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    • 91. 发明公开
    • 암모니아수를 이용한 이산화탄소 포집 공정 내 재생탑 세정수의 재이용 장치
    • 用于水质氨水二氧化碳捕集过程的再利用洗涤水的装置
    • KR1020140085672A
    • 2014-07-08
    • KR1020120153906
    • 2012-12-26
    • 재단법인 포항산업과학연구원
    • 이만수한건우안치규
    • B01D53/14B01D53/62B01D53/96B01D53/73
    • Y02A50/2342Y02C10/04Y02C10/06B01D53/14B01D53/62B01D53/73B01D53/96
    • The present invention relates to an apparatus and a method for reusing regeneration tower washing water in a carbon dioxide capture process for mixed gas. The apparatus for capturing carbon dioxide from the carbon dioxide-containing mixed gas by using the ammonia water includes an absorption tower that absorbs the carbon dioxide with the ammonia water from the carbon dioxide-containing mixed gas and discharges the carbon dioxide-absorbed ammonia water; an absorption tower cleaning end that is disposed in an upper portion of the absorption tower and uses washing water to absorb and clean ammonia volatilizing from the ammonia water; a regeneration tower that heats the ammonia water which is discharged from the absorption tower and separates the carbon dioxide into a gas phase; a regeneration tower cleaning end that is disposed in an upper portion of the regeneration tower and uses the washing water to absorb and clean the ammonia volatilizing from the ammonia water and the gas-phase carbon dioxide present in the upper portion of the regeneration tower; and a concentration tower that removes the ammonia and the carbon dioxide contained in a washing liquid which is discharged from the cleaning end, in which the regeneration tower washing water that is discharged from the regeneration tower cleaning end flows into the absorption tower cleaning end.
    • 本发明涉及一种用于混合气体的二氧化碳捕获过程中再利用再生塔清洗水再利用的装置和方法。 通过使用氨水从含二氧化碳的混合气体中捕获二氧化碳的装置包括:吸收塔,其利用来自含二氧化碳的混合气体的氨水吸收二氧化碳,排出二氧化碳吸收的氨水; 吸收塔清洗端,其设置在吸收塔的上部,并且使用洗涤水来吸收和清洁从氨水中挥发的氨; 加热从吸收塔排出的氨水并将二氧化碳分离成气相的再生塔; 再生塔清洗端设置在再生塔的上部,利用洗涤水吸收和清洗从氨水挥发的氨和存在于再生塔上部的气相二氧化碳; 以及浓缩塔,其除去从清洗端排出的洗涤液中所含的氨和二氧化碳,其中从再生塔清洗端排出的再生塔洗涤水流入吸收塔清洗端。
    • 92. 发明公开
    • 탄산무수화 효소를 이용한 조류 배양장치 및 이를 이용한 조류 배양방법
    • 使用碳水化合物制备阿尔法的装置及其使用方法
    • KR1020130137759A
    • 2013-12-18
    • KR1020120061270
    • 2012-06-08
    • 재단법인 포항산업과학연구원
    • 안치규김제영한건우이창훈이만수
    • C12M3/02C12M1/40C12M1/04C12N1/12
    • C12M43/00C12M29/00
    • The present invention provides an algae cultivating method including a reactor provided with a carbon dioxide-containing flue gas supplying unit, a water supplying unit, and carbonic anhydrase, and producing carbonated water by making carbon dioxide-containing flue gas and water flowed into each of the supplying units react with the carbonic anhydrase; and an algae cultivating apparatus including an algae culture bath for cultivating algae using carbonated water. The method comprises the steps of: supplying carbon dioxide-containing flue gas, and water in the reactor including carbonic anhydrase; producing carbonated water by making the carbon dioxide react with water by carbonic anhydrase within the reactor; and cultivating algae using the produced carbonated water. The use of the algae cultivating apparatus and the algae cultivating method using the same can enhance carbon dioxide dissolution efficiency and algae productivity and reduce energy consumed in cultivating algae.
    • 本发明提供了一种藻类栽培方法,其包括设置有含二氧化碳的烟道气供给单元,供水单元和碳酸酐酶的反应器,并且通过使含二氧化碳的烟道气和水流入各自的方法生产碳酸水 供应单元与碳酸酐酶反应; 以及藻类栽培装置,其包括使用碳酸水培养藻类的藻类培养浴。 该方法包括以下步骤:在含有碳酸酐酶的反应器中提供含二氧化碳的烟气和水; 通过在反应器内通过碳酸酐酶使二氧化碳与水反应来生产碳酸水; 并使用生产的碳酸水培养藻类。 使用藻类栽培装置和使用该藻类培养方法的藻类培养方法可以提高二氧化碳溶解效率和藻类生产力并减少培养藻类的能量消耗。
    • 93. 发明公开
    • 중탄산암모늄 제조방법 및 제조장치
    • 生产二硼酸铵的方法和装置
    • KR1020130061920A
    • 2013-06-12
    • KR1020110128240
    • 2011-12-02
    • 재단법인 포항산업과학연구원
    • 안치규김제영한건우
    • C01C1/26C01C1/28B01D43/00B01J19/24
    • Y02P20/129C01C1/26
    • PURPOSE: A manufacturing method of ammonium bicarbonate is provided to manufacture ammonium bicarbonate with a low cost using gas-liquid reaction of ammonia solution and carbon dioxide generated from coal gasification process. CONSTITUTION: A manufacturing method of ammonium bicarbonate comprises the following steps. Ammonia generated from coal gasification process is collected to be ammonia solution. Carbon dioxide generated from coal gasification process is collected and ammonium bicarbonate slurry containing ammonium bicarbonate salt and water is generated using gas-liquid reaction with ammonia solution. The ammonium bicarbonate salt is collected by separating liquid from ammonium bicarbonate slurry. And ammonium bicarbonate is transformed into a solid state. The concentration of ammonia solution is 5-30%. Molality concentration of carbon dioxide molality/molality concentration of ammonia is 0.25-1 in the gas-liquid reaction of step. Ammonium bicarbonate manufacturing device includes reactor, solid-liquid separator, and dehydrator. [Reference numerals] (AA) Coal; (BB) Oxygen(O_2); (CC) Steam(H_2O); (DD) Gasifier; (EE) Oxygen facility; (FF) Synthetic gas; (GG) High concentration ammonia solution; (HH) Liquid reaction; (II) Gas refining; (JJ) Ammonium bicarbonate production apparatus; (KK) Ammonium bicarbonate slurry; (LL) Solid-liquid separator; (MM) Supernatant; (NN) Dehydrator; (OO) Dehydrated filtrate; (PP) Solid ammonium bicarbonate; (QQ) Waste heat returning power generation; (RR) Methane synthesis; (SS) Synthetic natural gas; (TT) Concentrated ammonia solution; (UU) Ammonia concentrator; (VV) Wastewater
    • 目的:提供碳酸氢铵的制造方法以低成本制造碳酸氢铵,使用氨溶液的气液反应和由煤气化过程产生的二氧化碳。 构成:碳酸氢铵的制造方法包括以下步骤。 从煤气化过程产生的氨被收集为氨溶液。 收集由煤气化过程产生的二氧化碳,并使用与氨溶液的气液反应产生含有碳酸氢铵盐和水的碳酸氢铵浆液。 通过从碳酸氢铵浆液中分离液体来收集碳酸氢铵盐。 并将碳酸氢铵转化为固态。 氨溶液浓度为5-30%。 在步骤的气液反应中,二氧化碳的摩尔浓度/氨的摩尔浓度浓度为0.25-1。 碳酸氢铵制造装置包括反应器,固液分离器和脱水机。 (附图标记)(AA)煤; (BB)氧(O_2); (CC)蒸汽(H_2O); (DD)气化器; (EE)氧气设施; (FF)合成气; (GG)高浓度氨溶液; (HH)液体反应; (二)气体精炼; (JJ)碳酸氢铵生产装置; (KK)碳酸氢铵浆液; (LL)固液分离器; (MM)上清液; (NN)脱水剂; (OO)脱水滤液; (PP)固体碳酸氢铵; (QQ)余热发电; (RR)甲烷合成; (SS)合成天然气; (TT)浓氨水溶液; (UU)氨浓缩机; (VV)废水
    • 94. 发明公开
    • 친환경 열역학적 하이드레이트 형성 억제제
    • 环境热力学水合物形成抑制剂
    • KR1020130058483A
    • 2013-06-04
    • KR1020110124505
    • 2011-11-25
    • 재단법인 포항산업과학연구원
    • 한건우사정훈이건홍박다혜이보람
    • C09K3/00C07C229/08C07C229/00
    • PURPOSE: An environmental thermodynamic hydrate formation inhibitor is provided to thermodynamically suppress formation of a gas hydrate due to a reaction between gas and moisture and to be harmless to a human body and environment. CONSTITUTION: A hydrate formation inhibitor is an amino acid or a derivative thereof. The amino acid or the derivative thereof is one or more selected from L-proline, L-serine, glycine, L-alanine, and L-valine. A method for inhibiting formation of a hydrate comprises a step of injecting the amino acid or the derivative thereof into a moisture-containing gas up to a maximum solubility. [Reference numerals] (AA) Pressure(bar); (BB) Pure water(CSMGem); (CC) Pure water(example 1); (DD) Glycine 0.1 mole%; (EE) Glycine 0.5 mole%; (FF) Glycine 1.3 mole%; (GG) Glycine 2.2 mole%; (HH) Glycine 3.0 mole%; (II) Methanol 3.0 mole%; (JJ) Temperature(K)
    • 目的:提供一种环境热力学水合物形成抑制剂,用于热力学抑制由于气体和水分之间的反应而导致的天然气水合物的形成,并且对人体和环境无害。 构成:水合物形成抑制剂是氨基酸或其衍生物。 氨基酸或其衍生物是选自L-脯氨酸,L-丝氨酸,甘氨酸,L-丙氨酸和L-缬氨酸中的一种或多种。 抑制水合物形成的方法包括将氨基酸或其衍生物注入含水气体中达到最大溶解度的步骤。 (标号)(AA)压力(bar); (BB)纯水(CSMGem); (CC)纯水(实施例1); (DD)甘氨酸0.1摩尔%; (EE)甘氨酸0.5摩尔%; (FF)甘氨酸1.3摩尔% (GG)甘氨酸2.2mol%; (HH)甘氨酸3.0摩尔% (II)甲醇3.0摩尔% (JJ)温度(K)
    • 96. 发明公开
    • 미세기포 발생기를 이용한 이산화탄소 포집장치 및 그 포집방법
    • 使用微生物发生器捕获二氧化碳的装置和方法
    • KR1020130028413A
    • 2013-03-19
    • KR1020110091944
    • 2011-09-09
    • 재단법인 포항산업과학연구원
    • 한건우박흥수이민영
    • B01D53/14B01D53/62B01D53/78
    • Y02A50/2342Y02C10/04Y02C10/06B01D53/14B01D53/62B01D53/78
    • PURPOSE: Carbon dioxide collecting device and method using micro-bubbles are provided to collect carbon dioxide using a miniaturized device without a filler. CONSTITUTION: A carbon dioxide collecting method comprises the following steps: inserting mixed gas containing carbon dioxide into an absorptive tower(110); producing micro-bubbles using the mixed gas in a micro-bubble generator(130), floating the micro-bubbles to touch with absorption liquid inside the absorptive tower, and absorbing the carbon dioxide in the absorption liquid; transferring the absorption liquid containing the carbon dioxide to a regeneration tower(150); increasing the temperature of the absorption liquid in the regeneration tower for separating the carbon dioxide from the absorption liquid; and discharging the carbon dioxide to the upper side of the regeneration tower, and returning the absorption liquid to the absorptive tower.
    • 目的:提供使用微气泡的二氧化碳收集装置和方法,使用无填料的小型化装置收集二氧化碳。 构成:二氧化碳收集方法包括以下步骤:将含有二氧化碳的混合气体插入吸收塔(110)中; 在微气泡发生器(130)中使用混合气体产生微气泡,使微气泡漂浮以与吸收塔内的吸收液体接触,吸收吸收液体中的二氧化碳; 将含有二氧化碳的吸收液转移到再生塔(150); 增加再生塔中的吸收液体的温度,用于从吸收液中分离出二氧化碳; 并将二氧化碳排出到再生塔的上侧,并将吸收液体返回到吸收塔。
    • 97. 发明公开
    • 모델식을 이용한 이산화탄소 포집공정의 반응생성물 농도 예측방법 및 이를 이용한 포집 반응기
    • 使用二氧化碳捕集过程中使用模型方程的反应产物的密度和使用其的收集器反应器的方法
    • KR1020120128787A
    • 2012-11-28
    • KR1020110046647
    • 2011-05-18
    • 재단법인 포항산업과학연구원
    • 안치규김제영한건우이창훈박종문장용수김유리
    • B01J10/00B01J19/00B01D53/62G06F19/00
    • Y02A50/2342Y02C10/04G06F19/702B01D53/62B01J10/00B01J19/00
    • PURPOSE: A method for predicting the concentration of a reaction product from a carbon dioxide collecting process and a collecting reactor are provided to optimize the collecting process by obtaining the optimal model of the collecting process from various models on the web. CONSTITUTION: A method for predicting the concentration of a reaction product from a carbon dioxide collecting process includes the following steps: a state variable measured through a carbon dioxide collecting process is set as a varying variable(S100); the concentration of a reaction product from the collecting process obtained using the varying variable is set as a target variable(S200); a model is generated to predict the target variable(S300); and the concentration of the reaction product according to the variation of the varying variable is predicted by the model(S400). The state variable is at least one selected from the concentration of carbon dioxide, the pH value, the temperature, and the electric conductivity of ammonia water containing absorbed carbon dioxide. The reaction product is one selected from a group including hydrogen ion, hydroxide ion, bicarbonate ion, carbonate ion, carbamate ion, ammonium bicarbonate, ammonium carbamate, sulfate ion, and nitrate ion. [Reference numerals] (AA) Start; (BB) End; (S100) Setting a state variable measured through a carbon dioxide collecting process through web as a varying variable; (S200) Setting the concentration of a reaction product from the carbon dioxide collecting process obtained using the varying variable as a target variable; (S300) Generating a model for predicting the target variable; (S400) Predicting the concentration of the reaction product according to the varying variable by the model
    • 目的:提供一种预测来自二氧化碳收集过程和收集反应器的反应产物浓度的方法,以通过从网上的各种模型获得收集过程的最佳模型来优化收集过程。 构成:用于预测来自二氧化碳收集过程的反应产物浓度的方法包括以下步骤:将通过二氧化碳收集过程测量的状态变量设置为变化变量(S100); 将来自使用变化变量获得的收集处理的反应产物的浓度设定为目标变量(S200)。 生成模型来预测目标变量(S300); 并且通过模型预测根据变化变量的变化的反应产物的浓度(S400)。 状态变量是选自二氧化碳浓度,pH值,温度和含有吸收的二氧化碳的氨水的电导率中的至少一种。 反应产物是选自氢离子,氢氧根离子,碳酸根离子,碳酸根离子,氨基甲酸根离子,碳酸氢铵,氨基甲酸铵,硫酸根离子和硝酸根离子组成的组。 (附图标记)(AA)开始; (BB)结束; (S100)将通过二氧化碳收集过程测量的状态变量设置为变化的变量; (S200)将使用变化变量获得的二氧化碳收集过程的反应产物浓度设定为目标值; (S300)生成用于预测目标变量的模型; (S400)通过模型根据变化的变量预测反应产物的浓度
    • 99. 发明公开
    • 슬래그 건식 처리장치 및 방법
    • SLAG干燥成粒装置及方法
    • KR1020110119991A
    • 2011-11-03
    • KR1020100039452
    • 2010-04-28
    • 재단법인 포항산업과학연구원
    • 박흥수김제영박주형이민영한건우이창훈류성욱
    • C21B3/06C04B5/00
    • Y02W30/543C21B3/08C21B2200/00F27D15/02
    • PURPOSE: An apparatus and a method for slag dry granulation are provided to improve the recovery rate of heat energy from high-temperature slag produced during the granulation of molten slag. CONSTITUTION: An apparatus for slag dry granulation comprises a main body(10), a slag collision rotator(50), and a circulating cooling gas flow forming unit(70). The slag collision rotator is installed in the main body in order to provide the collision and scattering of molten slag(30). The circulating cooling gas flow forming unit provides the main body with circulating cooling gas flow which passes through the main body and cools the molten slag. The main body includes a slag feed hopper(12) for putting in molten slag and a vent(14) for discharging high-temperature gas(G') heat-exchanged with slag particles(30').
    • 目的:提供渣干造粒的设备和方法,以提高熔渣造粒过程中产生的高温炉渣的热能回收率。 构成:用于渣干造粒的装置包括主体(10),炉渣碰撞旋转器(50)和循环冷却气流形成单元(70)。 炉渣碰撞旋转器安装在主体中,以提供熔渣(30)的碰撞和散射。 循环冷却气体流动形成单元为主体提供通过主体的循环冷却气体流并使熔渣冷却。 主体包括用于放入熔融炉渣的供料料斗(12)和用于排出与炉渣颗粒(30')热交换的高温气体(G')的排气口(14)。