单体和三恶烷。

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