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11. 发明公开

KR1020110063623A 신규의 양쪽친화성 화합물, 이의 제조 방법, 및 이를 포함하는 염료를 이용한 염료감응 태양전지 无效
标题翻译：新型水性化合物，使用包含化合物的染料制备化合物和染料敏化太阳能电池的方法
公开(公告)号：KR1020110063623A
公开(公告)日：2011-06-13
申请号：KR1020110049488
申请日：2011-05-25
申请人： 고려대학교 산학협력단
发明人： 고재중 , 김점종
IPC分类号： C07F15/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , C07F15/0053 , C09B57/10 , H01G9/2059
摘要： PURPOSE: A novel amphiphilic compound is provided to improve Jsc value and to ensure excellent efficiency. CONSTITUTION: An amphiphilic compound is denoted by chemical formula 1. The compound of chemical formula 2 is prepared by successively reacting a compound of chemical formula 21, a compound of chemical formula 22, and a compound of chemical formula 23 to a compound of chemical formula 20. A dye sensitive solar cell comprises: a conductive substrate, a semiconductor electrode which is formed on the conductive substrate and contains a dye-adsorbed metal oxide layer; a opposite electrode; and an electrolyte solution filled between the semiconductor electrode and opposite electrode.
摘要翻译：目的：提供一种新型的两亲化合物，以提高Jsc值并确保优异的效率。构成：化学式1表示两亲性化合物。化学式2的化合物通过将化学式21的化合物，化学式22的化合物和化学式23的化合物连续反应到化学式 20.一种染料敏感性太阳能电池，包括：导电性基板，形成在所述导电性基板上并含有染料吸附金属氧化物层的半导体电极; 相对电极以及填充在半导体电极和相对电极之间的电解质溶液。

12. 发明公开

KR1020100127474A 신규의 퓨즈드-트리아릴아민을 함유하는 화합물, 이의 제조 방법, 및 이를 포함하는 염료를 이용한 염료감응 태양전지 有权
标题翻译：包含熔融三胺的新型化合物，使用包含化合物的染料制备化合物和染料敏化太阳能电池的方法
公开(公告)号：KR1020100127474A
公开(公告)日：2010-12-06
申请号：KR1020090045931
申请日：2009-05-26
申请人： 고려대학교 산학협력단
发明人： 고재중 , 김덕현 , 최현봉
IPC分类号： C07D409/02 , C07D409/08 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , C07D471/14 , H01L31/04
摘要： PURPOSE: A compound containing fused-triarylamine and dye-sensitive solar cell containing the same are provided to absorb light of various wave lengths and to prevent aggregation of dye. CONSTITUTION: A compound contains fused-triarylamine of chemical formula 1. The compound having fused-triarylamine is prepared by reacting a compound of chemical formula 13 or compound of chemical formula 14 or 15 to form a compound of chemical formula 16 and preparing a compound of chemical formula 17. A dye-sensitive solar cell comprises: a conductive substrate; a semiconductor electrode having a metal oxide layer in which dye containing the compound of chemical formula 1 is adsorbed; an opposing electrode; and an electrolyte solution filling between the semiconductor electrode and opposing electrode.
摘要翻译：目的：提供含有熔融三芳基胺和含有它们的感光太阳能电池的化合物以吸收各种波长的光并防止染料聚集。构成：化合物含有化学式1的稠合三芳基胺。具有稠合三芳基胺的化合物是通过使化学式13的化合物或化学式14或化合物15化合物反应形成化学式16的化合物并制备化合物化学式17.染料敏感的太阳能电池包括：导电基底; 具有含有化学式1的化合物的染料被吸附的金属氧化物层的半导体电极; 相对电极; 以及填充在半导体电极和相对电极之间的电解质溶液。

13. 发明公开

KR1020100125064A 나노입자에 염료를 흡착시키는 방법, 이를 이용한 염료감응 태양전지 제조방법 및 염료감응 태양전지 有权
标题翻译：在纳米粒子上吸附染料的方法，使用该方法制造使用其的透明致密的太阳能电池的方法和由其制造的透明的太阳能电池
公开(公告)号：KR1020100125064A
公开(公告)日：2010-11-30
申请号：KR1020090044077
申请日：2009-05-20
申请人： 고려대학교 산학협력단
发明人： 고재중 , 최현봉 , 김덕현
IPC分类号： B82B3/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , B82B3/00 , H01L31/04
摘要： PURPOSE: An adsorbing method of a dye to a nanoparticle, a manufacturing method of a dye-sensitized solar cell using thereof, and the dye-sensitized solar cell are provided to prevent the aggregation of the dye and the recombination of an electron by a macrocycle molecule. CONSTITUTION: An adsorbing method of a dye to a nanoparticle comprises the following steps: adsorbing a macrocycle molecule with a ring form molecule structure to the surface of the nanoparticle; and adsorbing the dye to the surface of the nanoparticle adsorbed with the macrocycle molecule. The inside of the ring form molecule structure of the macrocycle molecule is hydrophobic.
摘要翻译：目的：提供染料对纳米颗粒的吸附方法，其使用的染料敏化太阳能电池的制造方法和染料敏化太阳能电池，以防止染料的聚集和大环化合物的电子复合分子。构成：染料对纳米颗粒的吸附方法包括以下步骤：将具有环形分子结构的大环分子吸附到纳米颗粒的表面; 并将染料吸附到吸附有大分子分子的纳米颗粒表面。大环分子的环形分子结构的内部是疏水性的。

14. 发明公开

KR1020100121204A 신규의 양쪽친화성 화합물, 이의 제조 방법, 및 이를 포함하는 염료를 이용한 염료감응 태양전지 失效
标题翻译：新型水性化合物，使用包含化合物的染料制备化合物和染料敏化太阳能电池的方法
公开(公告)号：KR1020100121204A
公开(公告)日：2010-11-17
申请号：KR1020090040255
申请日：2009-05-08
申请人： 고려대학교 산학협력단
发明人： 고재중 , 김점종
IPC分类号： C07F15/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , C07F15/0053 , C09B57/10 , H01G9/2059
摘要： PURPOSE: A novel amphiphilic compound is provided to improve Jsc value and to absorb other wave length. CONSTITUTION: An amphiphilic compound is denoted by chemical formula 1. In chemical formula 1, R1 is alkyl of 1-20 carbon atoms, phenyl, and alkyl phenyl of 1-20 carbon atoms; and R2 and R3 are selected from hydrogen, alkyl of 1-20 carbon atoms, and alkyloxy of 1-20 carbon atoms. The amphiphilic compound is prepared by reacting compounds of chemical formulas 21, 22, and 23 with a compound of chemical formula 20. A dye-sensitive solar cell comprises: a conductive substrate, semiconductive electrode; and an electrolyte solution filling between the semicondutive electrode.
摘要翻译：目的：提供一种新型的两亲化合物来提高Jsc值并吸收其他波长。构成：化学式1表示两亲性化合物。在化学式1中，R 1为1-20个碳原子的烷基，苯基和1-20个碳原子的烷基苯基; R2和R3选自氢，1-20个碳原子的烷基和1-20个碳原子的烷氧基。通过使化学式21,22和23的化合物与化学式20的化合物反应制备两亲化合物。染料敏感的太阳能电池包括：导电基底，半导体电极; 以及在半电极之间填充的电解质溶液。

15. 发明公开

KR1020080103683A 신규한 줄로리딘계 염료 및 이의 제조방법 失效
标题翻译：新型基于乳糖的染色体及其制备方法
公开(公告)号：KR1020080103683A
公开(公告)日：2008-11-28
申请号：KR1020070050701
申请日：2007-05-25
申请人： 주식회사 동진쎄미켐 , 고려대학교 산학협력단
发明人： 이종찬 , 배호기 , 백종협 , 고재중 , 최현봉
IPC分类号： C09B49/00
CPC分类号： C09B57/00 , C09B23/005 , C09B23/0058 , C09B23/105 , H01L31/04
摘要： A julolidine-based dye and a preparation method thereof are provided to improve the efficiency of a solar battery and to improve molar extinction coefficient and a photoelectricity conversion efficiency compared with a conventional metal complex dye. A julolidine-based dye is represented by the chemical formula 1. In the chemical formula 1, R1 and R2, are independently, hydrogen, C1-12 alkyl or C1-12 alkoxy wherein R1 and R2 can form an oxygen-containing hetero ring in case of C1-12 alkoxy; and n is an integer of 2-5, wherein arbitrarily, two or more of thiophene units can be connected to a vinyl group.
摘要翻译：为了提高太阳能电池的效率，与以往的金属络合物染料相比，提供了一种高乐宁碱系染料及其制备方法，提高了摩擦消光系数和光电转换效率。在化学式1中，R 1和R 2独立地为氢，C 1-12烷基或C 1-12烷氧基，其中R 1和R 2可以形成含氧杂环， C1-12烷氧基的情况; n为2-5的整数，其中任意地，可以将两个以上的噻吩单元连接到乙烯基上。

16. 发明授权

KR101267658B1 염료감응 태양전지용 염료, 이의 제조방법 및 이를 포함하는 염료 감응태양 전지 有权
标题翻译：用于透明的SOLARCELL的DYE，其制备方法和包含其的透明的太阳能电池
公开(公告)号：KR101267658B1
公开(公告)日：2013-05-27
申请号：KR1020110065065
申请日：2011-06-30
申请人： 고려대학교 산학협력단
发明人： 고재중 , 임기민
IPC分类号： C09B62/503 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521
摘要： 본발명은염료감응태양전지용염료및 이로부터제조된염료감응태양전지에관한것으로, 상기염료는플루오레닐기및 인데노[1,2-b]티오펜(indeno[1,2-b]thiophene)기함유화합물을포함한다. 본발명의염료감응태양전지용염료는태양전지용광흡수층에적용되어태양전지의광전전류변환효율을개선시키고개방전압을상승시킬수 있다.

17. 发明公开

KR1020130007287A 염료감응 태양전지용 염료, 이의 제조방법 및 이를 포함하는 염료 감응태양 전지 有权
标题翻译：用于透明的SOLARCELL的DYE，其制备方法和包含其的透明的太阳能电池
公开(公告)号：KR1020130007287A
公开(公告)日：2013-01-18
申请号：KR1020110065065
申请日：2011-06-30
申请人： 고려대학교 산학협력단
发明人： 고재중 , 임기민
IPC分类号： C09B62/503 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , C09B49/126 , C07C211/54 , C07D333/10 , H01G9/2059 , H01L31/042
摘要： PURPOSE: A dye for a dye-sensitized solar cell is provided to improve photo-electric conversion efficiency and increase open voltage when applied to a light absorption layer for a solar cell. CONSTITUTION: A dye for a dye-sensitized solar cell comprises a compound indicated in chemical formula 1. In chemical formula 1, each of A and B is selected from a substituted or unsubstituted hydrocarbon, substituted or unsubstituted aromatic rings and combinations thereof. In chemical formula 1, each of A and B is selected from a substituted or unsubstituted aromatic hydrocarbon, a substituted or unsubstituted aromatic rings, and combinations thereof, A and/or B is a fluorenyl group, C is an indeno[1,2-b]thiophene group, and E is an acidic group. A dye-sensitized solar cell comprises a first electrode which comprises a conductive transparent substrate, a light-absorbing layer formed on one side of the first electrode, a second electrode arranged to face the first electrode; and an electrolyte arranged between the electrodes. The light-absorbing layer comprises a semiconductor particle and the dye.
摘要翻译：目的：提供用于染料敏化太阳能电池的染料，以在施加到太阳能电池的光吸收层时提高光电转换效率和增加开路电压。构成：用于染料敏化太阳能电池的染料包括化学式1所示的化合物。在化学式1中，A和B各自选自取代或未取代的烃，取代或未取代的芳族环及其组合。在化学式1中，A和B各自选自取代或未取代的芳族烃，取代或未取代的芳族环及其组合，A和/或B是芴基，C是茚并[1,2- b]噻吩基团，E为酸性基团。染料敏化太阳能电池包括第一电极，其包括导电透明基板，形成在第一电极的一侧上的光吸收层，布置成面对第一电极的第二电极; 和布置在电极之间的电解质。光吸收层包含半导体颗粒和染料。

18. 发明授权

KR101173658B1 염료감응 태양전지용 스쿠아레인계 염료 有权
标题翻译：染料敏化太阳能电池用Squaraine染料
公开(公告)号：KR101173658B1
公开(公告)日：2012-08-14
申请号：KR1020100104147
申请日：2010-10-25
申请人： 고려대학교 산학협력단
发明人： 고재중 , 백상현 , 최현봉 , 김철우
IPC分类号： C09B57/00 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521
摘要： 본 발명은 염료감응 태양전지용 스쿠아레인계 염료에 관한 것으로 본 발명의 스쿠아레인계 염료는 인돌(indole) 그룹 및 피롤(pyrrole) 그룹을 도입함으로써 780 nm 까지의 전색성의 빛을 수집할 수 있으며, 염료감응 태양전지에 사용되어 종래의 유기염료보다 향상된 단회로 광전류 밀도(J
sc ), 광전변환효율(η) 및 장기간 안정성을 나타내어 그린 하우스 또는 BIPV와 같은 태양광 창에 이용이 가능하다.

19. 发明公开

KR1020120035696A 염료감응 태양전지용 루테늄계 염료 有权
标题翻译：用于染色敏感的太阳能电池的红外线
公开(公告)号：KR1020120035696A
公开(公告)日：2012-04-16
申请号：KR1020100097381
申请日：2010-10-06
申请人： 고려대학교 산학협력단
发明人： 고재중 , 김점종 , 임기민
IPC分类号： C09B57/10 , C09B45/12 , H01L31/04
CPC分类号： Y02E10/542 , Y02P70/521 , C09B57/10 , C07D401/14 , C07F15/0053 , H01G9/2059 , H01L31/04
摘要： PURPOSE: A ruthenium-based dye for dye-sensitized solar battery is provided to have excellent molar light absorption coefficient, short circuit photoelectricity density(Jsc), photoelectricity converting efficiency, and long time stability because of the intrinsic stability of a ruthenium composite cyclic metalized by C-N-N ligand, and red-shifted light absorption properties. CONSTITUTION: A manufacturing method of a ruthenium-based dye comprises: a step of manufacturing a compound in chemical formula 4 by reacting a compound in chemical formula 3 with m-chloroperoxybenzoic acid; a step of manufacturing a compound in chemical formula 5 by reacting the compound in chemical formula 4 with POClO3; a step of manufacturing a compound in chemical formula 6 by reacting the compound in chemical formula 5 with 2,4- difluorophenylboric acid pinacol ester or 2,4-- dichlorophenylboronic acid pinacol ester; a step of manufacturing a compound in chemical formula 7 by reacting the compound in chemical formula 6 with methanol and potassium hydroxide; and a step of manufacturing a compound in chemical formula 1 by reacting the compound in chemical formula 7 with Ru(Cl)2(p-cymene)]2, a compound in chemical formula 8, and ammonium thiocyanate in order.
摘要翻译：目的：用于染料敏化太阳能电池的钌基染料具有优异的摩擦光吸收系数，短路光电密度（Jsc），光电转换效率和长时间的稳定性，因为钌复合环状金属化通过CNN配体和红移光吸收性能。构成：钌系染料的制造方法包括：通过化学式3中的化合物与间氯过氧苯甲酸反应制造化学式4的化合物的步骤; 通过使化学式4中的化合物与POClO 3反应制备化学式5的化合物的步骤; 通过使化学式5中的化合物与2,4-二氟苯基硼酸频哪醇酯或2,4-二氯苯基硼酸频哪醇酯反应制备化学式6化合物的步骤; 通过化学式6中的化合物与甲醇和氢氧化钾反应制备化学式7的化合物的步骤; 以及通过使化学式7中的化合物与Ru（Cl）2（对甲基异丙基苯）] 2，化学式8中的化合物和硫氰酸铵反应来制备化学式1中的化合物的步骤。

20. 发明公开

KR1020110013910A 신규의 티에노티오펜-비닐렌-티에노티오펜을 함유하는 화합물, 이의 제조 방법 및 이를 포함하는 염료를 이용한 염료감응 태양전지 有权
标题翻译：含有亚乙基苯乙烯 - 乙烯基苯酚的新型化合物，使用包含化合物的染料制备化合物和染料敏化太阳能电池的方法
公开(公告)号：KR1020110013910A
公开(公告)日：2011-02-10
申请号：KR1020090071616
申请日：2009-08-04
申请人： 고려대학교 산학협력단
发明人： 고재중 , 최현봉 , 김덕현
IPC分类号： C07D495/04 , C07D409/04 , C07D495/22
摘要： PURPOSE: A compound containing thienothiophene-vinylene-thienothiophene is provided to form a dye-sensitive solar cell. CONSTITUTION: A compound containing thienothiophene-vinylene-thienothiophene is denoted by chemical formula 1. The compound of chemical formula 1 is prepared by reacting a compound of chemical formula 22 and a compound of chemical formula 23, and forming a compound of chemical formula 24. A dye-sensitive solar cell is formed on a conductive substrate and comprises a semiconductor electrode having dye-adsorbed metal oxide layer; a counter electrode; and an electrolyte filling between semiconductor electrode and counter electrode. The metal oxide layer further has a coadsorbent. The coadsorbent is DCA··TBA(tetrabutylammonium chenodeoxycholic acid salt).
摘要翻译：目的：提供含噻吩并噻吩 - 亚乙烯基 - 噻吩并噻吩的化合物，形成染料敏感的太阳能电池。构成：化学式1表示含有噻吩并噻吩 - 亚乙烯基 - 噻吩并噻吩的化合物。化学式1的化合物通过使化学式22的化合物与化学式23的化合物反应，并形成化学式24的化合物而制备。染料敏感的太阳能电池形成在导电基板上，并且包括具有染料吸附的金属氧化物层的半导体电极; 对电极以及在半导体电极和对电极之间填充电解质。金属氧化物层还具有共吸附剂。共吸附剂是DCA··TBA（四丁基枯烯脱氧胆酸盐）。

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