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    • 6. 发明专利
    • Metal complex and method for production thereof
    • 金属复合材料及其生产方法
    • JP2011195570A
    • 2011-10-06
    • JP2011036584
    • 2011-02-23
    • Kuraray Co Ltd株式会社クラレ
    • INUBUSHI YASUTAKAIKEDA CHIKAKOKANEHIRA KOICHI
    • C07F3/06B01J20/22C07C63/333C07D213/22
    • Y02C10/08
    • PROBLEM TO BE SOLVED: To provide a metal complex having excellent performances in gas occlusion as well as gas separation.SOLUTION: The metal complex comprises a diphenyl dicarboxylic acid compound, at least one metal ion selected from the ions of metals belonging to the groups 2 and 7-12 in the periodic table, and an organic ligand (II) which can form a bidentate on the metal and is represented by general formula (II) (wherein Rto Rare the same or different and are each hydrogen, halogen or alkyl optionally having a substituent, or Rmay join R, or Rmay join Rto form alkenylene which may have a substituent). A method for production of the metal complex is also provided.
    • 要解决的问题:提供一种在气体闭塞以及气体分离中具有优异性能的金属络合物。溶液:金属络合物包括二苯基二羧酸化合物,至少一种选自属于第2族金属的金属离子的金属离子 和II-12的化合物,以及可以在金属上形成二齿的有机配体(II),并且由通式(II)表示(其中R 1至R 2相同或不同,各自为氢,卤素或烷基, 具有取代基或Rmay连接R,或Rmay连接R可形成可具有取代基的亚烯基)。 还提供了一种生产金属络合物的方法。